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Two New Ternary Cd(II) Coordination Polymers Containing Bis(thiabendazole) Ligands as Luminescent Sensors for Benzaldehyde and MnO4− Anions

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Abstract

Two new ternary Cd(II) coordination polymers (CPs), [Cd2(L)(mip)2·2H2O]n (1) and {[Cd2(L)(hip)2]·3.5H2O}n (2) (L = 1,4-bis(thiabendazol-1-ylmethyl)benzene, H2mip = 5-methylisophthalic acid, H2hip = 5-hydroxyisophthalic acid), have been synthesized and characterized by physicochemical and spectroscopic methods. 1 possesses a 1D chained structure while 2 exhibits a 2D hcb layer. Both CPs can be further extended into 2D/3D supramolecular frameworks via π–π stacking interactions. Both 1 and 2 can serve as dual-responsive luminescent probes for the selective detection of benzaldehyde (BZH) and permanganate anions (MnO4−) in aqueous system. The limits of detection (LODs) of 1 for BZH and MnO4− are 0.13 µM and 0.21 µM, separately, whereas the LODs of 2 for BZH and MnO4− are 1.30 µM and 1.95 µM, respectively.

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Acknowledgements

This work was developed within the scope of the project CICECO-Aveiro Institute of Materials, UIDB/50011/2020 and UIDP/50011/2020, financed by national funds through the Foundation for Science and Technology/MCTES.

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Authors and Affiliations

  1. College of Chemical Engineering, Hebei Key Laboratory for Environment Photocatalytic and Electrocatalytic Materials, North China University of Science and Technology, No. 21 Bohai Road, Caofeidian new-city, Tangshan, 063210, Hebei, People’s Republic of China

    Na-Na Zeng, Chao Han & Guang-Hua Cui

  2. Department of Physics and CICECO-Aveiro Institute of Materials, University of Aveiro, 3810-193, Aveiro, Portugal

    Lianshe Fu

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  1. Na-Na Zeng
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Correspondence to Guang-Hua Cui.

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Zeng, NN., Han, C., Fu, L. et al. Two New Ternary Cd(II) Coordination Polymers Containing Bis(thiabendazole) Ligands as Luminescent Sensors for Benzaldehyde and MnO4− Anions. J Inorg Organomet Polym 31, 4523–4531 (2021). https://doi.org/10.1007/s10904-021-02086-y

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