Abstract
In processing a mixture of petroleum derivatives and coal tar with clinkering coal, the temperature and pressure affect the composition and properties of the product, as here described. Increasing the temperature results in a pitch-like product with considerable coking value (content of coke residue) and high softening temperature. At high pressure (16 atm), the pitch-like product has properties similar to those of carbon binder with low softening temperature. The change in properties of the product is directly related to the aromatic content of its components.
Similar content being viewed by others
REFERENCES
Pérez, M., Granda, M., García, R., et al., Pyrolysis behavior of petroleum pitches prepared at different conditions, J. Anal. Appl. Pyrolysis, 2002, vol. 6, pp. 223–239.
Watanabe, F., Korai, Y., Mochida, I., and Nishimura, Y., Structure of melt-blown mesophase pitch-based carbon fiber, Carbon, 2000, vol. 38, pp. 741–747.
Kumar, S. and Srivastava, M., Meliorate optical textures and mesophase contents by promising approach of deasphalting of petroleum residues, J. Ind. Eng. Chem., 2017, vol. 48, pp. 133–141.
Kim, B.H., Kim, J.H., Kim, J.G., et al., Electrochemical and structural properties of lithium battery anode materials by using a molecular weight controlled pitch derived from petroleum residue, J. Ind. Eng. Chem., 2016, vol. 41, pp. 1–9.
Machado, M.L., Beatty, P.W., Fetzer, J.C., et al., Evaluation of the relationship between PAH content and mutagenic activity of fumes from roofing and paving asphalts and coal tar pitch, Fundam. Appl. Toxicol., 1993, vol. 21, pp. 492–499.
Mannweiler, U.C. and Perruchoud, R.C., Reduction of polycyclic aromatic hydrocarbons (PAH) in anodes by using petroleum pitch as binder material, in Light Metals 1997, Warrendale, PA: Miner., Met. Mater. Soc., 1997, pp. 555–558.
Greinke, R.A. and O’Connor, L.H., Determination of molecular weight distributions of polymerized petroleum pitch by gel permeation chromatography with quinoline eluent, Anal. Chem., 1980, vol. 52, pp. 1877–1884.
Shinohara, K. and Fujimoto, H., The microstructure of highly-oriented graphite tape prepared from mesophase pitch by melt-blowing, Carbon, 2012, vol. 50, pp. 4926–4933.
Perez, M., Granda, M., Santamaria, R., et al., Formulation, structure and properties of carbon anodes from coal tar pitch/petroleum pitch blends, in Light Metals 2003, Warrendale, PA: Miner., Met. Mater. Soc., 2003, vol. 4, pp. 495–501.
Rocha, V.G., Blanco, C., Santamaría, R., et al., Pitch/coke wetting behaviour, Fuel, 2005, vol. 84, pp. 1550–1556.
McHenry, E.R., Coal-tar/petro industrial pitches, in Light Metals 1997, Warrendale, PA: Miner., Met. Mater. Soc., 1997, pp. 543–548.
Wombles, R.H. and Kiser, M.D., Developing coal tar/petroleum pitches, in Light Metals 2000, Warrendale, PA: Miner., Met. Mater. Soc., 2000, pp. 537–541.
Kuznetsov, P.N., Obukhova, A.V., Kuznetsova, L.I., et al., Thermal dissolution of GZh coal in different paste-forming agents, Solid Fuel Chem., 2018, vol. 52, pp. 296–301.
Andrews, R., Rantell, T., Jacques, D., and Hower, J., Mild coal extraction for the production of anode coke from Blue Gem coal, Fuel, 2010, vol. 89, pp. 2640–2647.
Stansberry, P.G. and Zondlo, J.W., Development of binder pitches from coal extract and coal tar pitch blends, in Light Metals 2001, Warrendale, PA: Miner., Met. Mater. Soc., 2001, pp. 581–586.
Yang, J., Stansberry, P., Zondlo, J., and Stiller, A., Characteristics and carbonization behaviors of coal extracts, Fuel Process. Technol., 2002, vol. 79, pp. 205–222.
Suriyapraphadilok, U., Jennis-McGroarty, C., and Andersen, J., Comparison of alternative coal derived binder pitches for carbon materials, Prepr. Pap.-Am. Chem. Soc., Div. Fuel Chem., 2004, vol. 49, p. 636.
Kuznetsov, P.N., Perminov, N.V., Buryukin, F.A., et al., Thermal dissolution of coal in industrial solvents, Coke Chem., 2019, vol. 62, no. 1, pp. 12–17.
Maloletnev, A.S., Gyul’maliev, A.M., and Mazneva, O.A., Chemical composition of the distillate fractions of coal tar from OAO Altai-Koks, Solid Fuel Chem., 2014, vol. 48, no. 1, pp. 11–21.
Shui, H., Zhou, Y., Li, H., et al., Thermal dissolution of Shenfu coal in different solvents, Fuel, 2013, vol. 108, pp. 385–390.
Rahman, M., Samanta, A., and Gupta, R., Production and characterization of ash-free coal from low-rank Canadian coal by solvent extraction, Fuel Process. Technol., 2013, vol. 115, pp. 88–98.
Kuznetsov, P.N., Kamenskii, E.S., Kolesnikova, S.M., et al., Temperature effect on the thermal dissolution of coal, Solid Fuel Chem., 2018, vol. 52, pp. 163–168.
Kuznetsov, P.N., Kuznetsova, L.I., Buryukin, F.A., et al., Methods for the preparation of coal-tar pitch, Solid Fuel Chem., 2015, vol. 49, pp. 213–225.
Krzton, A., Cagniant, D., Gruber, R., et al., Application of Fourier self-deconvolution to the FT-i.r. characterization of coals and their N-methyl 2-pyrrolidinone extraction products, Fuel, 1995, vol. 74, pp. 217–225.
Butuzova, L., Krzton, A., Saranchuk, V., and Isajeva, L., Influence of oxygen on the behavior of oxygen-containing groups of soft coal in pyrolysis, Fuel, 1994, vol. 73, pp. 945–950.
ACKNOWLEDGMENTS
This research made use of equipment at the Krasnoyarsk Regional Collective-Use Center of the Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences.
Funding
State support was provided to the Institute of Chemistry and Chemical Technology, Siberian Branch, Russian Academy of Sciences (project 0287-2021-0014). Financial support was provided to Siberian Federal University by the Russian Foundation for Basic Research (grant 19-53-44001). Finally, financial support was provided to the Institute of Chemistry and Chemical Technology, Mongolian Academy of Sciences, by the Mongolian Foundation for Science and Technology (grant ShUGKh/OKhU/2019/3).
Author information
Authors and Affiliations
Corresponding authors
Additional information
Translated by B. Gilbert
About this article
Cite this article
Safin, V.A., Kuznetsov, P.N., Kositsyna, S.S. et al. Production of Carbon Binders from Petroleum and Coal Derivatives. Coke Chem. 64, 156–162 (2021). https://doi.org/10.3103/S1068364X21040074
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.3103/S1068364X21040074