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Oxidation of Propane: Influence of the Nature of Catalyst, Cocatalyst, and Coreductant

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Abstract

Variation of the nature of the components of the catalytic systems comprising a catalyst [Pd/C, Pd(α,α-bipy)Cl2, RhCl3] and a cocatalyst (FeSO4, CuSO4), as well as a coreductant (H2, CO), allows exerting some control over the selectivity of the process of propane oxidation with oxygen. In particular, the yield of carbonyl compounds such as acetone and propanal in the presence of the Pd/C–FeSO4–H2catalytic system reached 90%, and that of propyl esters in the presence of RhCl3–CuSO4–CO catalytic system was 64.5%. These differences are supposedly attributable to the changes in the process mechanism depending on the composition of the catalytic systems.

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Funding

The study was carried out within the framework of the state assignment of Merzhanov Institute of Structural Macrokinetics and Materials Science, Russian Academy of Sciences (theme no. 46.3).

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Correspondence to E. G. Chepaikin.

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The authors declare no conflict of interest requiring disclosure in this article.

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Translated from Neftekhimiya, 2021, Vol. 61, No. 4, pp. 540–546 https://doi.org/10.31857/S0028242121040092.

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Chepaikin, E.G., Menchikova, G.N. & Pomogailo, S.I. Oxidation of Propane: Influence of the Nature of Catalyst, Cocatalyst, and Coreductant. Pet. Chem. 61, 781–786 (2021). https://doi.org/10.1134/S0965544121070094

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  • DOI: https://doi.org/10.1134/S0965544121070094

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