Abstract
A procedure allowing preparation of mixed metal–carbon nanostructures from electroplating waste in a high yield was suggested. The following substances containing all the metals from the initial slime can be prepared from electroplating slimes (containing mainly iron or copper): metal phthalocyanines, phthalocyanine pyrolyzates, mixed endometallofullerenes, and their hydroxylated derivatives.
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Funding
The study was performed within the framework of the government assignment for the Konstantinov Institute of Nuclear Physics, National Research Center Kurchatov Institute.
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V.P. Sedov: experiment designing, manuscript writing; A.A. Borisenkova, synthesis of water-soluble metal-containing fullerenols, manuscript writing; M.V. Suyasova, UV spectrometric studies (determination of fullerene concentrations in electric arc soot) and X-ray fluorescence analysis; S.V. Fomin, electric arc synthesis of fullerene-containing soot, synthesis of metal phthalocyanine pyrolyzate samples; D.N. Orlova, analysis and interpretation of IR data for samples of metal phthalocyanines and their pyrolyzates, HPLC analysis of fullerene-containing soot; N.S. Fokin, synthesis of metal phthalocyanine samples; and A.A. Krivorotov, analysis and interpretation of the IR and UV spectra of water-soluble derivatives of metallofullerenes prepared in the course of electroplating slime processing.
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Translated from Zhurnal Prikladnoi Khimii, No. 5, pp. 553–561, January, 2021 https://doi.org/10.31857/S0044461821050029
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Sedov, V.P., Borisenkova, A.A., Fomin, S.V. et al. Processing of Metal-Containing Electroplating Slimes into Mixed Water-Soluble Metal–Carbon Structures. Russ J Appl Chem 94, 560–568 (2021). https://doi.org/10.1134/S1070427221050025
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DOI: https://doi.org/10.1134/S1070427221050025