Skip to main content
Log in

Simplification of interior latex paint using biopolymer to replace rheological additives and calcium carbonate extender

  • Published:
Journal of Coatings Technology and Research Aims and scope Submit manuscript

Abstract

An interior latex paint was simplified by using soy protein (SP) to replace hydroxyl ethyl cellulose (HEC) thickener, rheological modifier, and calcium carbonate. The rheological and solid-state properties of the latex paints were investigated. The SP paint had similar viscosity characteristics as that of the HEC paint for practical applications. Strain sweep experiments show that the SP paint has less antisettling characteristic compared to the HEC paint. The dispersion structure of the SP paint is less flexible than that of the HEC paint, but has similar strength at large strain. The values of storage moduli at very low frequency indicate both the HEC and SP paints have a long-term stability. The SP paint had a slower recovery rate after high shear compared to the HEC paint, indicating that the SP paint will have better leveling, but slightly more sagging during application. The dried SP paint had a greater storage modulus than the HEC paint under ambient temperature. The SP paint also had a higher glass transition temperature, indicating a greater ability of protein to immobilize polymer latex. The magnitude of G′ shows that the SP paint is more rigid than the HEC paint. The hardness test shows that the SP paint had a greater hardness than the HEC paint.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10

Similar content being viewed by others

References

  1. United States Department of Agriculture Foreign Agriculture Service, “Oilseeds: World Markets and Trade, May 2021.” https://apps.fas.usda.gov/psdonline/circulars/oilseeds.pdf

  2. Bock, J, Siano, DB, Valint, Jr., PL, Pace, SJ, “Structure and Properties of Hydrophobically Associating Polymers.” In: Glass, JE (eds.) Polymers in Aqueous Medias Advances in Chemistry Vol. 223, Chapter 22, pp. 411–424. American Chemical Society, Washington, DC (1989)

  3. Karlson, L, Joabsson, F, Thuresson, K, "Phase Behaviour and Rheology in Water and in Model Paint Formulations Thickened with HM-EHEC: Influence of the Chemical Structure and the Distribution of Hydrophobic Tails." Carbohydr. Polym., 41 35–35 (2000)

    Article  Google Scholar 

  4. Tanaka, R, Meadows, J, Phillips, GO, Williams, PA, “Viscometric and Spectroscopic Studies on the Solution Behaviour of Hydrophobically Modified Cellulosic Polymers.” Carbohydr. Polym., 12 443–459 (1990)

    Article  CAS  Google Scholar 

  5. Bergh, JS, Lundberg, DJ, Glass, JE, "Rheology of Associative Thickener Pigment and Pigmented Commercial Latex Dispersions." Prog. Org. Coat., 17 155–173 (1989)

    Article  CAS  Google Scholar 

  6. LeSota, S, Lewandowski, EW, Schaller, EJ, “Hydrophobically Modified Alkali-Soluble Emulsions as Thickener for Exterior Latex Paint.” In: Glass, JE (eds.) Polymers in Aqueous Medias, Advances in Chemistry, Vol. 223, Chapter 28, pp. 543–549. American Chemical Society, Washington, DC (1989)

  7. Jong, L, "Synergistic Effect of Calcium Carbonate and Biobased Particles for Rubber Reinforcement and Comparison to Silica Reinforced Rubber.” J. Compos. Sci., 4 (3) 113 (2020)

    Article  CAS  Google Scholar 

  8. Beeferman, HC, Bergren, DA, "Practical Applications of Rheology in the Paint Industry." J. Paint Technol., 38 (492) 9–17 (1966)

    CAS  Google Scholar 

  9. Croll, SG, Kisha, LW, "Observations of Sagging in Architectural Paints." Prog. Org. Coat., 20 27–52 (1992)

    Article  CAS  Google Scholar 

  10. Bosma, M, Brinkhuij, R, Coopmans, J, Reuvers, B, "The Role of Sag Control Agents in Optimizing the Sag/Leveling Balance and a New Powerful Tool to Study This." Prog. Org. Coat., 55 97–104 (2006)

    Article  CAS  Google Scholar 

  11. Cohu, O, Magnin, A, "The Levelling of Thixotropic Coatings." Prog. Org. Coat., 28 (2) 89–96 (1996)

    Article  CAS  Google Scholar 

  12. Eley, RR, "Applied Rheology in the Protective and Decorative Coatings Industry, Rheology Reviews." Br. Soc. Rheol., 2005 173–240 (2005)

    Google Scholar 

  13. Smith, NDP, Orchard, SE, Rhind-Tutt, AJ, "The Physics of Brush Marks." J. Oil Chem. Assoc., 44 618–633 (1961)

    CAS  Google Scholar 

  14. Patton, TC, "A New Method for the Viscosity Measurement of Paint in the Settling, Sagging, Levelling and Penetration Shear Rate Range of .001 to 1.0 Reciprocal Seconds, Using a Cone/Plate Spring Relaxation Technique." J. Paint Technol., 38 (502) 656–666 (1966)

    CAS  Google Scholar 

  15. Sarkar, N, Lalk, RH, "Rheological Correlation with the Application Properties of Latex Paints." J. Paint Technol., 46 29–34 (1974)

    CAS  Google Scholar 

  16. Patton, TC, Paint Flow and Pigment Dispersion, 2nd Ed., Chapter 27, pp. 541–545. Wiley, New York (1979)

  17. Pierce, PE, Donegan, VA, "The Rheology and Application Characteristics of Thixotropic Coatings." J. Paint Technol., 38 (492) 1–8 (1966)

    CAS  Google Scholar 

  18. Bhavsar, R, Shreepathi, S, "Evolving Empirical Rheological Limits to Predict Flow-Levelling and Sag Resistance of Waterborne Architectural Paints." Prog. Org. Coat., 101 15–23 (2016)

    Article  CAS  Google Scholar 

  19. Jong, L, "Rubber Composites Reinforced by Soy Spent Flakes." Polym. Int., 54 (11) 1572–1580 (2005)

    Article  CAS  Google Scholar 

  20. Grossman, P, Hino, T, Soane, D, "Dynamic Light-Scattering Studies of Hydroxyethyl Cellulose Solutions Used as Sieving Media for Electrophoretic Separations." J. Chromatogr., 608 79–83 (1992)

    Article  CAS  Google Scholar 

  21. Wang, W, Sande, S, "A Dynamic Light Scattering Study of Hydrogels with the Addition of Surfactant: A Discussion of Mesh Size and Correlation Length." Polym. J., 47 302–310 (2015)

    Article  Google Scholar 

  22. Ibanescu, C, Danu, M, Nanu, A, Lungu, M, Simionescu, BC, "Stability of Dispersed Systems Estimated Using Rheological Oscillatory Shear Tests." Rev. Roum. Chim., 55 (11–12) 933–940 (2010)

    CAS  Google Scholar 

  23. Bhavsar, R, Raj, R, Parmar, R, "Studies of Sedimentation Behavior of High Pigmented Alkyd Primer: A Rheological Approach." Prog. Org. Coat., 76 852–857 (2013)

    Article  CAS  Google Scholar 

  24. Brunel, F, Pochard, I, Gauffinet, S, Turesson, M, Labbez, C, “Structure and Yielding of Colloidal Silica Gels Varying the Range of Interparticle Interactions.” J. Phys. Chem. B, 120 5777–5785 (2016)

    Article  CAS  Google Scholar 

  25. Shih, WY, Shih, WH, Aksay, IA, "Elastic and Yield Behavior of Strongly Flocculated Colloids." J. Am. Ceram. Soc., 82 616–624 (1999)

    Article  CAS  Google Scholar 

  26. Negi, AS, Osuji, C, "New Insights on Fumed Colloidal Rheology-Shear Thickening and Vorticity-Aligned Structures in Flocculating Dispersions." Rheol. Acta., 48 871–881 (2009)

    Article  CAS  Google Scholar 

Download references

Acknowledgment

This work was supported by the US Department of Agriculture, Agricultural Research Service.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Lei Jong.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Mention of trade names or commercial products in this publication is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the US Department of Agriculture. USDA is an equal opportunity provider and employer.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Jong, L. Simplification of interior latex paint using biopolymer to replace rheological additives and calcium carbonate extender. J Coat Technol Res 18, 1603–1612 (2021). https://doi.org/10.1007/s11998-021-00514-9

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11998-021-00514-9

Keywords

Navigation