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CRYSTAL STRUCTURES OF TETRAMETHYLAMMONIUM SALTS [XW18O60]9–

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Abstract

Crystal structures of tetramethylammonium salts of [XW18O60]9– anions (X = As3+, Sb3+) are described for the first time. The structures of ((CH3)4N)6H3[AsW18O60]·3.8H2O (1) and ((CH3)4N)6H2.5Na0.5[SbW18O60]· 7.7H2O (2) are determined by single crystal X-ray diffraction. In the structure of complex 2, the [β-SbW18O60]9– isomer is discovered for the first time.

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  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    P. A. Abramov

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  1. P. A. Abramov
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Russian Text © The Author(s), 2021, published in Zhurnal Strukturnoi Khimii, 2021, Vol. 62, No. 7, pp. 1151-1156.https://doi.org/10.26902/JSC_id76138

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Abramov, P.A. CRYSTAL STRUCTURES OF TETRAMETHYLAMMONIUM SALTS [XW18O60]9–. J Struct Chem 62, 1073–1078 (2021). https://doi.org/10.1134/S0022476621070118

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  • DOI: https://doi.org/10.1134/S0022476621070118

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