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Micro-Mesoporous Catalyst Based on Natural Aluminosilicate Nanotubes and ZSM-5 Zeolite for Methanol Conversion to Hydrocarbons

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Abstract

A methanol conversion catalyst based on natural aluminosilicate nanotubes and H–ZSM-5 zeolite was synthesized. Its textural, structural, and acid properties were studied by low-temperature nitrogen adsorption–desorption, transmission electron microscopy, X-ray diffraction analysis, and temperature-programmed ammonia desorption. The influence exerted on the methanol conversion and product distribution by the reaction temperature (380–460°С), pressure (0.1–0.5 MPa), and feed space velocity (0.5–1 h–1) was studied. The catalyst based on halloysite aluminosilicate nanotubes showed high selectivity in formation of both lower olefins and aromatic hydrocarbons.

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Funding

The study was financially supported by the Russian Foundation for Basic Research (project no. 20-38-90269). Analysis of gaseous and liquid products of methanol conversion was financially supported by the Ministry of Science and Higher Education of the Russian Federation (agreement with Khromos Inzhiniring no. 075-11-2019-037 of November 22, 2019: Development of High-Tech Production of Boxes for Quality Control of Process Gases and Liquids, Based on On-Line Commercial Chromatographic Analyzers with Using Digital Technologies and Ensuring Monitoring of the Correctness and Reliability of Their Operation in the On-Line Mode, agreement between Khromos Inzhiniring and Gubkin National University of Oil and Gas no. 555-19 of September 20, 2019).

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Authors and Affiliations

  1. Gubkin National University of Oil and Gas, 119991, Moscow, Russia

    E. M. Smirnova, D. P. Melnikov, N. R. Demikhova, M. I. Rubtsova, S. S. Boev, A. P. Glotov & V. A. Vinokurov

  2. Kursk State Agricultural Academy, 305021, Kursk, Russia

    E. E. Brindukova

Authors
  1. E. M. Smirnova
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  2. D. P. Melnikov
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  3. N. R. Demikhova
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  4. M. I. Rubtsova
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  5. S. S. Boev
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  6. E. E. Brindukova
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  7. A. P. Glotov
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  8. V. A. Vinokurov
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Corresponding author

Correspondence to E. M. Smirnova.

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The authors declare no conflict of interest requiring disclosure in this article.

Additional information

Translated from Neftekhimiya, 2021, Vol. 61, No. 4, pp. 532–539 https://doi.org/10.31857/S0028242121040080.

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Smirnova, E.M., Melnikov, D.P., Demikhova, N.R. et al. Micro-Mesoporous Catalyst Based on Natural Aluminosilicate Nanotubes and ZSM-5 Zeolite for Methanol Conversion to Hydrocarbons. Pet. Chem. 61, 773–780 (2021). https://doi.org/10.1134/S0965544121070082

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