Abstract
Variation of the nature of the components of the catalytic systems comprising a catalyst [Pd/C, Pd(α,α-bipy)Cl2, RhCl3] and a cocatalyst (FeSO4, CuSO4), as well as a coreductant (H2, CO), allows exerting some control over the selectivity of the process of propane oxidation with oxygen. In particular, the yield of carbonyl compounds such as acetone and propanal in the presence of the Pd/C–FeSO4–H2catalytic system reached 90%, and that of propyl esters in the presence of RhCl3–CuSO4–CO catalytic system was 64.5%. These differences are supposedly attributable to the changes in the process mechanism depending on the composition of the catalytic systems.
REFERENCES
Chepaikin, E.G., Menchikova, G.N., and Pomogailo, S.I., Russ. Chem. Bull., Int. Ed., 2019, vol. 68, no. 8, pp. 1465–1477. https://doi.org/10.1007/s11172-019-2581-5
Kang, J. and Park, E.D., ChemCatChem., 2019, vol. 11, no. 7, pp. 4247–4251. https://doi.org/10.1002/cctc.201900919
He, Y., Luan, C., Fang, Y., Feng, X., Peng, X., Yang, G., and Tsubaki, N., Catal. Today, 2020, vol. 339, pp. 48–53. https://doi.org/10.1016/j.cattod.2019.02.043
Shilov, A.E. and Shul’pin, G.B., Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes, New York: Kluwer Academic, 2000.
Henry, P.M., Inorg. Chem., 1966, vol. 5, no. 4, pp. 688–689. https://doi.org/10.1021/ic50038a042
Sen, A., Acc. Chem. Res., 1998, vol. 31, no. 9, pp. 550–557. https://doi.org/10.1021/ar970290x
Chepaikin, E.G., Bezruchenko, A.P., Leshcheva, A.A., Boiko, G.N., Kuzmenkov, I.V., Grigoryan, E.H., and Shilov, A.E., J. Mol. Catal. A: Chem., 2001, vol. 169, pp. 89–98. https://doi.org/10.1016/S1381-1169(01)00046-2
Chepaikin, E.G., Bezruchenko, A.P., Boiko, G. N., and Leshcheva, A.A., Petrol. Chem., 2003, vol. 43, pp. 395–398.
Chepaikin, E.G., Menchikova, G.N., and Pomogailo, S.I., Petrol. Chem., 2020, vol. 60, no. 11, pp. 1260–1267. https://doi.org/10.1134/S096554412011002X
Campos-Martin, J.M., Blanco-Brieva, G., and Fierro, J.L.G., Angew. Chem., Int. Ed., 2006, vol. 45, no. 42, pp. 6962–6984. https://doi.org/10.1002/anie.200503779
Han, Y.-F. and Lunsford, J.H., J. Catal., 2005, vol. 230, no. 2, pp. 313–316. https://doi.org/10.1016/j.jcat.2004.12.001
Edwards, J.K., Freakley, S.J., Carley, A.F., Kiely, Ch.J., and Hutchings, G.J., Acc. Chem. Res., 2014, vol. 47, no. 3, pp. 845–854. https://doi.org/10.1021/ar400177
Freakley, S.J., He, Q., Harrhy, J.H., Lu, L, Crole, D.A., Morgan, D.J., Ntainjua, E.N., Edwards, J.K., Carley, A.F., Borisevich, A.Y., Kiely, C.J., and Hutchings, G.J., Science, 2016, vol. 351, no. 6276, pp. 965–968. https://doi.org/10.1126/science.aad5705
Lyu, J., Wei, J., Niu, L., Lu, C., Hu, Y., Xiang, Y., Zhang, G., Zhang, Q., Ding, C., and Li, X., RSC Adv., 2019, no. 9, pp. 13398–13402. https://doi.org/10.1039/C9RA02452B
Wang, S., Doronkin, D.E., Hähsler, M., Huang, X., Wang, D., Grunwaldt, J.-D., and Behrens, S., ChemSusChem, 2020, vol. 13, no. 12, pp. 3243–3251. https://doi.org/10.1002/cssc.202000407
Sintez kompleksnykh soedinenii metallov platinovoi gruppy (Synthesis of Complexes of Platinum Group Metals), Chernyaev, I.I., Ed., Moscow: Nauka, 1964.
Ogo, S., Thi Minh, L.T., Kikunaga, T., Ando, T., Matsumoto, T., Yatabe, T., and Kato, K., Organometallics, 2020, vol. 39, no. 20, pp. 3731–3741. https://doi.org/10.1021/acs.organomet.0c00565
Bianchi, D., Bortolo, R., D’Aloisio, R., and Ricci, M., J. Mol. Cat. A: Chem., 1999, vol. 150, pp. 87–94. https://doi.org/10.1016/S1381-1169(99)00218-6
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The study was carried out within the framework of the state assignment of Merzhanov Institute of Structural Macrokinetics and Materials Science, Russian Academy of Sciences (theme no. 46.3).
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Translated from Neftekhimiya, 2021, Vol. 61, No. 4, pp. 540–546 https://doi.org/10.31857/S0028242121040092.
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Chepaikin, E.G., Menchikova, G.N. & Pomogailo, S.I. Oxidation of Propane: Influence of the Nature of Catalyst, Cocatalyst, and Coreductant. Pet. Chem. 61, 781–786 (2021). https://doi.org/10.1134/S0965544121070094
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DOI: https://doi.org/10.1134/S0965544121070094