Abstract
In this study, a nanocomposite of activated carbon modified by copper hydroxide nanoparticles and stearic acid with high hydrophobic–oleophilic characteristics was synthesized, characterized and used to remove vegetable oils from oil/water emulsion. Effects of different parameters such as initial pH, temperature, and concentration on oil removal from emulsion were investigated. Langmuir and Freundlich adsorption isotherm models were employed to analyze equilibrium data. The results showed that maximum oil/water separation efficiency obtained about 100% at pH 7, the maximum oil adsorption capacity obtained 6.27 g/g, and the oil adsorption process by the nanocomposite followed the Freundlich adsorption isotherm. The thermodynamic results showed that the oil adsorption process with synthetic adsorbent is exothermic and spontaneous. The results showed that the resulted nanocomposite is an efficient and reusable adsorbent to remove vegetable oils from oil/water emulsion.
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REFERENCES
Sabouri, M.R., et al., Process Safety & Environmental Protection, 2019, vol. 126, pp. 182–192. https://doi.org/10.1016/j.psep.2019.04.006
Nwadiogbu, J.V. Ajiwe, and Okoye, P., Taibah University for Science, 2016, vol. 10, pp. 56–63. https://doi.org/10.1016/j.jtusci.2015.03.014
Frapiccini, E. and Marini, M., Water, Air, & Soil Pollution, 2015, vol. 226, p. 246. https://doi.org/10.1007/s11270-015-2510-7
Sabir, S., Critical Reviews in Environmental Science & Technology, 2015, vol. 45, pp. 1916–1945. https://doi.org/10.1080/10643389.2014.1001143
Okiel, K., El-Sayed, M., and El-Kady, M.Y., Egyptian J. Petroleum, 2011, vol. 20, pp. 9–15. https://doi.org/10.1016/j.ejpe.2011.06.002
Wahi, R., et al., Separation & Purification Technology, 2013, vol. 113, pp. 51–63. https://doi.org/10.1016/j.seppur.2013.04.015
Freitas, A.M. Mendes and Coelho, G., Chemical Thermodynamics, 2007, vol. 39, pp. 1027–1037. https://doi.org/10.1016/j.jct.2006.12.016
Othman, M.R., Int. J. Electrochem. Sci., 2015, vol. 10, pp. 4911–4921.
Khalifeh, S. and T.D. Burleigh, Magnesium and Alloys, 2018, vol. 6, pp. 327–336. https://doi.org/10.1016/j.jma.2018.08.003
Cao, C. and Cheng, J., Materials Letters, 2018, vol. 217, pp. 5–8. https://doi.org/10.1016/j.matlet.2018.01.026
Gao, J., et al., Central European J. Chem., 2012, vol. 10, pp. 1766–1772. https://doi.org/10.2478/s11532-012-0116-0
Nikkhah, A.A., et al., Chem. Eng., 2015, vol. 262, pp. 278–285. https://doi.org/10.1016/j.cej.2014.09.077
Wang, L., et al., Nanoscale, 2012, vol. 4, pp. 6850–6855. https://doi.org/10.1039/C2NR31898A
Mishra, A.K., et al., Scientific Reports, 2020, vol. 10, pp. 1–10. https://doi.org/10.1038/s41598-020-67986-4
Liu, Z., et al., Surface and Coatings Technology, 2018, vol. 352, pp. 313–319. https://doi.org/10.1016/j.surfcoat.2018.08.026
Zhang, M., et al., Applied Surface Science, 2012, vol. 261, pp. 764–769. https://doi.org/10.1016/j.apsusc.2012.08.097
Arfaoui, M., et al., Applied Surface Science, 2017, vol. 397, pp. 19–29. https://doi.org/10.1016/j.apsusc.2016.11.085
Devamani, R.H.P. and Alagar, M., Nano Biomed Eng, 2013, vol. 5, pp. 116–120 https://doi.org/10.5101/nbe.v5i3
Zeng, Y.-X., et al., J. Nanomaterials, 2013, vol. 2013, pp. 1–6. https://doi.org/10.1155/2013/270490
Bayat, M., Javanbakht, V., and Esmaili, J., Int. J. Biological Macromolecules, 2018, vol. 116, pp. 607–619. https://doi.org/10.1016/j.ijbiomac.2018.05.012
El Ghandoor, H., et al., Int. J. Electrochem. Sci, 2012, vol. 7, pp. 5734–5745.
Ding, Y., et al., ACS Applied Materials & Interfaces, 2018, vol. 10, pp. 6652–6660. https://doi.org/10.1021/acsami.7b13626
Zhu, Z., Ding, Y., and Heglund, D., US Patent App. 16/277437, 2019.
Liu, P., et al., Applied Surface Science, 2018, vol. 447, pp. 656–663. https://doi.org/10.1016/j.apsusc.2018.04.030
Urbina-Villalba, G., arXiv preprint arXiv:1608.04015, 2016, vol. 5, pp. 1–15.
Derjaguin, B., Churaev, N., and Muller, V., Surface Forces, 1987, Berlin: Springer, 1987.
Wang, Q., et al., Env. Sci.: Water Research & Technology, 2018, vol. 4, pp. 1553–1563. https://doi.org/10.1039/C8EW00188J
Hao, L., et al., Industrial & Eng. Chem. Res., 2016. vol. 55, pp. 1748–1759. https://doi.org/10.1021/acs.iecr.5b04401
Li, Z., et al., Colloid & Polymer Sci., 2016, vol. 294, pp. 1943–1958. https://doi.org/10.1007/s00396-016-3956-x
Xu, H., et al., Chem. Eng. J., 2018, vol. 337, pp. 10–18. https://doi.org/10.1016/j.cej.2017.12.084
Javanbakht, V., et al., Powder Technology, 2016, vol. 302, pp. 372–383. https://doi.org/10.1016/j.powtec.2016.08.069
Pauzan, M., Satirawaty, A., and Ahad, N., J. Chemistry, 2018, vol. 2018. https://doi.org/10.1155/2018/5059791
Gulistan, A.S., et al., Desalination & Water Treatment, 2016, vol. 57, pp. 15724–15732. https://doi.org/10.1080/19443994.2015.1130661
Rajak, V., et al., Chem. Eng. Comm., 2018, vol. 205, pp. 897–913. https://doi.org/10.1080/00986445.2017.1423288
Asadpour, R., et al., Water Sci. & Tech., 2014, vol. 70, pp. 1220–1228. https://doi.org/10.2166/wst.2014.355
Hassan, F., et al., Pakistan J. Eng. & Appl. Sci., 2018. vol. 23, pp. 86–92.
Kazemi, J. and Javanbakht, V., Int. J. Biological Macromol., 2020, vol. 154, pp. 1426–1437. https://doi.org/10.1016/j.ijbiomac.2019.11.024
Keyvani, F., Rahpeima, S., and Javanbakht, V., Solid State Sciences, 2018, vol. 83, pp. 31–42. https://doi.org/10.1016/j.solidstatesciences.2018.06.007
Sareban, Z. and Javanbakht, V., Korean J. Chem. Eng., 2017, vol. 34, pp. 2886–2900. https://doi.org/10.1007/s11814-017-0216-9
Wang, Y., Feng, Y., and Yao, J., J. Colloid Interface Sci., 2019, vol. 533, pp. 182–189. https://doi.org/10.1016/j.jcis.2018.08.073
Xue, Z., et al., Rsc Advances, 2013, vol. 3, pp. 23432–23437. https://doi.org/10.1039/C3RA41902A
Teas, C., et al., Desalination, 2001, vol. 140, pp. 259–264. https://doi.org/10.1016/S0011-9164(01)00375-7
Rajakovic, V., et al., J. Hazardous Materials, 2007, vol. 143, pp. 494–499. https://doi.org/10.1016/j.jhazmat.2006.09.060
Ibrahim, S., Ang, H.-M., and Wang, S., Bioresource technology, 2009, vol. 100, pp. 5744–5749. https://doi.org/10.1016/j.biortech.2009.06.070
Mysore, D., Viraraghavan, T., and Jin, Y.-C., Water Research, 2005, vol. 39, pp. 2643–2653. https://doi.org/10.1016/j.watres.2005.04.034
Ahmad, A., Sumathi, S., and Hameed, B., Water research, 2005, vol. 39, pp. 2483–2494. https://doi.org/10.1016/j.watres.2005.03.035
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Financial support of this work by ACECR Institute of Higher Education (Isfahan Branch) is gratefully appreciated.
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Javanbakht, V., Aghili, P. Modified Activated Carbon/Cu(OH)2 Nanocomposite for Oil/Water Emulsion Separation. Russ J Appl Chem 94, 680–691 (2021). https://doi.org/10.1134/S1070427221050177
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DOI: https://doi.org/10.1134/S1070427221050177