Abstract—
We have synthesized a GaSb–Fe3Ga4 semiconducting eutectic composite. It has been characterized by X-ray diffraction at different temperatures, and we have determined the elemental composition of its matrix, metallic inclusions, and the interfacial zone. Its specific magnetization and magnetic susceptibility have been measured by a ponderomotive method in the temperature range ~80–750 K and a vibrating sample method at 4.6 and 295 K in magnetic fields of up to B = ±14 T. The GaSb–Fe3Ga4 eutectic composite has been shown to have properties of a magnetic material with a Curie temperature TC = 355 K. At liquid-nitrogen temperature, the specific magnetization of the eutectic composite is σ ≈ 1.5 A m2/kg and its average magnetic moment is µ ≈ 0.17µВ. The magnetic characteristics of the composite have been shown to be stable to thermal loads up to 750 K and insensitive to the external magnetic field up to 14 T.
Similar content being viewed by others
REFERENCES
Muller, A. and Wilhem, M., Über den gerichteten Einbau von Schwermetall Phasen in AIIIBV-Verbindungen: die Eutektika GaSb–CrSb, GaSb–FeGa1.3, GaSb–CoGa1.3, InAs–CrAs und InAs–FeAs, J. Phys. Chem. Solids, 1965, vol. 26, no. 12, pp. 2029–2035. https://www.sciencedirect.com/journal/journal-of-physics-and-chemistry-of-solids/vol/26/issue/12
Wagini, H. and Wilhelm, M., Magnetische und electrische Messungen of System InSb–Mn, Z. Naturforsch, A, 1966, vol, 21, no. 4, pp. 329–333. http://zfn.mpdl.mpg.de/data/Reihe_A/21/ZNA-1966-21a-0329.pdf
Uher, C. and Goldsmid, H.J., A comparison of thermomagnetic materials for use of room temperature, J. Phys. D: Appl. Phys., 1972, vol. 5, no. 7, pp. 1478–1488. http://iopscience.iop.org/article/10.1088/0022-3727/ 5/8/318/meta
Aliev, M.I., Abdinova, S.G., and Aliev, S.A., Transport processes in a eutectic alloy, Izv. Akad. Nauk SSSR, Neorg. Mater., 1974, vol. 10, no. 5, pp. 823–826.
Aliev, M.I., Arasly, D.G., Guseinov, R.E., and Dzhabbarov, R.M., Thermal conductivity and thermal diffusivity of InSb–MnSb based eutectics, Izv. Akad. Nauk SSSR, Neorg. Mater., 1979, vol. 15, no. 8, pp. 1320–1323.
Aliev, M.I., Dadashov, P.Sh., and Safaraliev, G.I., Transport properties of Ga1 – xMnxSb alloys in the range 80–1000 K, Fiz. Met. Metalloved., 1980, vol. 49, no. 5, pp. 1093–1095.
Mamedov, I.Kh., Arasly, D.G., Khalilova, A.A., and Ragimov, R.N., Anisotropic electrical properties of a eutectic InSb + MnSb composite, Inorg. Mater., 2016, vol. 52, no. 4, pp. 423–428. https://doi.org/10.7868/S0002337X16040102
Aliyev, M.I., Khalilova, A.A., Arasly, D.H., Rahimov, R.N., Tanoglu, M., and Ozyuzer, L., Features of electron and phonon processes in GaSb–FeGa1.3, J. Phys. D: Appl. Phys., 2003, vol. 36, pp. 2627–2633. https://doi.org/10.1088/0022-3727/36/21/005
Mamedov, I.Kh., Ragimov, R.N., Khalilova, A.A., Arasly, D.G., and Aliev, M.I., Influence of doping on the microstructure and kinetic parameters of GaSb–FeGa1.3 eutectics, Crystallogr. Rep., 2012, vol. 57, no. 7, pp. 923–926. https://doi.org/10.1134/S106377451207019X
Rahimov, R.N., Khalilova, A.A., Arasly, D.H., Aliyev, M.I., Tanoglu, M., and Ozyuzer, L., Thermostable tensoresistors of Co doped GaSb–FeGa1.3 eutectic composites, Sens. Actuators, A, 2008, vol. 147, pp. 436–440. https://doi.org/10.1016j.sna.2008.05.032
Ragimov, R.N., Mamedov, I.Kh., Arasly, D.G., Khalilova, A.A., and Dzhabbarov, R.M., InSb–FeSb eutectic based thermal detector, Prikl. Fiz., 2006, no. 5, pp. 86–89.
Aliyev, M.I., Khalilova, A.A., Arasly, D.H., Rahimov, R.N., Tanoglu, M., and Ozyuzer, L., Strain gauges of GaSb–FeGa1.3 eutectic composites, Appl. Phys. A, 2004, vol. 79, no. 8, pp. 2075–2079. https://doi.org/10.1007s00339-004-2870-0
Marenkin, S.F., Kochura, A.V., Fedorchenko, I.V., Drogunov, S.V., Izotov, A.D., Vasil’ev, M.G., Trukhin, V.M., Shelkovaya, T.V., Novodvorskii, O.A., and Zheludkevich, A.L., Growth of eutectic composites in the InSb–MnSb system, Inorg. Mater., 2016, vol. 52, no. 3, pp. 268–273. https://doi.org/10.1134/S0020168516030110
Dmitriev, A.I., Kochura, A.V., Kuz’menko, A.P., Parshina, L.S., Novodvorskii, O.A., Khramova, O.D., Kochura, E.P., Vasil’ev, A.L., and Aronzon, B.F., Effect of heat treatment on the dispersion of the magnetic anisotropy of MnSb nanoinclusions embedded in thin GaMnSb films, Phys. Solid State, 2019, vol. 61, no. 4, pp. 523–529. https://doi.org/10.1134/S1063783419040073
Ivanov, V.A., Aminov, T.G., Novotortsev, V.M., and Kalinnikov, V.T., Spintronics and spintronic materials, Izv. Akad. Nauk, Ser. Khim., 2004, no. 11, pp. 2255–2303.
Talantsev, A.D., Kolpak, O.V., and Morgunov, R.B., Ferromagnetism and microwave magnetoresistance of GaMnSb films, Phys. Solid State, 2015, vol. 57, no. 2, pp. 322–330. https://doi.org/10.1134/S1063783415020353
Novotortsev, V.M., Kochura, A.V., Marenkin, S.F., Fedorchenko, I.V., Dorogunov, S.V., Lashkul, A., and Lähderanta, E.I., Synthesis and magnetic properties of the InSb-MnSb eutectic, Russ. J. Inorg. Chem., 2011, vol. 56, no. 12, pp. 1951–1956. https://doi.org/10.1134/S0036023611120400
Nilsen, T.A., Breivik, M., Myrvågnes, G., and Fimland, B., Thermal expansion of GaSb measured by temperature dependent X-ray diffraction, J. Vac. Sci. Technol. B, 2010, vol. 28, pp. 3117–3120. https://doi.org/10.1116/1.3336341
Kawamiya, N. and Adachi, K., Magneting and Mössbauer studies of metamagnetic Fe3Ga4, J. Phys. Soc. Jpn., 1986, vol. 55, pp. 634–640. https://doi.org/10.1143/JPSJ.55.634
Moura, K.O., de Oliveira, L.A.S., Rosa, P.F.S., Jesus, C.B.R., Saleta, M.E., Granado, E., Beron, F., Paglinso, P.G., and Pirota, K.R., Dimensionality tuning of the electronic structure in Fe3Ga4 magnetic materials, Sci. Rep., 2016, paper 6:28364. https://doi.org/10.1038/srep28364
Mendez, J.H., Ekuma, C.E., Wu, Y., Fulfer, B.W., Prestigiacomo, J.C., Shelton, W.A., Jarrelly, M., Moreno, J., Young, D.P., Adams, P.W., Karki, A., Jin, R., and Julia, Y., Competing magnetic states, disorder and the magnetic character of Fe3Ga4, Phys. Rev. B: Condens. Matter Mater. Phys., 2015, vol. 91, paper 144409. https://doi.org/10.1103/PhysRevB.91.144409
Wagini, H., Magnetische, elektrische und thermische Eigenschaften der bcc-a-Phase im System Fe–Ga, Z. Naturforsch., A, 1967, vol. 22, pp. 143–144. https://doi.org/10.1515/zna-1967-0125
Duijn, H.G.M., Brück, E., Buschow, K.H.J., de Boer, F.R., Waals, Van., Prokeš, K., and Sechovský, K., Pressure dependence of the ferromagnetic to antiferromagnetic transition in Fe3(Ga1−xAlx)4 with x = 0.0 and 0.1, J. Appl. Phys., 1999, vol. 85, pp. 4738–4740. https://doi.org/10.1063/1.370465
Kawamiya, N. and Adachi, K., Magneting phase change in (Fe1–xCox)3Ga4, J. Magn. Magn. Mater., 1986, vol. 54, pp. 941–945. https://doi.org/10.1016/0304-8853(86)90324-0
Moriya, T. and Usami, K., Coexistence of ferro- and antiferromagnetism and phase transitions in itinerant electron systems, Solid State Commun., 1977, vol. 23, pp. 935–938. https://doi.org/10.1016/0038-1098(77)90719-0
Lotgering, P.K. and Gorter, E.W., Solid solution between ferromagnetic and antiferromagnetic compounds with NiAs structure, J. Phys. Chem. Solids, 1957, vol. 3, pp. 238–249. https://doi.org/10.1016/0022-3697(57)90028-8
Sanygin, V.P., Izotov, A.D., and Pashkova, O.N., Dislocation magnetism of the GaSb〈Mn〉 semiconductor, Inorg. Mater., 2019, vol. 55, pp. 892–897. https://doi.org/10.1134/S0020168519090164
Funding
This work was supported in part by the Belarusian Republican Foundation for Fundamental Research (project no. T18Az-029) and the Belarussian Academy of Sciences (national research program, 2016–2020).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Mammadov, I.K., Yanushkevich, K.I., Arasly, D.G. et al. Magnetic Characteristics of a GaSb–Fe3Ga4 Eutectic Composite. Inorg Mater 57, 767–774 (2021). https://doi.org/10.1134/S0020168521080045
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0020168521080045