Abstract
The paper investigates the effects of the aging of an initial aluminophosphate gel on the formation of intermediate phases and their subsequent crystallization into an AlPO4-11 molecular sieve. It was demonstrated that intermediate aluminophosphates can be deliberately formed either as amorphous or layered phases by varying, from 20 to 140°C, the holding temperature of the aluminophosphate gel with the following composition: 1.0Al2O3·1.0P2O5·1.0DPA·50H2O. The choice of the intermediate aluminophosphate was shown to be a factor of control over the AlPO4-11 morphology and over the characteristics of the secondary porous structure. The paper further suggests the mechanism of AlPO4-11 formation depending on the intermediate phase nature.
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Funding
The study was carried out within the state assignment for the IPC RAS on the topic “Zeolite Materials of Different Structural Types with High Crystallinity and Hierarchical Porous Structure as a New Generation of Catalysts for the Synthesis of Important Petrochemicals,” State Register entry no. AAAA-A19-119022290006-2, and with financial support from the Russian Presidential Scholarship for young researchers and graduate students (SP-3341.2021.1).
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Agliullin, M.R., Kutepov, B.I. Intermediate Aluminophosphates as a Tool of Control over the Morphology and Secondary Porous Structure of AlPO4-11. Pet. Chem. 61, 825–835 (2021). https://doi.org/10.1134/S0965544121080016
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DOI: https://doi.org/10.1134/S0965544121080016