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Assembly of Three New Co2/Mn5/Co5-Cluster-Based Metal–Organic Frameworks: Syntheses, Structure, Thermal Stability and Magnetic Properties

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Abstract

Three new metal–organic coordination polymers, {[Co2(TDC)2(H-3,3′-pytz)2(μ2-OH)]·4DMF}n (1), [Mn5(NDC)4(3,3′-pytz)(DMF)4(μ3-OH)2]n (2), [Co5(NDC)4(3,3′-pytz)(DMF)4(μ3-OH)2]n (3). (3,3′-pytz = 3,6-bis(3-pyridyl)-1,2,4,5-tetrazine; H-3,3′-pytz = protonated 3,6-bis(3-pyridyl)-1,2,4,5-tetrazine; H2TDC = 2,5-Thiophenedicarboxylic acid; H2NDC = 1,4-naphthalenedicarboxylic acid) were synthesized under hydro-/solvothermal conditions and characterized by techniques of single-crystal X-ray diffraction analysis, elemental analysis, infrared spectra (IR) and thermogravimetric analysis (TGA). The resulting analyses demonstrate that complex 1 displays a rare 3D 8-connected bcu framework with the point symbol of {424·64} based on dinuclear [Co2(μ2-OH)(COO)4] cluster, while complex 2 and 3 possessed a rare 3D 10-connected pentanuclear-cluster-based ile{36·434·53·62}framework. The variable-temperature magnetic susceptibility data show that the complex 1, 2 and 3 exhibit antiferromagnetic interaction.

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Acknowledgements

This work was financially supported by the Scientific Research Foundation for the Introduced Talents of Kunming University of Science and Technology (No.KKSY201507026), the Analysis Testing Fund of Kunming University of Science and Technology (No.2020M20192111072), the Joint Fund of National Natural Science Foundation of China and Yunnan (Grant No.U1502273), and the State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Kunming 650093 (Grant No.CNMRCUKF1606).

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Authors and Affiliations

  1. Faculty of Science, Kunming University of Science and Technology, Kunming, 650500, People’s Republic of China

    Kaiming Wang, Yuqi Liu, Nanhao Jin, Siyu Dai, Yanghua Li, Xinying Wang, Wei Li & Qiang Liu

  2. The State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Kunming, 650093, People’s Republic of China

    Wei Li

  3. Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming, 650093, People’s Republic of China

    Wei Li

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  1. Kaiming Wang
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Wang, K., Liu, Y., Jin, N. et al. Assembly of Three New Co2/Mn5/Co5-Cluster-Based Metal–Organic Frameworks: Syntheses, Structure, Thermal Stability and Magnetic Properties. J Clust Sci 33, 2123–2137 (2022). https://doi.org/10.1007/s10876-021-02129-x

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