Skip to main content
Log in

Metal–semiconductor interface engineering in layered 2D materials for device applications

  • Published:
Bulletin of Materials Science Aims and scope Submit manuscript

Abstract

The research in the field of layered materials, especially in monolayer and few layer forms, have surged in the past decade owing to their unique properties enabling a new kind of nano-dimensional device architecture. Electrical contacts connecting these materials to the outside circuit play very important role in deciding the device performance. In layered materials, particularly when considering the 2D regime, metal–semiconductor contacts become even more crucial. In this review, we present a comprehensive overview of the importance of metal contacts to 2D materials and discuss about the challenges faced which hinder the ultimate device performance. In particular, we discuss about the recent investigations towards improvement in electronic device performance by engineering the metal–semiconductor interfaces based on 2D semiconductors.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Figure 1
Figure 2
Figure 3
Figure 4
Figure 5

Similar content being viewed by others

References

  1. Novoselov K S, Jiang D, Schedin F, Booth T J, Khotkevich V V, Morozov S V et al 2005 Proc. Natl. Acad. Sci. USA 102 10451

    Article  CAS  Google Scholar 

  2. Castro Neto A H, Guinea F, Peres N M R, Novoselov K S and Geim A K 2009 Rev. Mod. Phys. 81 109

    Article  CAS  Google Scholar 

  3. Balandin A A, Ghosh S, Bao W Z, Calizo I, Teweldebrhan D, Miao F et al 2008 Nano Lett. 8 902

    Article  CAS  Google Scholar 

  4. Wilson J A and Yoffe A D 1969 Adv. Phys. 18 193

    Article  CAS  Google Scholar 

  5. Wang Q H, Kalantar-Zadeh K, Kis A, Coleman J N and Strano M S 2012 Nat. Nanotechnol. 7 699

    Article  CAS  Google Scholar 

  6. Pakdel A, Zhi C Y, Bando Y and Golberg D 2012 Mater. Today 15 256

    Article  CAS  Google Scholar 

  7. Hu Z H, Niu T C, Guo R, Zhang J L, Lai M, He J et al 2018 Nanoscale 10 21575

    Article  CAS  Google Scholar 

  8. Kou L Z, Ma Y D, Sun Z Q, Heine T and Chen C F 2017 J. Phys. Chem. Lett. 8 1905

    Article  CAS  Google Scholar 

  9. Kida T, Doi T and Shimanoe K 2010 Chem. Mater. 22 2662

    Article  CAS  Google Scholar 

  10. Khazaei M, Ranjbar A, Arai M, Sasaki T and Yunoki S 2017 J. Mater. Chem. C 5 2488

    Article  CAS  Google Scholar 

  11. Pang J B, Mendes R G, Bachmatiuk A, Zhao L, Ta H Q, Gemming T et al 2019 Chem. Soc. Rev. 48 72

    Article  CAS  Google Scholar 

  12. Lebegue S and Eriksson O 2009 Phys. Rev. B 79 115409

    Article  CAS  Google Scholar 

  13. Mak K F, Lee C, Hone J, Shan J and Heinz T F 2010 Phys. Rev. Lett. 105 136805

    Article  CAS  Google Scholar 

  14. Wilson J A, Di Salvo F J and Mahajan S 2001 Adv. Phys. 50 1171

    Article  Google Scholar 

  15. Mayorov A S, Gorbachev R V, Morozov S V, Britnell L, Jalil R, Ponomarenko L A et al 2011 Nano Lett. 11 2396

    Article  CAS  Google Scholar 

  16. Han M Y, Ozyilmaz B, Zhang Y B and Kim P 2007 Phys. Rev. Lett. 98 206805

    Article  CAS  Google Scholar 

  17. Li X L, Wang X R, Zhang L, Lee S W and Dai H J 2008 Science 319 1229

    Article  CAS  Google Scholar 

  18. Choi W, Cho M Y, Konar A, Lee J H, Cha G B, Hong S C et al 2012 Adv. Mater. 24 5832

    Article  CAS  Google Scholar 

  19. Kwak J Y, Hwang J, Calderon B, Alsalman H, Munoz N, Schutter B et al 2014 Nano Lett. 14 4511

    Article  CAS  Google Scholar 

  20. Das S, Robinson J A, Dubey M, Terrones H and Terrones M 2015 Annu. Rev. Mater. Res. 45 1

    Article  CAS  Google Scholar 

  21. Choi W, Choudhary N, Han G H, Park J, Akinwande D and Lee Y H 2017 Mater. Today 20 116

    Article  CAS  Google Scholar 

  22. Salvatore G A, Munzenrieder N, Barraud C, Petti L, Zysset C, Buthe L et al 2013 ACS Nano 7 8809

    Article  CAS  Google Scholar 

  23. Varghese S S, Varghese S H, Swaminathan S, Singh K K and Mittal V 2015 Electronics-Switz. 4 651

    Article  CAS  Google Scholar 

  24. Choudhary N, Patel M D, Park J, Sirota B and Choi W B 2016 J. Mater. Res. 31 824

    Article  CAS  Google Scholar 

  25. Radisavljevic B, Whitwick M B and Kis A 2012 Appl. Phys. Lett. 101 059901

    Article  CAS  Google Scholar 

  26. Lee H S, Min S W, Park M K, Lee Y T, Jeon P J, Kim J H et al 2012 Small 8 3111

    Article  CAS  Google Scholar 

  27. Wang H, Yu L L, Lee Y H, Shi Y M, Hsu A, Chin M L et al 2012 Nano Lett. 12 4674

    Article  CAS  Google Scholar 

  28. Fuhrer M S and Hone J 2013 Nat. Nanotechnol. 8 146

    Article  CAS  Google Scholar 

  29. Wang L N, Ma Y, Yang M and Qi Y X 2015 RSC Adv. 5 89059

    Google Scholar 

  30. Firmiano E G D, Rabelo A C, Dalmaschio C J, Pinheiro A N, Pereira E C, Schreiner W H et al 2014 Adv. Energy Mater. 4 1301380

    Article  CAS  Google Scholar 

  31. Kumar A, Asokan K, Kumar V and Singh R 2012 J. Appl. Phys. 112 024507

    Article  CAS  Google Scholar 

  32. Bampoulis P, van Bremen R, Yao Q R, Poelsema B, Zandvliet H J W and Sotthewes K 2017 ACS Appl. Mater. Interfaces 9 19278

    Article  CAS  Google Scholar 

  33. Su J, Feng L P, Zhang Y and Liu Z T 2017 Appl. Phys. Lett. 110 40940

    Google Scholar 

  34. Kim C, Moon I, Lee D, Choi M S, Ahmed F, Nam S et al 2017 ACS Nano 11 1588

    Article  CAS  Google Scholar 

  35. English C D, Shine G, Dorgan V E, Saraswat K C and Pop E 2016 Nano Lett. 16 3824

    Article  CAS  Google Scholar 

  36. Choi M S, Qu D, Lee D, Liu X, Watanabe K, Taniguchi T et al 2014 ACS Nano 8 9332

    Article  CAS  Google Scholar 

  37. Yuan H, Cheng G J, You L, Li H T, Zhu H, Li W et al 2015 ACS Appl. Mater. Interfaces 7 1180

    Article  CAS  Google Scholar 

  38. Radisavljevic B, Radenovic A, Brivio J, Giacometti V and Kis A 2011 Nat. Nanotechnol. 6 147

    Article  CAS  Google Scholar 

  39. Kang J H, Liu W, Sarkar D, Jena D and Banerjee K 2014 Phys. Rev. X 4 031005

    CAS  Google Scholar 

  40. Guo Y Z, Liu D M and Robertson J 2015 ACS Appl. Mater. Interfaces 7 25709

    Article  CAS  Google Scholar 

  41. Farmanbar M and Brocks G 2016 Phys. Rev. B 93 085304

    Article  CAS  Google Scholar 

  42. Smyth C M, Addou R, McDonnell S, Hinkle C L and Wallace R M 2016 J. Phys. Chem. C 120 14719

    Article  CAS  Google Scholar 

  43. Lince J R, Carre D J and Fleischauer P D 1987 Phys. Rev. B 36 1647

    Article  CAS  Google Scholar 

  44. Yoon H S, Joe H E, Kim S J, Lee H S, Im S, Min B K et al 2015 Sci. Rep.-UK 5 10440

    Article  Google Scholar 

  45. Tung R T 2014 Appl. Phys. Rev. 1 011304

    Article  CAS  Google Scholar 

  46. Das S, Chen H Y, Penumatcha A V and Appenzeller J 2013 Nano Lett. 13 100

    Article  CAS  Google Scholar 

  47. Maurel C, Coratger R, Ajustron F, Beauvillain J and Gerard P 2003 J. Appl. Phys. 94 1979

    Article  CAS  Google Scholar 

  48. Gourmelon E, Bernede J C, Pouzet J and Marsillac S 2000 J. Appl. Phys. 87 1182

    Article  CAS  Google Scholar 

  49. Kim G S, Kim S H, Park J, Han K H, Kim J and Yu H Y 2018 ACS Nano 12 6292

    Article  CAS  Google Scholar 

  50. Li H-M, Lee D-Y, Choi M S, Qu D, Liu X, Ra C-H et al 2014 Sci. Rep.-UK 4 4041

    Article  CAS  Google Scholar 

  51. Townsend N J, Amit I, Craciun M F and Russo S 2018 2D Mater. 5 025023

    Article  CAS  Google Scholar 

  52. Sotthewes K, Bremen R V, Dollekamp E, Boulogne T, Nowakowski K, Kas D et al 2019 J. Phys. Chem. C 123 5411

    Article  CAS  Google Scholar 

  53. Fang H, Chuang S, Chang T C, Takei K, Takahashi T and Javey A 2012 Nano Lett. 12 3788

    Article  CAS  Google Scholar 

  54. Fang H, Tosun M, Seol G, Chang T C, Takei K, Guo J et al 2013 Nano Lett. 13 1991

    Article  CAS  Google Scholar 

  55. Du Y, Liu H, Neal A T, Si M and Ye P D 2013 IEEE Electron Device Lett. 34 10

    Article  CAS  Google Scholar 

  56. Kiriya D, Tosun M, Zhao P, Kang J S and Javey A 2014 J. Am. Chem. Soc. 136 7853

    Article  CAS  Google Scholar 

  57. Yang L, Majumdar K, Liu H, Du Y, Wu H, Hatzistergos M et al 2014 Nano Lett. 14 6275

    Article  CAS  Google Scholar 

  58. Kappera R, Voiry D, Yalcin S E, Branch B, Gupta G, Mohite A D et al 2014 Nat. Mater. 13 1128

    Article  CAS  Google Scholar 

  59. Zhu J, Wang Z, Yu H, Li N, Zhang J, Meng J et al 2017 J. Am. Chem. Soc. 139 10216

    Article  CAS  Google Scholar 

  60. Cho S, Kim S, Kim J H, Zhao J, Seok J, Keum D H et al 2015 Science 349 625

    Article  CAS  Google Scholar 

  61. Song S, Keum D H, Cho S, Perello D, Kim Y and Lee Y H 2016 Nano Lett. 16 188

    Article  CAS  Google Scholar 

  62. Du Y, Yang L, Zhang J, Liu H, Majumdar K, Kirsch P D et al 2014 IEEE Electron Device Lett. 35 599

    Article  CAS  Google Scholar 

  63. Chuang H J, Chamlagain B, Koehler M, Perera M M, Yan J, Mandrus D et al 2016 Nano Lett. 16 1896

    Article  CAS  Google Scholar 

  64. Wang J, Yao Q, Huang C W, Zou X, Liao L, Chen S et al 2016 Adv. Mater. 28 8302

    Article  CAS  Google Scholar 

  65. Khan M A, Rathi S, Lee C, Lim D, Kim Y, Yun S J et al 2018 ACS Appl. Mater. Interfaces 10 23961

    Article  CAS  Google Scholar 

  66. Park W, Kim Y, Lee S K, Jung U, Yang J H, Cho C et al 2014 IEEE Int. Electron Devices Meet. https://doi.org/10.1109/IEDM.2014.7046986

  67. Dankert A, Langouche L, Kamalakar M V and Dash S P 2014 ACS Nano 8 476

    Article  CAS  Google Scholar 

  68. Smithe K K H, English C D, Suryavanshi S V and Pop E 2016 2D Mater. 4 011009

    Article  CAS  Google Scholar 

  69. Smyth C M, Addou R, McDonnell S, Hinkle C L and Wallace R M 2017 2D Mater. 4 025084

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Monika Moun.

Additional information

This article is part of the special issue on ‘Quantum Materials and Devices’.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Moun, M., Singh, R. Metal–semiconductor interface engineering in layered 2D materials for device applications. Bull Mater Sci 44, 223 (2021). https://doi.org/10.1007/s12034-021-02512-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s12034-021-02512-4

Keywords

Navigation