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Geochemical assessment of metal contamination in Manora picnic point sediment core from Karachi coast, Pakistan

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Abstract

This study is focused on the metals’ pollution level in sediment core collected from Manora Picnic Point of Karachi coastal area Pakistan. The sediment was categorized in terms of pH, particle size, total organic carbon (TOC), calcium carbonate, and heavy metals, besides the determining the mineralogy composition of sediment. Metals were determined using proton-induced X-ray emission spectroscopy (PIXE) technique. The results of abundant and heavy metals in the sediment core indicated a significant upward enrichment, which could be the cause of discharge of industrial effluents and domestic wastewaters of Metropolitan Karachi into sea. The average geo-accumulation index values showed that sediments were moderately polluted with Co and Pb, and unpolluted for metals (Al, Ca Mg, Cr, Cu, Fe, K, Mn, Ni, Ti, V, and Zn). The pollution load index values indicate an increasing trend from bottom to top, which may be due to the influence of anthropogenic sources. According to the sediment quality guidelines of United States Environmental Protection Agency (USEPA), core sediment was heavily polluted with Ni and moderately polluted with Pb, Cu and Zn.

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References

  • Aitchison J (1986) The statistical analysis of compositional data. Chapman and Hall, London-New York, p 416

    Book  Google Scholar 

  • Allison LE (1965) Organic carbon. In: Black CA, Evans DD, White JL, Enisminger LE, Clark FE (eds) Methods of soil analysis. American Society of Agronomy, Wisconsin, pp 1372–1378

    Google Scholar 

  • Al-Saad HT, Mostafa YZ, Al-Imarah FJ (1997) Distribution of trace metals in tissues of fish from Shatt Al-Arab Estuary, Iraq. Mesoamerican Reef 11:15–25

    Google Scholar 

  • Anitha G, Kumar SP (2014) Environmental geochemistry of elements in a sediment core off Thengapattanam estuary, south west coastal zone, Tamilnadu, India. Int J Res Chem Environ 4(1):12–24

    Google Scholar 

  • Aprile FM, Bouvy M (2008) Distribution and enrichment of heavy metals in sediment at the Tapacura River Basin, North eastern Brazil. Braz J Aquat Sci Tech 12(1):1–8

    Article  Google Scholar 

  • Bano F (1999) A study of physical and major chemical constituents of Malir river (within Karachi) to determine the extent of pollution, PhD thesis, Karachi University, pp 1–4.

  • Baptista Neto JA, Smith BJ, McAllister JJ (2000) Heavy metal concentrations in surface sediment in a nearshore environment, Jurujuba Sound, Southeast Brazil. Environ Pollut 109(1):1–9

    Article  Google Scholar 

  • Beiras R, Bellas J, Fernandez N, Lorenzo JI, Cobela-Garcia A (2003) Assessment of coastal marine pollution in Galicia (NW Iberian Peninsula) metal concentrations in seawater, sediment and mussels (Mytilus galloprovincialis) verus embryo-larval bioassays using Paracentrotus lividus and Ciona intestinalis. Mar Environ Res 56:531–553

    Article  Google Scholar 

  • Birch G (2003) A scheme for assessing human impacts on costal aquatic environments using sediment. In: Woodcoffee CD, Furness RA (eds) Costal GIS. Wollongong University papers in Center for Maritime Policy, Australia

    Google Scholar 

  • Brown G, Brindly GW (1984) X-ray diffraction procedures for clay mineral identification. In: Brown B (ed) Crystal structure of clay minerals and their X-ray identification, vol 5. Minerological Society, London, pp 305–360

  • Bryan G, Langston W (1992) Bioavailability, accumulation and effects of heavy metals in sediments with special reference to United Kingdom estuaries: a review. Environ Pollut 76(2):89–131

    Article  Google Scholar 

  • Caccia VG, Millero FJ, Palanques A (2003) The distribution of trace metals in Florida Bay sediment. Mar Pollut Bull 46:1420–1433

    Article  Google Scholar 

  • Cardoso A, Boaventura G, Silva E, Brod J (2001) Metal distribution in sediment from the Ribiera bay, Rio de Janeiro—Brazil. J Braz Chem Soc 12(6):767–774

    Article  Google Scholar 

  • Chaudhary MZ, Ahmad N, Mashiatullah A, Munir S, Javed T (2013a) Assessment of metals concentration and ecotoxicology of the sediment core of Rehri creek, Karachi coast–Pakistan. Acta Geol Sin-Engl 87(5):1434–1443

    Article  Google Scholar 

  • Chaudhary MZ, Ahmad N, Mashiatullah A, Ahmad N, Ghaffar A (2013b) Geochemical assessment of metal concentrations in sediment core of Korangi Creek along Karachi Coast, Pakistan. Environ Monit Assess 185:6677–6691

    Article  Google Scholar 

  • Chaudhary MZ, Ahmad N, Mashiatullah A, Javed T, Yaqoob N, Robab U, Khan MS, Abid J (2021a) Sediment accumulation rates in Karachi coastal area Pakistan using 210Pb dating method. J Radioanal and Nucl Chem 327(1):13–20

    Article  Google Scholar 

  • Chaudhary MZ, Ahmad N, Mashiatullah A, Yaqoob N, Robab U (2021b) Metal contamination in Sunairi Point sediment core along Karachi Coast, Pakistan. J Radioanal and Nucl Chem 328(2):605–615. https://doi.org/10.1007/s10967-021-07666-3

    Article  Google Scholar 

  • Ekwere SJ (1992) Geochemical studies of sediments in Qua Iboe estuary associated creeks, south eastern Nigeria. Trop Jo Appl Sci 2:91–95

    Google Scholar 

  • Ergin M, Saydam C, Basturk O, Erdem E, Yoruk R (1991) Heavy metal concentrations in surface sediment from the two coastal inlets (Golden Horn Estuary and Izmit Bay) of the north eastern Sea of Marmara. Chem Geol 91(3):269–285

    Article  Google Scholar 

  • Folk RL, Ward WC (1957) Brazos river bar: a study in the significance of grain size parameters. J Sediment Petrol 27(1):3–27

    Article  Google Scholar 

  • GESAMP (2001) IMO/FAO/UNESCO/WHO/WMO/IAEA/ UNDP joint group of experts on the scientific aspects of marine pollution (GESAMP): reports and studies no. 71, protecting the oceans from land-based activities, land base sources and activities affecting the quality and uses of the marine, coastal and associated freshwater environment.

  • Ghaffar A, Tabata M, Nishimoto J (2010) A history of metal accumulation at kawazoe area of Ariake Bay, Japan. Elec J Env Agricult Food Chem 9(2):369–384

    Google Scholar 

  • Goldberg ED (1992) Marine metal pollutants. A small set. Mar Pollut Bull 14:45–47

    Article  Google Scholar 

  • Hakanson L (1980) Ecological risk index for aquatic pollution control. A sedimentological approach. Water Res 14(5):975–1001

    Article  Google Scholar 

  • Hasnie FR, Qureshi NA (2002) Quantification of pollution load in wastewater channels of village Rehri draining in to Korangi Creek. J Pak Steel Res 3:47–54

    Google Scholar 

  • Jain CK, Singhal DC, Sharma MK (2005) Metal pollution assessment of sediment and water in the river—Hindon, Indian Environ. Monit Assess 105:193–207

    Article  Google Scholar 

  • Jones B, Turki A (1997) Distribution and speciation of heavy metals in surficial sediment from the Tees Estuary, north-east England. Mar Pollut Bull 34:768–779

    Article  Google Scholar 

  • Karbassi AR, Nabi-Bidhendi GR, Bayati I (2005) Environmental geochemistry of heavy metals in a sediment core off Bushehr, ersian Gulf. Iran. J Environ Health Sci Eng 2:255–260

    Google Scholar 

  • Keil RG, Montlucon DB, Prahl FR, Hedges JI (1994) Sorptive preservation of labile organic matter in marine sediment. Nature 370:549–552

    Article  Google Scholar 

  • Krishna K, Mohan KR, Murthy NN (2011) A multivariate statistical approach for monitoring of heavy metals in sediment: a case study from wailpalli watershed, Nalgonda District, Andhra Pradesh, India. Environ Earth Sci 3(2):103–113

    Google Scholar 

  • Kumar SP, Edward JKP (2009) Assessment of metal concentration in the sediment cores of Manakudy estuary, south west coast of India. Indian J Mar Sci 38(2):235–248

    Google Scholar 

  • Langston W (1990) Toxic effects of metals and incidence of marine ecosystems. In: Furness RW, Rainbow PS (eds) Heavy metals in the marine environment. CRC Press, New York

    Google Scholar 

  • Lina F, Nayak GN, Ilangovan D (2012) Geochemical assessment of metal concentrations in mangrove sediment along Mumbai coast India. World Acad Sci Eng Technol 61:258–263

    Google Scholar 

  • Loring DH, Rantala RTT (1992) Manual for the geochemical analyses of marine sediment and suspended particulate matter. Earth-Sci Rev 32:235–283

    Article  Google Scholar 

  • Martin WR, Sayles FL (1996) CaCO3 dissolution in sediments of the Ceara Rise, western equatorial pacific. Geochim Cosmochim Acta 60:243–263

    Article  Google Scholar 

  • Mashiatulla A, Chaudhary MZ, Ahmad N, Qureshi RM, Javed T, Ghaffar A, Khan MS (2011) Metal pollution assessment in sediment of Karachi Coast, Pakistan. The Nucleus 48(3):223–230

    Google Scholar 

  • Mashiatullah A, Qureshi RM, Ahmad N, Khalid F, Javed T (2009) Physico-chemical and biological water quality of Karachi coastal water. The Nucleus 46(1–2):53–59

    Google Scholar 

  • Mashiatullah A, Chaudhary MZ, Ahmad N, Ahmad N, Javed T, Ghaffar A (2015) Geochemical assessment of metal pollution and ecotoxicology in sediment cores along Karachi coast Pakistan. Environ Monit Assess 187:249–264

    Article  Google Scholar 

  • Mucha AP, Vasconcelos MTSD, Bordalo AA (2003) Macrobenthic community in the Doura estuary: relations with trace metals and natural sediment characteristics. Environ Pollut 121(2):169–180

    Article  Google Scholar 

  • Muller G (1969) Index of geo-accumulation in sediment of the Rhine River. Geol J 2(3):108–118

    Google Scholar 

  • Nergis Y, Sharif M, Farooq Choudhry A, Hussain A, Butt AJ (2012) Impact of industrial and sewage effluents on Karachi coastal water and sediment quality, middle-east. J Sci Res 11(10):1443–1454

    Google Scholar 

  • Nour HES (2019) Distribution ecological risk, and source analysis of heavy metal in recent beach sediments of Sharm El—Sheikh, Egypt. Environ Monit Assess 191:546

    Article  Google Scholar 

  • Pederson F, Bjorestad E, Anderson HV, Kjolholt J, Poll C (1998) Characterization of sediment from Copenhagen harbour by use of biotests. Water Sci Technol 37(6–7):233–240

    Article  Google Scholar 

  • Perin G, Bonardi M, Fabris R, Simoncini B, Manente S, Tosi L, Scotto S (1997) Heavy metal pollution in central Venice Lagoon bottom sediments, evaluation of the metal bioavailability by geochemical speciation procedure. Environ Technol 18:593–604

    Article  Google Scholar 

  • Rahman MS, Molla AH, Saha N, Rahman A (2012) Study on heavy metals levels and its risk assessment in some edible fishes from Bangshi River, Savar, Dhaka. Bangladesh Food Chem 134(4):1847–1854

    Article  Google Scholar 

  • Rajeshkumar S, Li X (2018) Bioaccumulation of heavy metals in fish species from the Meiliang Bay, Taihu Lake, China. Toxicol Rep 5:288–295

    Article  Google Scholar 

  • Ramirez M, Serena M, Frache R, Correa J (2005) Metal speciation and environmental impact on sandy beaches due to El Salvador copper mine. Chile Mar Pollut Bull 50:62–72

    Article  Google Scholar 

  • Rashed M (2001) Monitoring of environmental heavy metals in fish from Nasser Lake. Environ Int 27(1):27–33

    Article  Google Scholar 

  • Rizvi SHN, Saleem M, Baquer J (1988) Steel mill effluents: influence on the Bakran Creek environment. In: Thompson MF, Tirmizi NM (eds) Proceedings of marine science of the Arabian Sea. American institutes of biological sciences, Washington DC, pp 549–569

    Google Scholar 

  • Saleem M, Kazi GH (1998) Concentration and distribution of heavy metals (lead, cadmium, copper, nickel, zinc) in Karachi shore and off shore sediment. Pak J Mar Sci 7:71–79

    Google Scholar 

  • Saleem S, Mashiatullah A, Asma M, Yaqoob N, Khan MS (2015) Radiological risk assessment to marine biota along Manora channel Karachi Coast-Pakistan. IJEE 6(3):212–216

    Google Scholar 

  • Siddique A, Mumtaz M, Zaigham NA, Mallick KA, Saied S, Zahir E, Khwaja HA (2009) Heavy metal toxicity levels in the coastal sediment of the Arabian Sea along the urban Karachi (Pakistan) region. Baseline/ Mar Pollut Bull 58:1406–1419

    Article  Google Scholar 

  • Singh JK, Kumar P, Kumar R (2020) Ecological risk assessment of heavy metal contamination in mangrove forest sediment of Gulf of Khambhat region, West Coast of India. SN Appl Sci 2:1–11. https://doi.org/10.1007/s42452-020-03890-w

  • Sulieman HMA, Suliman EM (2019) Appraisal of heavy metal levels in some marine organisms gathered from the Vellar and Uppanar estuaries Southeast Coast of Indian Ocean. J Taibah Univ Sci 13(1):338–343

    Article  Google Scholar 

  • Szefer P, Szefer K, Hallera GJ, Glasby GP, Pempkowsak J, Kaliszan R (1996) Heavy metal pollution in surficial sediment from the Southern Baltic Sea of Poland. J Environ Sci Health Part A 33:2723–2754

    Google Scholar 

  • Tam NFY, Wong YS (2000) Spatial variation of heavy metals in surface sediment of Hong Kong mangrove swamps. Environ Pollut 110(2):195–205

    Article  Google Scholar 

  • Tomilson DC, Wilson DJ, Harris CR, Jeffrey DW (1980) Problems in the assessment of heavy metal levels in estuaries and the formation of a pollution index. Helgol Mar Res 33(1–4):566–575

    Google Scholar 

  • Turekian KK, Wedepohl KH (1961) Distribution of the elements in some major units of the earth’s crust. Geol Soc Am Bull 72(2):175–192

    Article  Google Scholar 

  • Uwah IE, Dan SF, Etiuma RA, Umoh UE (2013) Evaluation of status of heavy metals pollution of sediment in Qua-Iboe River estuary and associated creeks, south-eastern Nigeria, Environment and Pollution 2, No. 4. Canadian Center of Science and Education, pp 110–122. https://doi.org/10.5539/ep.v2n4p110

  • Veerasingam S, Venkatachalapathy R, Ramkumar T (2012) Heavy metals and ecological risk assessment in marine sediment of Chennai, India. Carpathian J Earth Environ Sci 7(2):111–124

    Google Scholar 

  • Veerasingam S, Venkatachalapathy R, Ramkumar T (2014) Distribution of clay minerals in marine sediment off Chennai, Bay of Bengal, India: indicators of sediment sources and transport processes. Int J Sedim Res 29:11–23

    Article  Google Scholar 

  • Venkatachalapathy R, Veerasinga S, Basavaiah N, Ramkumar T, Deenadayalan K (2011) Environmental magnetic and petroleum hydrocarbons records in sediment cores from the north east coast of Tamilnadu, Bay of Bengal, India. Mar Pollut Bull 62:681–690

    Article  Google Scholar 

  • Wedepohl KH (1995) The composition of continental crust. Geochim Cosmochim Acta 59:1217–1233

    Article  Google Scholar 

  • Yousif RA, Masyamsir D, Sunarto Z (2016) Assessment the levels of heavy metals and water quality in Cikuda River, Indonesia. Glob J Bio-Sci Biotechnol 5(2):240–244

    Google Scholar 

  • Zaigham NA (2004) Unauthorized squatter settlements are one of major sources for polluting surface and subsurface waters in Karachi. In: Proceedings of the WSSD workshop on human settlement and environment (Pakistan’s response to its obligations under the WSSD plan of implementation), Islamabad, December 14–15, pp 100–112.

  • Zar JH (1996) Bio statistical analysis, 3rd edn. Prentice-Hall, NJ, USA

    Google Scholar 

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Acknowledgements

The authors are highly thankful to Head IAD, Director Technology and Director General PINSTECH for providing financial support to conduct this research work.

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Correspondence to Muhammad Zaman Chaudhary.

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Chaudhary, M.Z., Ahmad, N., Yaqoob, N. et al. Geochemical assessment of metal contamination in Manora picnic point sediment core from Karachi coast, Pakistan. Environ Earth Sci 80, 475 (2021). https://doi.org/10.1007/s12665-021-09776-3

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