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Droplet formation in oval microchannels with a double T junction: a CFD and experimental study

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Abstract

The use of microfluidics can improve the process of droplet formation while reducing energy consumption. In the present work, a microreactor system with a double T junction and oval microchannel reactor 2509 mm long was analyzed. The stream was composed of styrene, water, and an emulsifier. The concentration of water in the emulsion and the flow rates of water and styrene were evaluated. Droplets were observed at styrene/water flow rate ratios (Qd/Qc) ranging from 1:10 to 1:80. The simulations in the double T junction were carried out with laminar flow and the Volume Of Fluids model was selected for the phase interactions. Experiments with four flow rates of styrene and water were carried out. A simple optical system was used for in-line observation of droplets formed in the microreactor. For the flow ratio 1:1, there was no drop formation. For the other rates, droplets were observed from 59 to 200 μm. The droplets moved along the reactor maintaining shape and size. This fact indicated that the micro reaction system is suitable for developing a system that requires stability, such as emulsion polymerizations. The comparison between model and experimental results pointed out that these were reasonably represented by the model.

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References

  • Anna SL, Bontoux N, Stone HA (2003) Formation of dispersions using “flow focusing” in microchannels. Appl Phys Lett 82(3):364–366

    Article  CAS  Google Scholar 

  • Asua JM (2004) Emulsion polymerization: from fundamental mechanisms to process developments. J Polym Sci Part a Polym Chem 42(5):1025–1041

    Article  CAS  Google Scholar 

  • Costa ALR, Gomes A, Cunha RL (2017) Studies of droplets formation regime and actual flow rate of liquid-liquid flows in flow-focusing microfluidic devices. Exp Therm Fluid Sci 85:167–175

    Article  CAS  Google Scholar 

  • Fuerstman MJ, Garstecki P, Whitesides G (2007) Coding/decoding and reversibility of droplet trains in microfluidic networks. Science 315:828–832

    Article  CAS  Google Scholar 

  • Fullin L, Melloni E, Vianna AS Jr (2015) Solution styrene polymerization in a millireactor. Chem Eng Process 98:1–12

    Article  CAS  Google Scholar 

  • Garstecki P, Fuerstman MJ, Stone HA, Whitesides GM (2006) Formation of droplets and bubbles in a microfluidic T-junction—scaling and mechanism of break-up. Lab Chip 6:437–446

    Article  CAS  Google Scholar 

  • Ge XH, Huang JP, Xu JH, Chen J, Luo GS (2016) Water-oil Janus emulsions: microfluidic synthesis and morphology design. Soft Matter 12:3425–3430

    Article  CAS  Google Scholar 

  • Gupta A, Murshed SS, Kumar R (2009) Droplet formation and stability of flows in a microfluidic T-junction. Appl Phys Lett 94:164–177

    Google Scholar 

  • Kokal SL (2005) Crude oil emulsions: a state-of-the-art review. Soc Pet Eng 20:5–13. https://doi.org/10.2118/77497-PA

    Article  CAS  Google Scholar 

  • Li XB, Li FB, Yang JC, Kinoshita H, Oishi M, Oshima M (2012) Study on the mechanism of droplet formation in T-Junction microchannel. Chem Eng 69:340–351

    Article  CAS  Google Scholar 

  • Maan AA, Nazir A, Khan MKI, Boom R, Schroën K (2015) Microfluidic emulsification in food processing. J Food Eng 147:1–7

    Article  CAS  Google Scholar 

  • Okushima S, Nisisako T, Torii T, Higuchi T (2004) Controlled production of monodisperse double emulsions by two-step droplet breakup in microfluidic devices. Langmuir 20(23):9905–9908

    Article  CAS  Google Scholar 

  • Peres JCG, Herrera CC, Baldochi SL, De Rossi W, Vianna AS Jr (2019) Analysis of a microreactor for synthesizing nanocrystals by computational fluid dynamics. Can J Chem Eng 97:594–603

    Article  CAS  Google Scholar 

  • Prakash M, Gershenfeld N (2007) Microfluidic bubble logic. Science 315:832–835

    Article  CAS  Google Scholar 

  • Purwanti N, Ichikawa S, Neves MA, Uemura K, Nakajima M, Kobayashi I (2016) B—lactoglobulin as food grade surfactant for clove oil-in-water and limonene-in-water emulsion droplets produced by microchannel emulsification. Food Hydrocolloids 60:98–108

    Article  CAS  Google Scholar 

  • Qiu D, Tonkovich AL, Silva LJ, Long RQ, Yang BL, Trenkamp KM, Freeman JA (2009) Process for forming an emulsion using microchannel process technology. U.S. Patent No. 7,485,671

  • Schindler M, Ajdari A (2008) Droplet traffic in microfluidic networks: a simple model for understanding and designing. Phys Rev Lett 100:044501:1-044501:4

    Article  Google Scholar 

  • Siqueira FC, Farias IS, Moraes Júnior D, Vianna AS Jr (2019) CFD simulation of annular oil flow wrapped with water. Can J Chem Eng 97(2):444–451. https://doi.org/10.1002/cjce.23326

    Article  CAS  Google Scholar 

  • Steegamans MLJ, Warmerdam A, Schroen KGPH, Boom RM (2009) Boom, Dynamic interfacial tension measurements with microfluidic Y-junctions. Langmuir 25:9751–9758

    Article  Google Scholar 

  • Sugiura S, Nakajima M, Yamamoto K, Iwamoto S, Oda T, Satake M, Seki M (2004) Preparation characteristics of water-in-oil-in-water multiple emulsions using microchannel emulsification. J Colloid Interf Sci 270:221–228

    Article  CAS  Google Scholar 

  • Thorsen T, Roberts RW, Arnold FH, Quake SR (2001) Dynamic pattern formation in a vesicle-generating microfluidic device. Phys Rev Lett 86:4163

    Article  CAS  Google Scholar 

  • Tice JD, Song H, Lyon AD, Ismagilov RF (2003) Formation of droplets and mixing in multiphase microfluidics at low values of the reynolds and the capillary numbers. Langmuir 19:9127–9133

    Article  CAS  Google Scholar 

  • Ushikubo FY, Oliveira DRB, Michelon M, Cunha RL (2015) Designing food structure using microfluidics. Food Eng Rev 7:393–416

    Article  CAS  Google Scholar 

  • van Rijn CJ, van Heugten WG (2017) Droplet formation by confined liquid threads inside microchannels. Langmuir 33(38):10035–10040

    Article  Google Scholar 

  • Vladisavljević GT, Kobayashi I, Nakajima M (2012) Production of uniform droplets using membrane, microchannel and microfluidic emulsification devices. Microfluid Nanofluid 13:151–178

    Article  Google Scholar 

  • Wehking JD, Gabany M, Chew L, Kumar R (2014) Effects of viscosity, interfacial tension, and flow geometry on droplet formation in a microfluidic T-junction. Microfluid Nanofluid 16(3):441–453

    Article  CAS  Google Scholar 

  • Wu Z, Sundén B (2019) Liquid-liquid two-phase flow patterns in ultra-shallow straight and serpentine microchannels. Heat Mass Transf 55(4):1095–1108

    Article  CAS  Google Scholar 

  • Yadav AK, Cal JC, Barandiaran MJ (2011) Feasibility of tubular microreactors for emulsion polymerization. Macromol React Eng 5:69–77

    Article  CAS  Google Scholar 

  • Yadav AK, Cal JC, Barandiaran MJ (2012) Synthesis of water-bone Polymer nanoparticles in a continuous microreactor. Chem Eng J 198:191–200

    Article  Google Scholar 

  • Yamanishi Y, Feng L, Fumihito A (2010) On-demand production of emulsion droplets over a wide range of sizes. Adv Robot 24(14):2005–2018

    Article  Google Scholar 

  • Zheng B, Tice JD, Ismagilov RF (2004) Formation of droplets of alternating composition in microfluidic channels and applications to indexing of concentrations in droplet-based assays. Anal Chem 76:4977–4982

    Article  CAS  Google Scholar 

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Acknowledgements

This study was financed in part by the Coordenação de Aperfeiçoamento de Pessoal de Nível Superior—Brasil (CAPES)—Finance Code 001.

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Correspondence to Ardson dos S. Vianna Jr.

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Siqueira, F.C.S., Giannini, H. & Vianna, A.d.S. Droplet formation in oval microchannels with a double T junction: a CFD and experimental study. Braz. J. Chem. Eng. 38, 485–493 (2021). https://doi.org/10.1007/s43153-021-00133-2

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  • DOI: https://doi.org/10.1007/s43153-021-00133-2

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