Skip to main content
SpringerLink
Log in

Mono- and Binuclear Zinc Complexes with a Bidentate Phenol-Containing 2-Benzylideneamino-5-Methylphenol Schiff Base

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

The reaction of zinc chloride with 2-benzylideneamino-5-methylphenol (LH), a bidentate Schiff base, in 1 : 1 molar ratio in the presence of triethylamine gives the ionic complex [Et3NH]+[LZnCl2]– (I). The reaction between the zinc salt (chloride or acetate) and LH in 1 : 2 ratio results in complete displacement of the zinc salt anions to give bis-o-iminophenolate ZnL2 (II), which exists in the crystalline state as the (ZnL2)2 dimer formed via μ-bridging oxygen atoms of two out of the four o-iminophenolate ligands. The molecular structure of ligand LH and complexes I and (II·CDCl3)2 was established by X-ray diffraction (CIF files CCDC nos. 2052647 (LH), 2052645 (I), 2052646 (II·CDCl3)2).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.

Similar content being viewed by others

REFERENCES

  1. Vigato, P.A. and Tamburini, S., Coord. Chem. Rev., 2004, vol. 248, nos. 17–20, p. 1717.

    Article  CAS  Google Scholar 

  2. Liu, X. and Hamon, J.-R., Coord. Chem. Rev., 2019, vol. 389, p. 94.

    Article  CAS  Google Scholar 

  3. Miroslaw, B., Int. J. Mol. Sci., 2020, vol. 21, no. 10, p. 3493.

    Article  CAS  Google Scholar 

  4. Clarke, R.M. and Storr, T., Dalton Trans., 2014, vol. 43, no. 25, p. 9380.

    Article  CAS  Google Scholar 

  5. Liu, X., Manzur, C., Novoa, N., et al., Coord. Chem. Rev., 2018, vol. 357, p. 144.

    Article  CAS  Google Scholar 

  6. Zoubi, W.A., Al-Hamdani, A.A.S., and Kaseem, M., Appl. Organomet. Chem., 2016, vol. 30, no. 10, p. 810.

    Article  Google Scholar 

  7. Gupta, K.C. and Sutar, A.K., Coord. Chem. Rev., 2008, vol. 252, nos. 12–14, p. 1420.

    Article  CAS  Google Scholar 

  8. Hameed, A., Rashida, M., Uroos, M., et al., Exp. Opin. Ther. Pat., 2017, vol. 27, no. 1, p. 63.

    Article  CAS  Google Scholar 

  9. Hossain, M.S., Roy, P.K., Zakaria, C.M., et al., Int. J. Chem. Stud., 2018, vol. 6, no. 1, p. 19.

    CAS  Google Scholar 

  10. Kumar, M., Abbas, Z., Tuli, H.S., and Rani, A., Curr. Pharmacol. Rep., 2020, vol. 6, p. 167.

    Article  CAS  Google Scholar 

  11. Kaczmarek, M.T., Zabiszak, M., Nowak, M., and Jastrzab, R., Coord. Chem. Rev., 2018, vol. 370, p. 42.

    Article  CAS  Google Scholar 

  12. More, M.S., Joshi, P.G., Mishra, Y.K., and Khanna, P.K., Mater. Today Chem., 2019, vol. 14, p. 100195.

    Article  CAS  Google Scholar 

  13. Malik, M.A., Dar, O.A., Gull, P., et al., Med. Chem. Commun., 2018, vol. 9, no. 3, p. 409.

    Article  CAS  Google Scholar 

  14. Berhanu, A.L., Gaurav, I., Mohiuddin, A.K., et al., Trends Anal. Chem., 2019, vol. 116, p. 74.

    Article  CAS  Google Scholar 

  15. Zhang, J., Xu, L., and Wong, W.-Y., Coord. Chem. Rev., 2018, vol. 355, p. 180.

    Article  CAS  Google Scholar 

  16. Oiye, É.N., Ribeiro, M.F.M., Katayama, J.M.T., et al., CRC Crit. Rev. Anal. Chem., 2019, vol. 49, no. 6, p. 488.

    Article  CAS  Google Scholar 

  17. Udhayakumari, D. and Inbaraj, V., J. Fluoresc., 2020, vol. 30, p. 1203.

    Article  CAS  Google Scholar 

  18. Garnovsky, A.D., Antsyshkina, A.S., Sadikov, G.G., et al., Russ. J. Inorg. Chem., 1995, vol. 40, p. 64.

    Google Scholar 

  19. Kim, Y.-I., Yun, S.-J., Hwang, I.-H., et al., Acta Crystallogr., Sect. E: Struct. Rep. Online, 2012, vol. 68, p. m504.

    Article  CAS  Google Scholar 

  20. Gordon, A. and Ford, R., The Chemist’s Companion: A Handbook of Practical Data, Techniques, and References, New York: Wiley, 1972.

    Google Scholar 

  21. Bruker. APEX3, Madison: Bruker AXS Inc., 2015.

  22. Rigaku Oxford Diffraction. CrysAlisPro. Version 1.171.38.46, Wroclaw: Rigaku Corporation, 2015.

  23. Krause, L., Herbst-Irmer, R., Sheldrick, G.M., and Stalke, D., J. Appl. Crystallogr., 2015, vol. 48, no. 1, p. 3.

    Article  CAS  Google Scholar 

  24. Sheldrick, G.M., Acta Crystallogr., Sect. C: Struct. Chem., 2015, vol. 71, no. 1, p. 3.

    Google Scholar 

  25. Fedushkin, I.L., Tishkina, A.N., Fukin, G.K., et al., Eur. J. Inorg. Chem., 2008, no. 3, p. 483.

  26. Fedushkin, I.L., Skatova, A.A., Ketkov, S.Y., et al., Angew. Chem., Int. Ed. Engl., 2007, vol. 46, p. 4302.

    Article  CAS  Google Scholar 

  27. Batsanov, S.S. Russ. J. Inorg. Chem., 1991, vol. 36, p. 1694.

    Google Scholar 

  28. Briel, O., Fehn, A., Polborn, K., and Beck, W., Polyhedron, 1999, vol. 18, nos. 1–2, p. 225.

    Article  CAS  Google Scholar 

  29. Novoa, N., Roisnel, T., and Hamon, P., Dalton Trans., 2015, vol. 44, no. 41, p. 18019.

    Article  CAS  Google Scholar 

  30. Perez, S., Lopez, C., Caubet, A., et al., J. Organomet. Chem., 2007, vol. 692, p. 2402.

    Article  CAS  Google Scholar 

  31. Pérez, S., López, C., Caubet, A., et al., Eur. J. Inorg. Chem., 2008, vol. 2008, p. 1599.

    Article  Google Scholar 

  32. Baryshnikova, S.V., Poddel’sky, A.I., Cherkasov, A.V., and Smolyaninov, I.V., Inorg. Chim. Acta, 2019, vol. 495, p. 118963.

    Article  CAS  Google Scholar 

  33. Baryshnikova, S.V., Bellan, E.V., Poddel’sky, A.I., et al., Inorg. Chem. Commun., 2016, vol. 69, p. 94.

    Article  CAS  Google Scholar 

  34. Baryshnikova, S.V., Bellan, E.V., Poddel’sky, A.I., et al., Eur. J. Inorg. Chem., 2016, vol. 2016, no. 33, p. 5230.

    Article  CAS  Google Scholar 

  35. Poddel’sky, A.I., Arsenyev, M.V., Astaf’eva, T.V., et al., J. Organomet. Chem., 2017, vol. 835, p. 17.

    Article  Google Scholar 

  36. Poddel’sky, A.I. Astaf’eva, T.V., et al., J. Organomet. Chem., 2018, vol. 873, p. 57.

    Article  Google Scholar 

  37. Baryshnikova, S.V., Poddel’sky, A.I., Bellan, E.V., et al., Inorg. Chem., 2020, vol. 59, no. 10, p. 6774.

    Article  CAS  Google Scholar 

  38. Elmali, A., Elerman, Y., Zeyrek, C.T., and Svoboda, I., Z. Naturforsch. B: J. Chem. Sci., 2003, vol. 58, no. 5, p. 433.

    Article  CAS  Google Scholar 

  39. Wong, J.L., Sanchez, R.H., Logan, J.G., et al., Chem. Sci., 2013, vol. 4, no. 4, p. 1906.

    Article  CAS  Google Scholar 

  40. Klementyeva, S.V., Smolentsev, A.I., Abramov, P.A., and Konchenko, S.N., Inorg. Chem. Commun., 2017, vol. 86, p. 154.

    Article  CAS  Google Scholar 

  41. Klementyeva, S.V., Lukoyanov, A.N., Afonin, M.Yu., et al., Dalton Trans., 2019, vol. 48, p. 3338.

    Article  CAS  Google Scholar 

  42. Piskunov, A.V., Maleeva, A.V., Meshcheryakova, I.N., and Fukin, G.K., Russ. J. Coord. Chem., 2013, vol. 39, p. 245. https://doi.org/10.1134/S107032841303007X

    Article  CAS  Google Scholar 

  43. Meshcheryakova, I.N., Shavyrin, A.S., Cherkasov, A.V., and Piskunov, A.V., Izv. Akad. Nauk, Ser. Khim., 2019, no. 7, p. 1414.

Download references

ACKNOWLEDGMENTS

The studies were performed using research equipment of the Center for Collective Use “Analytical Center of the Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences” at the Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences.

Funding

The studies of zinc salt reactions with o-iminophenol were supported by the Russian Foundation for Basic Research (project no. 19-03-00208a); spectroscopic studies were carried out within the framework of state assignment for the Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences.

Author information

Authors and Affiliations

  1. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia

    N. A. Protasenko, S. V. Baryshnikova, T. V. Astaf’eva, A. V. Cherkasov & A. I. Poddel’sky

Authors
  1. N. A. Protasenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. V. Baryshnikova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. T. V. Astaf’eva
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. V. Cherkasov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. I. Poddel’sky
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. I. Poddel’sky.

Ethics declarations

The authors declare that they have no conflicts of interest.

Additional information

Translated by Z. Svitanko

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Protasenko, N.A., Baryshnikova, S.V., Astaf’eva, T.V. et al. Mono- and Binuclear Zinc Complexes with a Bidentate Phenol-Containing 2-Benzylideneamino-5-Methylphenol Schiff Base. Russ J Coord Chem 47, 417–423 (2021). https://doi.org/10.1134/S1070328421060038

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070328421060038

Keywords:

Search

Navigation