Abstract
Manganese hexacyanoferrate was synthesized by the hydrothermal method and its cubic structure was established. Manganese hexacyanoferrate powder was studied in the composition of a cathode material for sodium-ion batteries with an electronically conductive carbon black additive and a polyvinylidene fluoride binder polymer. The electrochemical properties of manganese hexacyanoferrate-based electrodes in a propylene carbonate solution of sodium perchlorate were investigated by the cyclic voltammetry and charge-discharge curves. The specific capacities of the cathode material and their dependence on the current density were found. The stability of the capacitive characteristics of the material was studied during long-term charge-discharge cycling.
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ACKNOWLEDGMENTS
Scanning electron microscopy studies were carried out using equipment from the RC “Nanotechnology” of the Research Park of St. Petersburg State University. Powder X-ray diffraction studies were performed with the equipment of the RC “X-ray diffraction research methods” of the Research Park of St. Petersburg State University. Thermographic studies were performed at the RC “Thermogravimetric and Calorimetric Research Methods” of the Research Park of St. Petersburg State University.
Funding
This work was carried out with financial support from St. Petersburg State University (grant no. 26455158).
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Translated from Zhurnal Prikladnoi Khimii, No. 6, pp. 811–816, January, 2021 https://doi.org/10.31857/S0044461821060153
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Kamenskii, M.A., Shkreba, E.V., Tolstopyatova, E.G. et al. Synthesis and Study of the Electrochemical Properties of Manganese Hexacyanoferrate as a Cathode Material for Na-Ion Batteries. Russ J Appl Chem 94, 818–823 (2021). https://doi.org/10.1134/S107042722106015X
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DOI: https://doi.org/10.1134/S107042722106015X