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Oxidative Cracking of Propane in the Presence of Hydrogen

  • Organic Synthesis and Industrial Organic Chemistry
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Abstract

An effect of hydrogen additions to the initial mixture on the parameters of the oxidative cracking of propane at atmospheric pressure, temperatures of 500–750°C, reaction time of 2 s, and С3H82 initial ratio ~2 was experimentally investigated. It was shown that small amounts of hydrogen promote the process due to the formation of additional active radicals OH and H. Performance of the oxidative cracking of propane in a large excess of hydrogen results in an increase in the yield of methane and ethane, while the yield of ethylene, the target product of the process, decreases.

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REFERENCES

  1. Churilin, A.S. and Zelentsova, N.I., Ekspozitsiya NEFT’ GAZ, 2013, no. 1, pp. 49–53.

  2. Ozerskii, A.V., Zimin, Y.S., Komarov, I.K., Nikitin, A.V., Sedov, I.V., Fokin, I.G., Savchenko, V.I., andArutyunov, V.S., Russ. J. Appl. Chem., 2019, vol. 92, no. 12, pp. 1745–1750. https://doi.org/10.1134/S1070427219120162 

    Article  CAS  Google Scholar 

  3. Lange, J.-P., Schoonebeek, R.J., Mercera, P.D.L., and van Breukelen, F.M., Appl. Catal. A: General., 2005, vol. 283, no. 1–2, pp. 243–253. https://doi.org/10.1016/j.apcata.2005.01.011

    Article  CAS  Google Scholar 

  4. Nikitin, A.V., Ozerskii, A.V., Afaunov, A.A, Sedov, I.V., Savchenko, V.I., and Arutyunov, V.S., Russ. J. Appl. Chem., 2018, vol. 91, no. 11, pp. 1767–1772. https://doi.org/10.1134/S1070427218110058 

    Article  CAS  Google Scholar 

  5. Wang, D. and Feng, X., Int. J. Hydrogen Energy, 2013, vol. 38, pp. 12968–12976. https://doi.org/10.1016/j.ijhydene.2013.04.077

    Article  CAS  Google Scholar 

  6. Arutyunov, V.S. and Strekova, L.N., Russ. J. Phys. Chem. B, 2012, vol. 6, no. 4, pp. 486–497. https://doi.org/10.1134/S1990793112080027 

    Article  CAS  Google Scholar 

  7. Borisov, A.A., Troshin, K.Ya., Skachkov, G.I., Kolbanovskii, Yu.A., andBilera, I.V., Russ. J. Appl. Chem., 2014, vol. 8, no. 6, pp. 866–869. https://doi.org/10.1134/S1990793114110153 

    Article  CAS  Google Scholar 

  8. Liu, Y., Zhang, Y., Zhao, D., Yin, J., Liu, L., and Shu, C., Int. J. Hydrogen Energy, 2019, vol. 44, no. 40, pp. 22712–22718. https://doi.org/10.1016/j.ijhydene.2019.03.064

    Article  CAS  Google Scholar 

  9. Li, Y., Bi, M., Gao, W., Zhou, Y., and Huang, L., J. Loss. Prev. Process Ind., 2020, vol. 64, ID 104078. https://doi.org/10.1016/j.jlp.2020.104078

    Article  CAS  Google Scholar 

  10. Bunev, V.A., Namyatov, I.G., and Babkin, V.S., Khim. Fizika, 2007, vol. 26, no. 9, pp. 39–45.

    CAS  Google Scholar 

  11. Zamashchikov, V.V., Namyatov, I.G., and Bunev, I.G., Fizika Goreniya Vzryva, 2004, vol. 40, no. 5, pp. 30–41.

    CAS  Google Scholar 

  12. Savchenko, V.I., Arutyunov, V.S., Fokin, I.G., Nikitin, A.V., and Sedov, I.V., Petrol. Chem., 2017, vol. 57, no. 3, pp. 236–243. https://doi.org/10.1134/S0965544117020232

    Article  CAS  Google Scholar 

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Funding

This work was supported by a grant from the Russian Science Foundation (project no. 19-73-00291).

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Authors

Contributions

A.V. Ozersky, K.A. Timofeev, and Ya.S. Zimin conducted experiments on the oxidative cracking of propane, chromatographic analysis of reagents and products, analysis and generalization of experimental results; A.V. Nikitin, V.S. Arutyunov formulated research problems, discussed the results of an experimental study of the oxidative cracking of propane in the presence of hydrogen; I.V. Sedov conducted a literary review on the research topic.

Corresponding author

Correspondence to Ya. S. Zimin.

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The authors declare that they have no conflicts of interest requiring disclosure in this article.

Additional information

Translated from Zhurnal Prikladnoi Khimii, No. 6, pp. 778–783, January, 2021 https://doi.org/10.31857/S0044461821060128

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Ozerskii, A.V., Zimin, Y.S., Timofeev, K.A. et al. Oxidative Cracking of Propane in the Presence of Hydrogen. Russ J Appl Chem 94, 787–792 (2021). https://doi.org/10.1134/S1070427221060124

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  • DOI: https://doi.org/10.1134/S1070427221060124

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