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Activity of Various Cation-Exchange Forms of LSX and X Zeolites in СО2 Adsorption

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Abstract

Samples of Na, Li, K, and Ca forms of dispersed LSX and Х zeolites of high phase purity and almost 100% degree of crystallinity were synthesized. The influence of the kind and content of the exchangeable cation on the adsorption characteristics of the porous structure of the synthesized cation-exchange forms of LSX and Х zeolites with respect to water and benzene vapors was studied. The amounts of the carbon dioxide adsorbed at 25°C from gas–air mixtures containing 0.04 and 10 vol % CO2 onto various ion-exchange forms of LSX and X zeolites until reaching the limiting capacity for СО2 were compared.

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REFERENCES

  1. Ruthven, D.M., Farooq, S., and Knaebel, K., Pressure Swing Adsorption, New York: VCH, 1994.

  2. Glupanov, V.N., Shumyatskii, Yu.I., Seregin, Yu.A., and Brekhner, S.A., Poluchenie kisloroda i azota adsorbtsionnym razdeleniem vozdukha (Production of Oxygen and Nitrogen by Adsorption Separation of Air), TsINTIKhimneftemash, 1991.

  3. Mel’gunov, M.S., Korotkotsiklovaya beznagrevnaya adsorbtsiya (Pressure Swing Adsorption), Moscow: Kalvis, 2009.

  4. Shumyatskii, Yu.I., Promyshlennye adsorbtsionnye protsessy (Industrial Adsorption Processes), Moscow: KolosS, 2009.

  5. Bonenfant, D., Kharoune, M., Niquette, P., Mimeault, M., and Hausler, R., Sci. Technol. Adv. Mater., 2008, vol. 9, pp. 1–7. https://doi.org/10.1088/1468-6996/9/1/013007

    Article  CAS  Google Scholar 

  6. Baciocchi, R., Storti, G., and Mazzotti, M., Chem. Eng. Process., 2006, vol. 45, pp. 1047–1058. https://doi.org/10.1016/j.cep.2006.03.015

    Article  CAS  Google Scholar 

  7. Goeppert, A., Czaun, M., Prahash, G.K., and Olah, G.A., Energ. Environ. Sci., 2012, vol. 5, pp. 7833–7853. https://doi.org/10.1039/C2EE21586A

    Article  CAS  Google Scholar 

  8. Cheng, H. and Tan, C., Sep. Purif. Technol., 2011, vol. 82, pp. 156–166. https://doi.org/10.1016/j.seppur.2011.09.004

    Article  CAS  Google Scholar 

  9. Keith, D.W., Science, 2009, vol. 25, pp. 1654–1655. https://doi.org/10.1126/science.1175680

    Article  CAS  Google Scholar 

  10. Breck, D.W., Zeolite Molecular Sieves: Structure, Chemistry and Use, New York: Wiley, 1974.

  11. Pavlova, I.N., Travkina, O.S., and Garieva, G.F., Petrol. Chem., 2020, vol. 60, no. 8, pp. 903–908. https://doi.org/10.1134/S0965544120080101

    Article  CAS  Google Scholar 

  12. Pavlova, I.N., Garieva, G.F., Travkina, O.S., Kutepov, B.I., Fomkin, A.A., and Shkolin, A.V., Prot. Met. Phys. Chem. Surf., 2015, vol. 51, no. 5, pp. 767–772.

    Article  CAS  Google Scholar 

  13. Kel’tsev, N.V., Osnovy adsorbtsionnoi tekhniki (Principles of Adsorption Technique), Moscow: Khimiya, 1984.

  14. Pavlova, I.N., Ilibaev, R.S., Travkina, O.S., Il’yasova, R.R., and Kutepov, B.I., Khim. Tekhnol., 2010, no. 4, pp. 208–213.

    Google Scholar 

  15. Kuronen, M., Weller, M., Townsend, R., and Harjula, R., React. Funct. Polym., 2006, vol. 66, no. 11, pp. 1350–1361. https://doi.org/10.1016/j.reactfunctpolym.2006.03.019

    Article  CAS  Google Scholar 

  16. Treacy, M.M.J. and Higgins, J.B., Collection of Simulated XRD Powder Patterns for Zeolites, Elsevier, 2001.

  17. Zhdanov, S.P., Khvoshchev, S.S., and Samulevich, N.N., Sinteticheskie tseolity. Kristallizatsiya, strukturnokhimicheskoe modifitsirovanie i adsorbtsionnye svoistva (Synthetic Zeolites. Crystallization, Structure-Chemical Modification, and Adsorption Properties), Moscow: Khimiya, 1981.

  18. Hutson, N.D. and Yang, R.T., AIChE J., 2000, vol. 46, no. 11, pp. 2305–2317. https://doi.org/10.1002/aic.690461121

    Article  CAS  Google Scholar 

  19. Jacobs, P.A., Van Cauwelaert, F.H., Vansant, E.F., and Uytterhoeven, J.B., J. Chem. Soc., Faraday Trans. 1, 1973, vol. 69, pp. 1056–1068. https://doi.org/10.1039/F19736901056

    Article  CAS  Google Scholar 

  20. Montanari, T. and Busca, G., Vibr. Spectrosc., 2008, vol. 46, pp. 45–51. https://doi.org/10.1016/j.vibspec.2007.09.001

    Article  CAS  Google Scholar 

  21. Hasegawa, K. and Matsumoto, A., AIP Conf. Proc., 2017, vol. 1865, 020002. https://doi.org/10.1063/1.4993321

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Funding

The study was performed within the framework of the government assignment for the Institute of Petroleum Chemistry and Catalysis, Ufa Federal Research Center, Russian Academy of Sciences, theme: Zeolite Materials of Various Structural Types with High Degree of Crystallinity and Hierarchic Pore Structure: A New Generation of Practically Important Petrochemical Products, state registry no. AAAA-A19-119022290006-2.

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Authors and Affiliations

  1. Institute of Petrochemistry and Catalysis of the Russian Academy of Sciences, Ufa Federal Research Center, 450075, Ufa, Russia

    I. N. Pavlova, O. S. Travkina & B. I. Kutepov

  2. Ishimbai Specialized Chemical Plant of Catalysts, 453203, Ishimbay, Russia

    G. F. Garieva

Authors
  1. I. N. Pavlova
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  2. O. S. Travkina
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  3. G. F. Garieva
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  4. B. I. Kutepov
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Corresponding author

Correspondence to O. S. Travkina.

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Pavlova, I.N., Travkina, O.S., Garieva, G.F. et al. Activity of Various Cation-Exchange Forms of LSX and X Zeolites in СО2 Adsorption. Pet. Chem. 61, 925–931 (2021). https://doi.org/10.1134/S0965544121080065

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  • DOI: https://doi.org/10.1134/S0965544121080065

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