Skip to main content
SpringerLink
Log in

SYNTHESIS, CHARACTERIZATION, COMPUTATIONAL STUDIES AND SINGLE CRYSTAL STRUCTURES OF [Ru(N–P)2(O–O)] COMPLEXES

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

An Erratum to this article was published on 01 September 2021

This article has been updated

Abstract

The title complexes [Ru(N–P)2(O–O)] (N–P = (8-diphenylphosphino)quinoline, O–O = dianion of oxalate (1), malonate (2) or 1,1-cyclobutandicarboxylate (3)), are prepared from [Ru(N–P)2Cl2] by a reaction with potassium salt of oxalate, malonate, or cyclobutandicarboxylate, respectively. All the complexes have distorted octahedral structures. Complex 1 crystallizes in the monoclinic system with space groups P21/c. On the other hand, complexes 2 and 3 crystallizes in the triclinic system with the space group P-1. The UV-Vis spectra of the three complexes are modeled using time dependent density function theory (TD–DFT).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

Change history

REFERENCES

  1. D. W. Franco. Coord. Chem. Rev., 1992, 119, 199-225.

    Article  CAS  Google Scholar 

  2. S. Wesselbaum, T. vom Stein, J. Klankermayer, and W. Leitner. Angew. Chem., Int. Ed., 2012, 51(30), 7499-7502.

    Article  CAS  Google Scholar 

  3. J. O. Krause, O. Nuyken, K. Wurst, and M. R. Buchmeiser. Chem. - Eur. J., 2004, 10(3), 777-784.

    Article  CAS  PubMed  Google Scholar 

  4. O. Kröcher, R. A. Köppel, and A. Baiker. Chimia, 1997, 51(1-2), 48-51.

  5. D. A. Hey, P. J. Fischer, W. Baratta, and F. E. Kühn. Dalton Trans., 2019, 48(14), 4625-4635.

    Article  CAS  PubMed  Google Scholar 

  6. T. Suzuki, T. Kuchiyama, S. Kishi, S. Kaizaki, H.D. Takagi, and M. Kato. Inorg. Chem., 2003, 42(3), 785-795.

  7. T. Suzuki, T. Kuchiyama, S. Kishi, S. Kaizaki, and M. Kato. Bull. Chem. Soc. Jpn., 2002, 75(11), 2433-2439.

    Article  CAS  Google Scholar 

  8. M. A. Al-Wahish, F. F. Awwadi, R. K. Al-Shwieki, and H. A. Hodali. Inorg. Nano-Met. Chem., 2017, 47(5), 655-660.

    Article  CAS  Google Scholar 

  9. G. Nakamura, M. Okamura, M. Yoshida, T. Suzuki, H. D. Takagi, M. Kondo, and S. Masaoka. Inorg. Chem., 2014, 53(14), 7214-7226.

    Article  CAS  PubMed  Google Scholar 

  10. C. S. Allardyce and P. J. Dyson. Platinum Met. Rev., 2001, 45(2), 62-69.

  11. G. Süss-Fink. Dalton Trans., 2010, 39(7), 1673-1688.

    Article  CAS  PubMed  Google Scholar 

  12. F. A. Cotton, G. Wilkinson, C. A. Murillo, and M. Bochmann. Advanced Inorganic Chemistry, 6th ed. Wiley-Interscience: New York, 1999, Part 3, Ch. 2.

  13. L. Bíró, E. Farkas, and P. Buglyó. Dalton Trans., 2010, 39(42), 10272-10278.

    Article  CAS  PubMed  Google Scholar 

  14. S. H. Dale and M. R. Elsegood. Acta Crystallogr., Sect. C: Cryst. Struct. Commun., 2006, 62(4), m166-m170.

    Article  Google Scholar 

  15. H.-Y. Shen, W.-M. Bu, D.-Z. Liao, Z.-H. Jiang, S.-P. Yan, and G.-L. Wang. Inorg. Chem. Commun., 1999, 2(12), 615-618.

    Article  CAS  Google Scholar 

  16. C. F. Liu, N. C. Liu, and J. C. Bailar Jr. Inorg. Chem., 1964, 3(8), 1197-1198.

    Article  CAS  Google Scholar 

  17. Y.-L. Yu, L.-H. Huang, Y.-F. Zhou, J.-D. Lou, and X. L. Lu. J. Coord. Chem., 2014, 67(7), 1208-1218.

    Article  CAS  Google Scholar 

  18. R. D. Feltham and H. G. Metzger. J. Organomet. Chem., 1971, 33, 347-355.

    Article  CAS  Google Scholar 

  19. I. Evans, A. Spencer, and G. Wilkinson. J. Chem. Soc., Dalton Trans. 2, 1973, 204-209.

    Article  Google Scholar 

  20. W. L. Armarego. Purification of Laboratory Chemicals. Butterworth-Heinemann, 2017.

  21. CrysAlisPro, Version 1.171.35.19 (release 27-10-2011 CrysAlis171.NET). Oxford Diffraction Ltd., 2011.

  22. O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. Howard, and H. Puschmann. J. Appl. Crystallogr., 2009, 42(2), 339-341.

    Article  CAS  Google Scholar 

  23. L. J. Bourhis, O. V. Dolomanov, R. J. Gildea, J. A. Howard, and H. Puschmann. Acta Crystallogr., Sect. A: Found. Adv., 2015, 71(1), 59-75.

    Article  CAS  Google Scholar 

  24. G. M. Sheldrick. Acta Crystallogr., Sect. A: Found. Adv., 2015, 71(1), 3-8.

    Article  Google Scholar 

  25. R. Dennington, T. A. Keith, J. M. Millam. GaussView 5.0.9. Semichem Inc.: Shawnee Mission, KS, 2009.

  26. A. Becke. J. Chem. Phys., 1993, 98, 5648.

    Article  CAS  Google Scholar 

  27. N. M. Oboyle, A. L. Tenderholt, and K. M. Langner. J. Comput. Chem., 2008, 29(5), 839-845.

    Article  CAS  PubMed  Google Scholar 

  28. K. Kalyanasundaram. Coord. Chem. Rev., 1982, 46, 159-244.

    Article  CAS  Google Scholar 

Download references

Funding

The authors gratefully acknowledge the financial support provided by the Deanship of Academic Research (Project No. 1331), The University of Jordan, Amman 11942, Jordan.

Author information

Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, The University of Jordan, Amman, Hashemite Kingdom of Jordan

    M. A. Al-Wahish, F. F. Awwadi & H. A. Hodali

Authors
  1. M. A. Al-Wahish
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. F. F. Awwadi
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. H. A. Hodali
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to H. A. Hodali.

Ethics declarations

The authors declare that they have no conflict of interests.

Additional information

Text © The Author(s), 2021, published in Zhurnal Strukturnoi Khimii, 2021, Vol. 62, No. 7, pp. 1134-1143.https://doi.org/10.26902/JSC_id74443

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Al-Wahish, M.A., Awwadi, F.F. & Hodali, H.A. SYNTHESIS, CHARACTERIZATION, COMPUTATIONAL STUDIES AND SINGLE CRYSTAL STRUCTURES OF [Ru(N–P)2(O–O)] COMPLEXES. J Struct Chem 62, 1056–1065 (2021). https://doi.org/10.1134/S002247662107009X

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S002247662107009X

Keywords

Search

Navigation