Abstract
The effect of hybrid filling of polyethylene terephthalate with short glass fibers in amount from 15 to 60 wt % and multi-walled carbon nanotubes in amount of 0.5 and 1.6 wt % on the structure, static and dynamic mechanical properties of composites produced by blending in a melt by the method of reactive extrusion was studied. It was shown that nanotubes initiate heterophase crystallization of the polymer matrix, which improves the transfer of stresses to the nanofiller and makes the main contribution to the reinforcing of both nano- and hybrid-filled composites. The elastic moduli of cast specimens increase upon stretching by 41–54% for nanocomposites and by 20–30% for hybrid-filled composites, and upon bending, by 5–18 and 16–21% compared to the initial and glass-filled polymer, respectively. It was demonstrated that the magnitude of the reinforcing effect is related to the orientation of the nano- and micro-filler and depends on the specimen production technology and on the test method.
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REFERENCES
Pesetskii, S.C., Polim. Mat. Tekhol., 2015, vol. 1, no. 2, p. 5.
Pesetskii, S.S., Bogdanovich, S.P., and Sodyleva, T.M., Dokl. Nats. Akad. Nauk Belarusi, 2017, vol. 61, no. 2, pp. 74–83.
Pesetskii, S.S., Bogdanovich, S.P., Dubrovskii, V.V., Sodyleva, T.M., Aderikha, V.N., and Usova, V.N., Polim. Mat. Tekhol., 2016, vol. 2, no. 3, pp. 45–57.
Clifford, M.J. and Wan, T.M., Polymer, 2010, vol. 51, pp. 535–539. https://doi.org/10.1016/j.polymer.2009.11.046
Meszaros, L. and Deak, T., Compos. Sci. Technol., 2013, vol. 75, pp. 22–27. https://doi.org/10.1016/j.compscitech.2012.11.013
Pedrazzoli, D. and Pegoretti, A., Compos. Sci. Technol., 2013, vol. 76, pp. 77–83. https://doi.org/10.1016/j.compscitech.2012.12.016
Arao, Y., Yumitori, S., Suzuki, H., Tanaka, T., and Katayama, T., Composites, Part A, 2013, vol. 55, pp. 19–26. https://doi.org/10.1016/j.compositesa.2013.08.002
Asadi, A., Miller, M., Moon, R., and Kalaitzidou, K., eXPRESS Polym. Lett., 2016, vol. 10 (7), pp. 587–597. https://doi.org/10.3144/expresspolymlett.2016.54
Munoz-Vulez, M.F., Valadez-Gonzalez, A., and Herrera-Franco, P.J., eXPRESS Polym. Lett., 2017, vol. 11 (9), pp. 704–718. https://doi.org/10.3144/expresspolymlett.2017.68
Pegoretti, A., Mahmood, H., Pedrazzoli, D., and Kalaitzidou, K., IOP Conf. Ser.: Mater. Sci. Eng., 2016, vol. 139(1), ID 012004. https://doi.org/10.1088/1757-899X/139/1/012004
Dubrovskii, V.V., Aderikha, V.N., Shapovalov, V.A., and Pesetskii, S.S., Dokl. Nats. Akad. Nauk Belarusi, 2018, vol. 62, no. 1, pp. 120–128.
Dubrovsky, V.V., Shapovalov, V.A., Aderikha, V.N., and Pesetskii, S.S., Mater. Today Commun., 2018, vol. 17, pp. 15–23. https://doi.org/10.1016/j.mtcomm.2018.08.002
Pesetskii, S.S., Shevchenko, V.V., and Dubrovsky, V.V., J. Appl. Polym. Sci., 2018, vol. 135, ID 45711. https://doi.org/10.1002/app.45711
Wunderlich, B., Polym. Eng. Sci., 1978, vol. 18(6), pp. 431–436. https://doi.org/10.1002/pen.760180603
Fakirov, S., eXPRESS Polym. Lett., 2020, vol. 14(5), pp. 436–466. https://doi.org/10.3144/expresspolymlett.2020.36
Ma, P.C., Siddiqui, N.A., Marom, G., and Kim, J.K., Composites, Part A, 2010, vol. 41, pp. 1345–1367. https://doi.org/10.1016/j.compositesa.2010.07.003
May-Pat, A., Avilés, F., Toro, P., Yazdani-Pedram, M., and Cauich-Rodríguez, J.V., eXPRESS Polym. Lett., 2012, vol. 6 (2), pp. 96–106. https://doi.org/10.3144/expresspolymlett.2012.11
Mills, N.J., Plastics. Microstructure and Engineering Application, Elsevier, 2005, pp. 129–130. https://doi.org/10.1016/B978-0-7506-5148-6.X5000-4
Xu, J.Z., Zhong, G.-J., Hsiao, B.S., Fua, Q., and Li, Z.-M., Prog. Polym. Sci., 2014, vol. 39, pp. 555–593. https://doi.org/10.1016/j.progpolymsci.2013.06.005
Cruz-Delgado, V.J., Ávila-Orta, C.A., Espinoza-Martínez, A.B., Mata-Padilla, J.M., Solis-Rosales, S.G., Jalbout, A.F., Medellín-Rodríguez, F.J., and Hsiao, B.S., Polymer, 2014, vol. 55, pp. 642–650. https://doi.org/10.1016/j.polymer.2013.12.029
Ning, N., Fu, S., Zhang, W., Chen, F., Wang, K., Deng, H., Zhang, Q., and Fu, Q., Prog. Polym. Sci., 2012, vol. 37, pp. 1425–1455. https://doi.org/10.1016/j.progpolymsci.2011.12.005
Heeley, E.L., Hughes, D.J., Crabb, E.M., Bowen, J., Bikondo, O., Mayoral, B., Leung, S., and McNally, T., Polymer, 2017, vol. 117, pp. 208–219. https://doi.org/10.1016/j.polymer.2017.04.033
Karger-Kocsis, J., Mahmood, H., Pegoretti, A., Prog. Mater. Sci., 2015, vol. 73, pp. 1–43. https://doi.org/10.1016/j.pmatsci.2015.02.003
Choi, N.-S. and Takahashi, K., Handbook of Thermoplastic Polymers: Homo-polymers, Copolymers and Composites, Fakirov, S., Ed., Weinheim: Wiley-VCH Verlag GmbH, 2002. https://doi.org/10.1002/3527601961.ch25a
Gauthier, C., Chailan, J.-F., and Chauchard, J., Die Makromolekulare Chemie, 1992, vol. 193, pp. 1001–1009. https://doi.org/10.1002/macp.1992.021930416
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The work was carried out within the framework of task 6.53 of the state program of scientific research “Physical materials science, new materials and technologies,” subprogram “Polymer materials and technologies” of the National Academy of Sciences of Belarus.
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Translated from Zhurnal Prikladnoi Khimii, No. 6, pp. 758–766, January, 2021 https://doi.org/10.31857/S0044461821060104
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Dubrovskii, V.V., Aderikha, V.N., Pesetskii, S.S. et al. Hybrid Filling of Polyethylene Terephthalate with Multi-Walled Carbon Nanotubes and Short Glass Fibers. Russ J Appl Chem 94, 768–776 (2021). https://doi.org/10.1134/S1070427221060100
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DOI: https://doi.org/10.1134/S1070427221060100