Abstract
Sodium-tungsten-manganese supported on silica (Na-W-Mn/SiO2) and hydroxyapatite (HAp) are representative catalysts for oxidative coupling of methane (OCM). In this work, the effect of the HAp doping in a Na-W-Mn/SiO2 catalysts on the OCM performance was studied. To enhance the ethylene selectivity of the Na-W-Mn/SiO2 catalyst, silica supports were coated with HAp containing hydroxyl and phosphate groups as oxygen species. A series of Na-W-Mn/xHAp_SiO2 (x=1, 3, 5 and 7) catalysts with the different HAp coating cycles were prepared through the alternative soaking method, and X-ray diffraction (XRD) and scanning electron microscopy (SEM) showed that the amount of HAp doping was dependent on the HAp coating cycles. In addition, the change of oxygen species upon HAp doping was examined with X-ray photoelectron spectroscopy (XPS) and oxygen temperature-programmed desorption (O2-TPD) techniques. With HAp doping, the increase of oxygen species assigned to metal oxide responsible for selective oxidation of methane to ethylene was observed in O 1s XPS spectra. In addition, weakly bound oxygen species were observed with the introduction of HAp doping in O2-TPD profiles of prepared catalysts. The influence of these oxygen species on OCM catalytic performance was evaluated at an operating temperature of 775 °C and gas hourly space velocity of 18,000 ml/gcat·h. The amount of HAp doping provided reactive oxygen species for oxidative dehydrogenation of ethane, which resulted in as much as 120% increase in C2H4/C2H6 ratio over the Na-W-Mn/3HAp_SiO2 catalyst compared to the Na-W-Mn/SiO2 catalyst.
Similar content being viewed by others
References
Y. Kathiraser, Z. Wang and S. Kawi, Environ. Sci. Technol., 47, 14510 (2013).
K. Takanabe, J. Jap. Petrol. Inst., 55, 1 (2012).
P. Schwach, X. Pan and X. Bao, Chem. Rev., 117, 8497 (2017).
R. Horn and R. Schlögl, Catal. Lett., 145, 23 (2015).
P. J. Strong, S. Xie and W. P. Clarke, Environ. Sci. Technol., 49, 4001 (2015).
O. Shtyka, M. Zakrzewski, R. Ciesielski, A. Kedziora, S. Dubkov, R. Ryazanov, M. Szynkowska and T. Maniecki, Korean J. Chem. Eng., 37, 209 (2020).
B. J. Lee, Y. G. Hur, D. H. Kim, S. H. Lee and K.-Y. Lee, Fuel, 253, 449 (2019).
S. H. Lee, J. K. Kang and E. D. Park, Korean J. Chem. Eng., 35, 2145 (2018).
Y. Gambo, A. Jalil, S. Triwahyono and A. Abdulrasheed, J. Ind. Eng. Chem., 59, 218 (2018).
J. Wu, S. Li, J. Niu and X. Fang, Appl. Catal. A: Gen., 124, 9 (1995).
S. Ji, T. Xiao, S. Li, L. Chou, B. Zhang, C. Xu, R. Hou, A. P. York and M. L. Green, J. Catal., 220, 47 (2003).
S.-f. Ji, T.-c. Xiao, S.-b. Li, C.-z. Xu, R.-l. Hou, K. S. Coleman and M. L. Green, Appl. Catal. A: Gen., 225, 271 (2002).
J. Wang, L. Chou, B. Zhang, H. Song, J. Zhao, J. Yang and S. Li, J. Mol. Catal. A: Chem., 245, 272 (2006).
Y. Gordienko, T. Usmanov, V. Bychkov, V. Lomonosov, Z. Fattakhova, Y. Tulenin, D. Shashkin and M. Sinev, Catal. Today, 278, 127 (2016).
Y. T. Chua, A. R. Mohamed and S. Bhatia, Appl. Catal. A: Gen., 343, 142 (2008).
R. T. Yunarti, S. Gu, J.-W. Choi, J. Jae, D. J. Suh and J.-M. Ha, ACS Sustain. Chem. Eng., 5, 3667 (2017).
Q. Yan, Y. Wang, Y. Jin and Y. J. Chen, Catal. Lett., 13, 221 (1992).
A. Malekzadeh, A. Khodadadi, A. Dalai and M. Abedini, J. Nat. Gas Chem., 16, 121 (2007).
S.-H. Lee and K. J. Yoon, Korean J. Chem. Eng., 18, 228 (2001).
G. Keller and M. Bhasin, J. Catal., 73, 9 (1982).
K. Y. Lee, Y. C. Han, D. J. Suh and T. J. Park, Stud. Surf. Sci. Catal., 119, 385 (1998).
S. Arndt, T. Otremba, U. Simon, M. Yildiz, H. Schubert and R. Schomäcker, Appl. Catal. A: Gen., 425–426, 53 (2012).
T. W. Elkins and H. E. Hagelin-Weaver, Appl. Catal. A: Gen., 497, 96 (2015).
C. Uzunoglu, A. Leba and R. Yildirim, Appl. Catal. A: Gen., 547, 22 (2017).
X. Fang, S. Li, J. Lin and Y. Chu, J. Mol. Catal. (China), 6, 427 (1992).
Z. C. Jiang, C. J. Yu, X. P. Fang, S. B. Li and H. L. Wang, J. Phys. Chem., 97, 12870 (1993).
S. Gu, H.-S. Oh, J.-W. Choi, D. J. Suh, J. Jae, J. Choi and J.-M. Ha, Appl. Catal. A: Gen., 562, 114 (2018).
J. H. Park, D.-W. Lee, S.-W. Im, Y. H. Lee, D.-J. Suh, K.-W. Jun and K.-Y. Lee, Fuel, 94, 433 (2012).
D. Kwon, I. Yang, Y. Sim, J.-M. Ha and J. C. Jung, Catal. Comm., 128, 105702 (2019).
K. Y. Lee, M. Houalla, D. M. Hercules and W. K. Hall, J. Catal., 145, 223 (1994).
S. C. Oh, Y. Lei, H. Chen and D. Liu, Fuel, 191, 472 (2017).
I. Kim, G. Lee, H. B. Na, J.-M. Ha and J. C. Jung, Mol. Catal., 435, 13 (2017).
S. Sugiyama and H. Hayashi, Int. J. Mod. Phys. B, 17, 1476 (2003).
K. Suzuki, T. Yumura, M. Mizuguchi, T. Taguchi, K. Sato, J. Tanaka and M. Akashi, J. Sol-Gel Sci. Technol., 21, 55 (2001).
P. Li, I. Kangasniemi, K. De Groot, T. Kokubo and A. Yli-Urpo, J. Non-Cryst. Solids, 168, 281 (1994).
A. Palermo, J. P. H. Vazquez, A. F. Lee, M. S. Tikhov and R. M. Lambert, J. Catal., 177, 259 (1998).
J. Elliott, Structure Chemistry of the Apatites and Other Calcium Orthophosphates: Hydroxyapatite and Nonstoichiometric Apatites, 18, 111 (1994).
M. Domínguez F. Romero-Sarria, M. Centeno and J. Odriozola, Appl. Catal. B: Environ., 87, 245 (2009).
A. Galadima and O. Muraza, J. Ind. Eng. Chem., 37, 1 (2016).
K. Takanabe and E. Iglesia, Angew. Chem. Int. Ed., 120, 7803 (2008).
Acknowledgements
This research was supported by the C1 Gas Refinery Program through the National Research Foundation of Korea (NRF) and funded by the Ministry of Science and ICT (2021M3D3A1A010 22109).
Author information
Authors and Affiliations
Corresponding authors
Rights and permissions
About this article
Cite this article
Lee, B.J., Lee, J.H., Han, GH. et al. Effect of hydroxyapatite-doping in Na-W-Mn/SiO2 catalysts on oxidative coupling of methane. Korean J. Chem. Eng. 38, 1818–1825 (2021). https://doi.org/10.1007/s11814-021-0833-1
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11814-021-0833-1