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Inverse Emulsion Copolymerization of Acrylamide and 2-Acrylamido-2-methylpropane Sulfonic Acid Sodium Salt for Preparing Water-Soluble Drag Reduction Additives

  • Macromolecular Compounds and Polymeric Materials
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Abstract

A copolymer of acrylamide (AA) and 2-acrylamido-2-methylpropane sulfonic acid sodium salt (AMPSNa) was prepared by inverse emulsion radical polymerization in the presence of azobisisobutyronitrile initiator. The effect of temperature, initiator, and sum of the monomers on the rate of inverse emulsion copolymerization of acrylamide and AMPSNa was studied by dilatometry. The kinetic parameters of the process were determined, including the effective copolymerization constants, reaction activation energy, reaction rate, and orders with respect to the initiator and monomers. The synthesized AA–AMPSNa copolymer was characterized by IR spectroscopy and elemental analysis. The intrinsic viscosity of the copolymers was determined, and the viscosity-average molecular weight was calculated by the Mark–Kuhn–Houwink equation. The drag reduction was studied by capillary turbulent viscometry. The AA–AMPSNa copolymers can be efficiently used as drag reduction additives to water flows.

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ACKNOWLEDGMENTS

The study was performed using the equipment of the Center for Shared Use for Studies of Materials and Substances, Perm Federal Research Center, Ural Branch, Russian Academy of Sciences.

Funding

The study was financially supported by the Russian Foundation for Basic Research within the framework of research project no. 19-33-90193.

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Authors and Affiliations

  1. Institute of Technical Chemistry, Branch of the Perm Federal Research Center, Ural Branch, Russian Academy of Sciences, 614013, Perm, Russia

    N. S. Voronina, A. I. Nechaev, V. N. Strel’nikov & V. A. Val’tsifer

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  1. N. S. Voronina
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  2. A. I. Nechaev
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  3. V. N. Strel’nikov
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  4. V. A. Val’tsifer
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Correspondence to N. S. Voronina or A. I. Nechaev.

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Additional information

Translated from Zhurnal Prikladnoi Khimii, No. 6, pp. 736–746, January, 2021 https://doi.org/10.31857/S0044461821060086

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Voronina, N.S., Nechaev, A.I., Strel’nikov, V.N. et al. Inverse Emulsion Copolymerization of Acrylamide and 2-Acrylamido-2-methylpropane Sulfonic Acid Sodium Salt for Preparing Water-Soluble Drag Reduction Additives. Russ J Appl Chem 94, 748–757 (2021). https://doi.org/10.1134/S1070427221060082

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