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Reactive Adsorption Desulfurization of Dibenzothiophene in Presence of Mesoporous Adsorbents

  • Organic Synthesis and Industrial Organic Chemistry
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Abstract

Reactive adsorption desulfurization of a model fuel containing dibenzothiophene with various adsorbents was studied. Adsorbents based on MCM-41 mesoporous material with supported Ni and ZnO phases were prepared and characterized. The desulfurization activity of the material in a fixed-bed flow-through reactor was compared to that of alumina-based adsorbents. The adsorbent based on MCM-41 considerably surpasses its analog on Al2O3 support in the adsorption capacity in reactive adsorption desulfurization of dibenzothiophene at 350°С, pressure of 2 MPa, and feed space velocity of 1 h–1.

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ACKNOWLEDGMENTS

The authors are grateful to staff members of the Nanochemistry and Nanomaterials Center for Shared Use, Moscow State University, for analyzing the samples by transmission electron microscopy.

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Authors and Affiliations

  1. Chemical Faculty, Moscow State University, 119991, Moscow, Russia

    O. V. Golubev, H. Zhou & E. A. Karakhanov

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  1. O. V. Golubev
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  2. H. Zhou
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  3. E. A. Karakhanov
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Correspondence to O. V. Golubev.

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Additional information

Translated from Zhurnal Prikladnoi Khimii, No. 5, pp. 580–589, January, 2021 https://doi.org/10.31857/S0044461821050054

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Golubev, O.V., Zhou, H. & Karakhanov, E.A. Reactive Adsorption Desulfurization of Dibenzothiophene in Presence of Mesoporous Adsorbents. Russ J Appl Chem 94, 586–594 (2021). https://doi.org/10.1134/S1070427221050050

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