Skip to main content
SpringerLink
Log in

Co(II) Schiff base Complexes Encapsulated in the Nanopores of Zeolite Y as Heterogeneous Catalysts for Selective Epoxidation of Alkenes with Molecular Oxygen

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

Co(II) macrocyclic Schiff base complex nanoparticles have been encapsulated in the nanopores of zeolite Y. The new Schiff base complexes entrapped in the nanoreactor of zeolite Y were characterized by several techniques: chemical analysis and spectroscopic methods (FT-IR, XRD, and DRS). These complexes (neat and encapsulated) were used for epoxidation of alkenes with O2 as oxidant in different solvents. The catalyst demonstrated excellent activity for a variety of alkenes in a mild, inexpensive and efficient protocol. Reaction parameters including temperature, catalyst amount and solvent were screened by reaction time. The recycling experiment results indicated that the catalysts were highly stable and maintained activity and selectivity even after being used for five cycles.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.

Similar content being viewed by others

REFERENCES

  1. Talsi, E.P. and Bryliakov, K.P., Coord. Chem. Rev., 2012, vol. 256, p. 1418.

    Article  CAS  Google Scholar 

  2. Adam, W., Saha Moller, C.R., and Ganeshpure, P.A., Chem. Rev., 2001, vol. 101, p. 3499.

    Article  CAS  Google Scholar 

  3. Blaser, H.U., Pugin, B., and Spindler, F., J. Mol. Catal., A, 2005, vol. 231, p. 1.

  4. Beller, M., Adv. Synth. Catal., 2004, vol. 346, p. 107.

    Article  CAS  Google Scholar 

  5. Silva, A.R., Budarin, V., Clark, J.H., et al., Carbon, 2005, vol. 43, p. 2096.

    Article  CAS  Google Scholar 

  6. Jørgensen, K.A., Chem. Rev., 1989, vol. 89, p. 431.

    Article  Google Scholar 

  7. Hunter, R., Turner, P., and Rimmer, S., Synth. Commun., 2000, vol. 30, p. 4461.

    Article  CAS  Google Scholar 

  8. Sheldon, R.A. and Kochi, J.K., Metal-Catalyzed Oxidation of Organic Compounds, New York: Academic, 1981, р. 271.

    Google Scholar 

  9. Koola, J.D. and Kochi, J.K., J. Org. Chem., 1987, vol. 52, p. 4545.

    Article  CAS  Google Scholar 

  10. Zombeck, A., Hamilton, D., and Drago, R.S., J. Am. Chem. Soc., 1982, vol. 104, p. 6782.

    Article  CAS  Google Scholar 

  11. Hamilton, D.E., Drago, R.S., and Zombeck, A., J. Am. Chem Soc., 1987, vol. 109, p. 374.

    Article  CAS  Google Scholar 

  12. Bezaatpour, A., Amiri, M., and Jahed, V., J. Coord. Chem., 2011, vol. 64, p. 1837.

    Article  CAS  Google Scholar 

  13. Salavati-Niasari, M., Salimi, Z., Bazarganipour, M., and Davar, F., Inorg. Chim. Acta, 2009, vol. 362, p. 3715.

    Article  CAS  Google Scholar 

  14. Banaei, A. and Rezazadeh, B., J. Coord. Chem., 2013, vol. 66, p. 2129.

    Article  CAS  Google Scholar 

  15. Tas, E., Aslanoglu, M., Kilic, A., et al., J. Chem. Res., 2006, vol. 4, p. 242.

    Article  Google Scholar 

  16. Temel, H., Cakir, U., and Ugras, I.H., Synt. React. Inorg. Met. Org. Chem., 2004, vol. 34, p. 819.

    Article  CAS  Google Scholar 

  17. Corma, A. and Garcia, H., Eur. J. Inorg. Chem., 2004, p. 1143.

  18. Quayle, W.H. and Lunsford, J.H., Inorg. Chem., 1982, vol. 21, p. 97.

    Article  CAS  Google Scholar 

  19. Kumar, D.S. and Alexander, V., Polyhedron, 1999, vol. 18, p. 1561.

    Article  CAS  Google Scholar 

  20. Salavati-Niasari, M., Davara, F., and Saberyan, K., Polyhedron, 2010, vol. 29, p. 2149.

    Article  CAS  Google Scholar 

  21. Temel, H., Kilic, A., and Tas, E., J. Coord. Chem., 2008, vol. 61, p. 1443.

    Article  CAS  Google Scholar 

  22. Ilhan, S., Temel, H., Kilic, A., and Tas, E., Transition, Met. Chem., 2007, vol. 32, p. 1012.

    CAS  Google Scholar 

  23. Diegruber, H., Plath, P.J., Schulz-Ekloff, G., and Mohl, M., J. Mol. Catal., 1984, vol. 24, p. 115.

    Article  CAS  Google Scholar 

  24. Salavati-Niasari, M., J. Mol. Catal. A: Chem., 2008, vol. 283, p. 120.

    Article  CAS  Google Scholar 

  25. Le, Z.G., Liu, Z., Qian, Y., and Wang, C., Appl. Surf. Sci., 2012, vol. 258, p. 5348.

    Article  CAS  Google Scholar 

  26. Saha, D., Maity, T., Bera, R., and Koner, S., Polyhedron, 2013, vol. 56, p. 30.

    Article  Google Scholar 

  27. Li, Z., Wu, Sh., Ding, H., et al., New J. Chem., 2013, vol. 37, p. 1561.

    Article  CAS  Google Scholar 

  28. Ma, X.T., Lu, X.H., Wei, C.C., et al., Catal. Commun., 2015, vol. 67, p. 98.

    Article  CAS  Google Scholar 

  29. Bhadbhade, M.M. and Srinivas, D., Inorg. Chem., 1993, vol. 32, p. 6122.

    Article  CAS  Google Scholar 

  30. Deshpande, S., Srinivas, D., and Ratnasamy, P., J. Catal., 1999, vol. 188, p. 261.

    Article  CAS  Google Scholar 

  31. Rezazadeh, B., Pourali, A., Banaei, A., and Behniafar, H., J. Coord. Chem., 2019, vol. 72, p. 3401.

    Article  CAS  Google Scholar 

  32. Bhunia, S., Jana, S., Saha, D., et al., Catal. Sci. Technol., 2014, vol. 4, p. 1820.

    Article  CAS  Google Scholar 

  33. Kazemnejadi, M., Shakeri, A., Nikookar, M., et al., Res. Chem. Intermed., 2017, vol. 43, p. 6889.

    Article  CAS  Google Scholar 

  34. Dhar, D., Koltypin, Y., Gedanken, A., and Chandrasekaran, S., Catal. Lett., 2003, vol. 86, p. 197.

    Article  CAS  Google Scholar 

  35. Qi, B., Lu, X.H., Fang, S.Y., et al., J. Mol. Catal. A, 2011, vol. 334, p. 44.

    Article  CAS  Google Scholar 

Download references

ACKNOWLEDGMENTS

The authors acknowledge the Damghan University for the support of this work.

Author information

Authors and Affiliations

  1. School of Chemistry, Damghan University, Damghan, Iran

    B. Rezazadeh, A. R. Pourali & S. Tabari

  2. Department of Chemistry, Payame Noor University, Tehran, Iran

    A. R. Banaei

Authors
  1. B. Rezazadeh
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. R. Pourali
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. R. Banaei
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. S. Tabari
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to A. R. Pourali or A. R. Banaei.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Rezazadeh, B., Pourali, A.R., Banaei, A.R. et al. Co(II) Schiff base Complexes Encapsulated in the Nanopores of Zeolite Y as Heterogeneous Catalysts for Selective Epoxidation of Alkenes with Molecular Oxygen. Russ J Coord Chem 47, 424–437 (2021). https://doi.org/10.1134/S107032842106004X

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S107032842106004X

Keywords:

Search

Navigation