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Synthesis of Butadiene from Formaldehyde and Propylene on Cesium Salts of Silicotungstic Heteropoly Acid

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Abstract

A one-stage gas-phase synthesis of butadiene from formaldehyde and propylene on silica-supported cesium salts of silicotungstic heteropoly acid was realized for the first time. The physicochemical properties of the catalysts were studied by X-ray fluorescence analysis, low-temperature nitrogen adsorption, XRD, SEM, Raman spectroscopy, and NH3–TPD. The coke deposits were studied by the TGA–DTA method. Analysis of the catalytic properties showed that an increase in the concentration of cesium atoms in CsxH4–xSiW12O40/SiO2 (x = 0–3) has a beneficial effect on the endurance of the catalyst but is accompanied by a decrease in activity and butadiene selectivity. In the case of CsH3SiW12O40/SiO2, the butadiene selectivity was 51 mol %.

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REFERENCES

  1. White, W.C., Chem.-Biol. Inter., 2007, vol. 166, pp. 10– 14. https://doi.org/10.1016/j.cbi.2007.01.009

    Article  CAS  Google Scholar 

  2. Qi, Y., Liu, Z., Gui, L., Dai, Q., He, J., Dong, W., and Bai, Ch., Catalysts, 2019, vol. 1, no. 97, pp. 1–25. https://doi.org/10.3390/catal9010097

    Article  CAS  Google Scholar 

  3. Bedenko, S.P., Dement’ev, K.I., Tret’yakov, V.F., and Maksimov, A.L., Petrol. Chem., 2020, vol. 60, pp. 723–730. https://doi.org/10.1134/S0965544120070026

    Article  CAS  Google Scholar 

  4. Vasiliadou, E.S., Gould, N.S., and Lobo, R.F., ChemCatChem., 2017, vol. 9, pp. 4417–4425. https://doi.org/10.1002/cctc.201701315

    Article  CAS  Google Scholar 

  5. Wang, Y., Wang, F., Song, Q., Xin, Q., Xu, S., and Xu, J., J. Am. Chem. Soc., 2013, vol. 135, pp. 1506–1515. https://doi.org/10.1021/ja310498c

    Article  CAS  PubMed  Google Scholar 

  6. Liakumovich A.G., Akhmed'yanova, R.A., Bogacheva, T.M., Miloslavskii, D.G., Yunusova, L.M., Golovanova, K.V., and Zaboristov, V.N., RF Patent 2561734, 2015.

  7. Kots, P.A., Artsiusheuski, M.A., Grigoriev, Y.V., and Ivanova, I.I., ACS Catal., 2020, vol. 10, pp. 15149– 15161. https://doi.org/10.1021/acscatal.0c03282

    Article  CAS  Google Scholar 

  8. Okuhara, T., Catal. Today, 2002, vol. 73, pp. 167–176. https://doi.org/10.1016/S0920-5861(01)00509-0

    Article  CAS  Google Scholar 

  9. Okuhara, T., Nishimura, T., Watanabe, H., and Misono, M., J. Mol. Catal., 1992, vol. 74, pp. 247–256. https://doi.org/10.1016/0304-5102(92)80242-9

    Article  CAS  Google Scholar 

  10. Matachowski, L., Zięba, A., Zembala, M., and Drelinkiewicz, A., Catal. Lett., 2009, vol. 133, pp. 49–62. https://doi.org/10.1007/s10562-009-0149-y

    Article  CAS  Google Scholar 

  11. Nakato, T., Toyoshi, Y., Kimura, M., and Okuhara, T., Catal. Today, 1999, vol. 52, pp. 23–28. https://doi.org/10.1016/S0920-5861(99)00059-0

    Article  CAS  Google Scholar 

  12. Raveendra, G., Rajasekhar, A., Srinivas, M., Sai Prasad, P.S., and Lingaiah, N., Appl. Catal. A: Gen., 2016, vol. 520, pp. 105–113. https://doi.org/10.1016/j.apcata.2016.04.017

    Article  CAS  Google Scholar 

  13. Pesaresi, L., Brown, D.R., Lee, A.F., Montero, J.M., Williams, H., and Wilson, K., Appl. Catal. A: Gen., 2009, vol. 360, pp. 50–58. https://doi.org/10.1016/j.apcata.2009.03.003

    Article  CAS  Google Scholar 

  14. Songsiria, N., Rempel, G.L., and Prasassarakich, P., Mol. Catal., 2017, vol. 439, pp. 41–49. https://doi.org/10.1016/j.mcat.2017.06.002

    Article  CAS  Google Scholar 

  15. Misono, M., Chem. Commun., 2001, pp. 1141v1152. https://doi.org/10.1039/b102573m

  16. Berry, F.J., Derric, G.R., and Mortimer, M., Polyhedron, 2014, vol. 68, pp. 17–22. https://doi.org/10.1016/j.poly.2013.10.014

    Article  CAS  Google Scholar 

  17. Lwin, S., Li, Y., Frenkel, A.I., and Wachs, I.E., ACS Catal., 2016, vol. 6, pp. 3061–3071. https://doi.org/10.1021/acscatal.6b00389

    Article  CAS  Google Scholar 

  18. Rocchiccioli-Deltcheff, C., Fournier, M., Franck, R., and Thouvenot, R., Inorg. Chem., 1983, vol. 22, pp. 207–216. https://doi.org/10.1021/ic00144a006

    Article  CAS  Google Scholar 

  19. Legagneux, N., Basset, J.-M., Thomas, A., Lefebvre, F., Goguet, A., Sá, J., and Hardacre, C., Dalton Trans., 2009, pp. 2235–2240. https://doi.org/10.1039/B816806G

  20. Ivanova, I.I., Sushkevich, V.L., Kolyagin, Y.G., and Ordomsky, V.V., Angew. Chem., 2013, vol. 52, pp. 12961–12964. https://doi.org/10.1002/anie.201307083

    Article  CAS  Google Scholar 

  21. Ponomareva, O.A., Chistov, D.L., Kots, P.A., Drozhzhin, V.R., Rodionova, L.I, and Ivanova, I.I., Petrol. Chem., 2020, vol. 60, pp. 942–949. https://doi.org/10.1134/S0965544120080125

    Article  CAS  Google Scholar 

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Funding

Research on the synthesis of catalysts, their morphology, porous and spectral characteristics, and catalytic properties was financially supported by the Russian Foundation for Basic Research (project no. 20-03-00587-a). Study of the structural features and acid properties of the samples was performed by the state order “Physical Chemistry of Surface, Adsorption, and Catalysis.”

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Correspondence to О. А. Ponomareva.

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I.I. Ivanova, a co-author, is the Chief Editor at the Advanced Molecular Sieves Journal. The other co-authors declare no conflict of interest requiring disclosure in this article.

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Ponomareva, О.А., Matveeva, О.D., Nikiforov, A.I. et al. Synthesis of Butadiene from Formaldehyde and Propylene on Cesium Salts of Silicotungstic Heteropoly Acid. Pet. Chem. 61, 916–924 (2021). https://doi.org/10.1134/S0965544121080120

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