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Synthesis of Some Heteropolyfunctional Reactive Dyes and Their Application on Silk, Wool, and Cotton Fibers

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Abstract

Some heteropolyfunctional reactive dyes (5a-5n) containing poly(monochlorotriazine and sulfatoethylsulfone) reactive systems have been synthesized by coupling of tetrazotized 4,4’-methylene bis(2-carboxy aniline) with various 4-(ethylsulfurate sulfonyl)anilino cyanurated coupling components (4a-4n) such as H-acid, Gamma acid, J-acid, N-methyl Jacid, N-phenyl J-acid, Chicago acid, S-acid, K-acid, Bronner acid, Peri acid, Laurent acid, Koch acid, Naphthionic acid, and Tobias acid. The synthesized dyes were characterized by nitrogen elemental analysis, IR, and 1H-NMR spectra. They were applied on wool, silk, and cotton fibers. Their dyeing properties, fastness properties, and colorimetric data (L*, a*, b*, C*, H*, and K/S) have also been investigated.

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Acknowledgements

Authors are thankful to Department of Chemistry, Narmada College of Science and Commerce, Zadeshwar, Bharuch, India for providing research facility, Atul Ltd., Atul, Valsad, India for providing dyeing facility, fastness properties, colorimetric data, and SAIF, Chandigarh, India for spectral data.

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Correspondence to Paresh S. Patel.

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Patel, P.S., Patel, D.H. & Patel, K.C. Synthesis of Some Heteropolyfunctional Reactive Dyes and Their Application on Silk, Wool, and Cotton Fibers. Fibers Polym 23, 86–97 (2022). https://doi.org/10.1007/s12221-021-0413-3

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  • DOI: https://doi.org/10.1007/s12221-021-0413-3

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