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Optimization of basic magenta adsorption onto Fe/Cu nanocomposites synthesized by sweet potato leaf extract using response surface methodology

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Abstract

Green synthesis of metal nanoparticles using plant extracts as an effective bio-reducing reagent has attracted considerable attention. Fe/Cu nanocomposites synthesized by extracts of sweet potato leaves served to remove basic magenta (BM) from aqueous solution. The adsorption operation conditions of BM on Fe/Cu nanocomposites were optimum by Box-Behnken design (BBD) model of response surface methodology (RSM). The adsorption equilibrium data were well described by the Sips and Redlich-Peterson models. The thermodynamic studies showed that the adsorption process was endothermic and spontaneous. The maximum adsorption capacity from the Sips model was 235.92 mg/g at 298 K, which indicated that Fe/Cu nanocomposites had potential application in wastewater treatment. As indicated by pseudo-second order kinetics model, the adsorption of BM onto Fe/Cu nanocomposites could be achieved through the complexation, H-bonding, π-π adsorbate-adsorbent interaction, and electrostatic interaction at different pH values.

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Acknowledgements

This project is funded by the Program of Processing and Efficient Utilization of Biomass Resources of Henan Center for Outstanding Overseas Scientists (No. GZS2018004) and Science and Technology Department of Henan Province (No. 162102210002).

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  1. These authors contributed equally to this work.

Authors and Affiliations

  1. School of Chemical Engineering, Zhengzhou University, Zhengzhou, 450001, China

    Yuanyuan Niu, Ruijuan Jia, Chenglin Liu, Xiuli Han, Chun Chang & Junying Chen

  2. Henan Center for Outstanding Overseas Scientists, Zhengzhou, 450001, China

    Xiuli Han, Chun Chang & Junying Chen

Authors
  1. Yuanyuan Niu
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  2. Ruijuan Jia
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  3. Chenglin Liu
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  4. Xiuli Han
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  5. Chun Chang
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  6. Junying Chen
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Correspondence to Xiuli Han.

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Niu, Y., Jia, R., Liu, C. et al. Optimization of basic magenta adsorption onto Fe/Cu nanocomposites synthesized by sweet potato leaf extract using response surface methodology. Korean J. Chem. Eng. 38, 1556–1565 (2021). https://doi.org/10.1007/s11814-021-0828-y

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  • DOI: https://doi.org/10.1007/s11814-021-0828-y

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