Abstract
A one-stage gas-phase synthesis of butadiene from formaldehyde and propylene on silica-supported cesium salts of silicotungstic heteropoly acid was realized for the first time. The physicochemical properties of the catalysts were studied by X-ray fluorescence analysis, low-temperature nitrogen adsorption, XRD, SEM, Raman spectroscopy, and NH3–TPD. The coke deposits were studied by the TGA–DTA method. Analysis of the catalytic properties showed that an increase in the concentration of cesium atoms in CsxH4–xSiW12O40/SiO2 (x = 0–3) has a beneficial effect on the endurance of the catalyst but is accompanied by a decrease in activity and butadiene selectivity. In the case of CsH3SiW12O40/SiO2, the butadiene selectivity was 51 mol %.
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Funding
Research on the synthesis of catalysts, their morphology, porous and spectral characteristics, and catalytic properties was financially supported by the Russian Foundation for Basic Research (project no. 20-03-00587-a). Study of the structural features and acid properties of the samples was performed by the state order “Physical Chemistry of Surface, Adsorption, and Catalysis.”
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I.I. Ivanova, a co-author, is the Chief Editor at the Advanced Molecular Sieves Journal. The other co-authors declare no conflict of interest requiring disclosure in this article.
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Ponomareva, О.А., Matveeva, О.D., Nikiforov, A.I. et al. Synthesis of Butadiene from Formaldehyde and Propylene on Cesium Salts of Silicotungstic Heteropoly Acid. Pet. Chem. 61, 916–924 (2021). https://doi.org/10.1134/S0965544121080120
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DOI: https://doi.org/10.1134/S0965544121080120