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Condensation of Diamantan-3-one with Malononitrile and Methyl and Ethyl Cyanoacetates in the Presence of Binder-Free FeHY and NiHy Zeolites

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Abstract

Binder-free iron- and nickel-containing micro-, meso-, and macroporous zeolites FeHY and NiHY were found to effectively catalyze Knoevenagel condensation of diamantan-3-one with malononitrile, methyl cyanoacetate, and ethyl cyanoacetate at 40°C (5 h) with 94–98% yield.

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ACKNOWLEDGMENTS

This study was performed in the framework of state assignment of the Ministry of Science and Higher Education of the Russian Federation (project no. AAAA-A19119022290009-3). Structural studies of compounds 3a, 4b, 4c, 5b, and 5c were performed using the facilities of the Agidel joint center (Institute of Petrochemistry and Catalysis, Ufa Research Center, Russian Academy of Sciences; project no. AAAA-A19-119022290004-8).

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Authors and Affiliations

  1. Institute of Petrochemistry and Catalysis, Ufa Federal Research Center, Russian Academy of Sciences, 450075, Ufa, Russia

    R. I. Khusnutdinov, N. A. Shchadneva, Yu. Yu. Mayakova & R. I. Aminov

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  1. R. I. Khusnutdinov
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  2. N. A. Shchadneva
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  3. Yu. Yu. Mayakova
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  4. R. I. Aminov
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Correspondence to R. I. Khusnutdinov.

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Translated from Zhurnal Organicheskoi Khimii, 2021, Vol. 57, No. 6, pp. 877–881 https://doi.org/10.31857/S0514749221060100.

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Khusnutdinov, R.I., Shchadneva, N.A., Mayakova, Y.Y. et al. Condensation of Diamantan-3-one with Malononitrile and Methyl and Ethyl Cyanoacetates in the Presence of Binder-Free FeHY and NiHy Zeolites. Russ J Org Chem 57, 950–953 (2021). https://doi.org/10.1134/S1070428021060105

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