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Crystallization of Zeolites in the Presence of Diquaternary Alkylammonium Salts Derived from Dimethylethanolamine

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Abstract

Zeolite-containing materials of various structural types (MFI, MEL, MTW) were prepared by the hydrothermal method using organic templates based on quaternary polymethylenediammonium salts. The materials were characterized by X-ray diffraction analysis, low-temperature nitrogen adsorption–desorption, temperature-programmed ammonia desorption, IR spectroscopy, scanning electron microscopy, X-ray fluorescence analysis, transmission electron microscopy, solid-state 27Al NMR spectroscopy, and IR spectroscopy of adsorbed pyridine. The effect of the template on the structure of the material obtained was revealed.

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ACKNOWLEDGMENTS

The study was performed using the equipment of the Center for Shared Use Analytical Center for Problems of Deep Oil Refining and Petroleum Chemistry at the Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences.

Funding

The study was financially supported by the Russian Science Foundation (project no. 20-79-00313).

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Correspondence to D. E. Tsaplin or E. R. Naranov.

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A.L. Maximov is the Editor-in-Chief of Petroleum Chemistry journal. The other authors declare no conflict of interest requiring disclosure in this article.

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Tsaplin, D.E., Naranov, E.R., Kulikov, L.A. et al. Crystallization of Zeolites in the Presence of Diquaternary Alkylammonium Salts Derived from Dimethylethanolamine. Pet. Chem. 61, 815–824 (2021). https://doi.org/10.1134/S0965544121080089

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