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Alkylation of Benzene with Propylene on Hierarchical MWW Zeolites Prepared by Recrystallization

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Abstract

The effect of the base type [NaOH, tetramethylammonium hydroxide, and tetrapropylammonium hydroxide] and concentration (3–12 mmol/g) on the formation of mesopores during recrystallization of MWW zeolites was studied. It was shown that with NaOH, cylindrical mesopores are mainly formed, while with tetraalkylammonium hydroxides, slit-like pores. The effect of recrystallization on the catalytic activity of MWW zeolites in benzene alkylation with propylene was studied. It was shown that slit-like mesopores lead to an increase in activity, while cylindrical mesopores only slightly affect the catalytic properties.

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Funding

Synthesis of microporous MWW zeolites and assessment of their catalytic activity in benzene alkylation with propylene were funded by the Russian Science Foundation (project no. 19-73-10160). Analysis of the structure and acidity of hierarchical MWW zeolites were performed in the framework of the state order “Physical Chemistry of Surface, Adsorption, and Catalysis.”

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Correspondence to A. V. Shkuropatov.

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I.I. Ivanova is the Сhief Editor of the journal “Advanced Molecular Sieves.” The other authors declare no conflict of interest requiring disclosure in this article.

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Shkuropatov, A.V., Popov, A.G. & Ivanova, I.I. Alkylation of Benzene with Propylene on Hierarchical MWW Zeolites Prepared by Recrystallization. Pet. Chem. 61, 908–915 (2021). https://doi.org/10.1134/S0965544121080132

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