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Diazotization of Aminopyridines in the Presence of Camphorsulfonic Acid. Synthesis and Some Properties of Pyridinyl Camphorsulfonates

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Abstract

Diazotization of 2-, 3-, and 4-aminopyridines in the presence of both racemic camphor-10-sulfonic acid and its pure enantiomers led to the formation of the corresponding pyridyl camphorsulfonates in moderate yields. Pyridyl camphorsulonates were found to be more reactive in alkaline alcoholysis than analogous pyridyl trifluoromethanesulfonates and pyridyl p-toluenesulfonates.

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Funding

This study was performed in the framework of state assignment of the Ministry of Science and Higher Education of the Russian Federation (project no. Nauka FSWW2020-011).

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Authors and Affiliations

  1. National Research Tomsk Polytechnic Uuniversity, 634050, Tomsk, Russia

    A. N. Sanzhiev, E. A. Krasnokutskaya, K. D. Erin & V. D. Filimonov

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  1. A. N. Sanzhiev
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  2. E. A. Krasnokutskaya
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  3. K. D. Erin
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  4. V. D. Filimonov
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Corresponding author

Correspondence to E. A. Krasnokutskaya.

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The authors declare no conflict of interest.

Additional information

Translated from Zhurnal Organicheskoi Khimii, 2021, Vol. 57, No. 6, pp. 842–851 https://doi.org/10.31857/S0514749221060069.

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Sanzhiev, A.N., Krasnokutskaya, E.A., Erin, K.D. et al. Diazotization of Aminopyridines in the Presence of Camphorsulfonic Acid. Synthesis and Some Properties of Pyridinyl Camphorsulfonates. Russ J Org Chem 57, 922–929 (2021). https://doi.org/10.1134/S1070428021060063

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