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CHEMICAL RECYCLING

Low strain, more gain

Nature Chemistry volume 13, pages 719–721 (2021)Cite this article

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Recycling polymers to their monomers would enable a circular polymer economy, but this can be challenging, especially for materials with all-carbon backbones. Now, by lowering the strain of cyclooctene through ring fusion, recyclable polymers with useful physical properties can be made by an olefin-metathesis-based route.

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Fig. 1: Dihedral angle distortion drives ring strain energy.
Fig. 2: Mechanical properties.

References

  1. The New Plastics Economy: Rethinking The Future of Plastics & Catalysing Action. (Ellen MacArthur Foundation, 2017); https://www.ellenmacarthurfoundation.org/publications/the-new-plastics-economy-rethinking-the-future-of-plastics-catalysing-action

  2. Parker, L. Global treaty to regulate plastic pollution gains momentum. National Geographic https://www.nationalgeographic.com/environment/article/global-treaty-to-regulate-plastic-pollution-gains-momentum (2021).

  3. Kosloski-Oh, S. C., Wood, Z. A., Manjarrez, Y., de los Rios, J. P. & Fieser, M. E. Mater. Horiz. 8, 1084–1129 (2021).

    Article  CAS  Google Scholar 

  4. Vollmer, I. et al. Angew. Chem. Int. Ed. 59, 15402–15423 (2020).

    Article  CAS  Google Scholar 

  5. Coates, G. W. & Getzler, Y. D. Y. L. Nat. Rev. Mater. 5, 501–516 (2020).

    Article  CAS  Google Scholar 

  6. Sathe, D. et al. Nat. Chem. https://doi.org/10.1038/s41557-021-00748-5 (2021).

  7. Martinez, H., Ren, N., Matta, M. E. & Hillmyer, M. A. Polym. Chem. 5, 3507–3532 (2014).

    Article  CAS  Google Scholar 

  8. Neary, W. J. & Kennemur, J. G. ACS Macro Lett. 8, 46–56 (2019).

    Article  CAS  Google Scholar 

  9. Scherman, O. A., Walker, R. & Grubbs, R. H. Macromolecules 38, 9009–9014 (2005).

    Article  CAS  Google Scholar 

  10. Hsu, T.-G. et al. J. Am. Chem. Soc. 142, 2100–2104 (2020).

    Article  CAS  Google Scholar 

  11. Fagnani, D. E. et al. ACS Macro Lett. 10, 41–53 (2021).

    Article  CAS  Google Scholar 

  12. Vora, N. et al. Sci. Adv. 7, eabf0187 (2021).

    Article  CAS  Google Scholar 

  13. Christensen, P. R., Scheuermann, A. M., Loeffler, K. E. & Helms, B. A. Nat. Chem. 11, 442–448 (2019).

    Article  CAS  Google Scholar 

Download references

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  1. Twitter: @GetzlerChem

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  1. Department of Chemistry, Kenyon College, Gambier, OH, USA

    Yutan Getzler

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  1. Yutan Getzler
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Correspondence to Yutan Getzler.

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Getzler, Y. Low strain, more gain. Nat. Chem. 13, 719–721 (2021). https://doi.org/10.1038/s41557-021-00759-2

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