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Fast Spontaneous Transport of a Non-wetting Fluid in a Disordered Nanoporous Medium

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Abstract

The experimental study of cooperative fast transport of non-wetting fluid in a disordered nanoporous medium is carried out in this work. New experimental data for simultaneous measurement of fluid flow, filled pore volume and pressure have been obtained. Dependencies of critical pressure and flow on porous particle mass and rapid compression energy have also been established. A new transport mechanism is proposed. The dynamics of fluid transport is represented as a process of evolution of two macroscopic growing modes of transport—spontaneous transport that occurs when new critical pressure of dynamic percolation transition and fluid transport caused by a constant critical pressure under impact compression of nanoporous particles suspension. Following the theory of critical dynamics of multiscale phenomena, a condition for the interaction of modes is proposed. Taking into account this interaction, rapid spontaneous transport is adjusted to the slow impact of impact compression, and the experimental dependencies should be described by the slow mode—impact compression. Such transport occurs simultaneously in two different time scales and is determined by the properties of spontaneous transport. The experimental dependencies are quantitatively described in the kinetic model. Under conditions of filled pores, the response of a fluid transport to impact is characterized by positive feedback.

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Acknowledgements

We are grateful to G.V. Lisichkin for the L23 sample.

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Authors and Affiliations

  1. Polymeric Membranes Laboratory, A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninsky prospekt, 29, Moscow, 119991, Russian Federation

    Vladimir Borman, Anton Belogorlov & Ivan Tronin

  2. Molecular Physics Department, National Research Nuclear University MEPhI, Kashirskoe sh. 31, Moscow, 115409, Russian Federation

    Vladimir Borman, Anton Belogorlov & Ivan Tronin

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  1. Vladimir Borman
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  2. Anton Belogorlov
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  3. Ivan Tronin
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Contributions

All authors contributed to the study conception and design. Material preparation, data collection and analysis were performed by Anton Belogorlov and Ivan Tronin. The first draft of the manuscript was written by Vladimir Borman. All authors read and approved the final manuscript.

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Correspondence to Anton Belogorlov.

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This work was supported by the Russian Science Foundation (project no. 18-13-00398).

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Borman, V., Belogorlov, A. & Tronin, I. Fast Spontaneous Transport of a Non-wetting Fluid in a Disordered Nanoporous Medium. Transp Porous Med 139, 21–44 (2021). https://doi.org/10.1007/s11242-021-01638-7

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