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Investigations on dielectric properties of polymer nanocomposites of PANI/Fe2O3

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Abstract

Inorganic compound of iron oxide (Fe2O3) nanoparticles was combined with the conducting polymers, which provides excellent modifications in chemical and physical properties. Therefore, the nanoparticles (NPs) of Fe2O3 synthesized by green combustion method, obtained iron oxide NPs of various quantity doped with polyaniline at 10, 30 and 50 wt%. Polymerization was conducted by in situ polymerization route with ammonium persulphate as an oxidizing agent in aqueous hydrochloric acid solution under constant stirring at 5°C. Characterizations of synthesized samples were carried through XRD analysis. The crystallite size 31 nm is found by using Debye–Scherrer relation, also the grain size is employed to calculate dislocation density and micro strain (η) which is influenced on diffraction-line broadening. And also, dielectric properties of the synthesized samples were studied as a function of frequency that shows the improved interaction between iron oxide nanoparticles and polyaniline. These polymer nanocomposites owe potential applications to the fields of optical, electrical and shielding materials.

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References

  1. Chandrakanthi R L N and Careem M A 2002 Thin Solid Films 417 51

  2. Somani P R, Marimuthu R, Mulik U P, Mulik S R, Sanikar S R and Amalnerkar D 1999 Synth. Met. 106 45

  3. He Y 2005 J. Mater. Chem. Phys. 268 134

  4. Geng L, Zhao Y, Huang X, Wang S, Zhang S and Wu J 2007 Sens. Actuators 34 568

  5. Yu S, Xi M, Jin X, Han K, Wang Z and Zhu H 2010 J. Catal. Commun. 57 1125

  6. Buron C C, Lakard B, Monnin A F, Moutarlier V and Lakard S 2011 Synth. Met. 161 2162

  7. Adhikari B and Majumdar S 2004 Prog. Polym. Sci. 29 699

  8. McQuade D T, Pullen A E and Swager T M 2000 Chem. Rev. 100 2537

  9. Gerard M, Chaubey A and Malhotra B D 2002 Biosens. Bioelectron. 17 345

  10. Chiang J P and MacDiarmid A G 1986 Synth. Met. 13 193

  11. Sugii N, Yamada H, Kagaya O, Yamasaki M, Sekine K, Yamashita K et al 1998 Appl. Phys. Lett. 72 261

    Article  CAS  Google Scholar 

  12. Popielarz R, Chiang C K, Nozaki R and Obrzut J 2001 Macromolecules 34 5910

  13. Koul S, Chandra R and Dhawan S K 2000 Polymer 41 9305

  14. Laberty C, Alphonse P, Demai J J, Sarada C and Rousset A 1997 Mater. Res. Bull. 32 249

  15. Bhuiyan Md S H, Yusuf Miah Md, Shujit Chandra Paul, Das Aka T, Saha O, Rahaman Md M et al 2020 Heliyon 6 e04603

  16. Karade V C, Parit S B, Dawkar V V, Devan R S, Choudhary R J, Kedge V V et al 2019 Heliyon 5 e02044

    Article  CAS  Google Scholar 

  17. Ahmmad B, Leonard K, Islam Md S, Kurawaki J, Muruganandham M, Ohkubo Takahiro et al 2013 Adv. Powder Technol. 24 160

    Article  CAS  Google Scholar 

  18. Jeong J M, Choi B G, Lee S C, Lee K G, Chang Sung-Jin, Han Young-Kyu et al 2013 Adv. Mater. https://doi.org/10.1002/adma.201302710

    Article  Google Scholar 

  19. Wang S, Hu Y, Zong R, Tang Y, Chen Z and Fan W 2004 Appl. Clay Sci. 25 49

    Article  Google Scholar 

  20. Khuspe G D, Navale S T, Bandgar D K, Sakhare R D, Chougule M A and Patil V B 2014 Electron. Mater. Lett. 10 191

    Article  CAS  Google Scholar 

  21. Yang Jing, Deng Wen, Li Qiang, Li Xin, Liang Akun, Su Yuzhu et al 2020 Matter Radiat. Extremes 5 058401

    Article  CAS  Google Scholar 

  22. Bae W J, Jo W H and Park Y H 2003 Synth. Met. 132 239

    Article  CAS  Google Scholar 

  23. Mallikarjuna N N, Manohar S K, Kulkarni P V, Venkataraman A and Aminabhavi T M 2005 J. Appl. Polym. Sci. 97 1868

    Article  CAS  Google Scholar 

  24. Sannakki Nagaraja, Ambalagi S M, Inamdar H K, Bharathi B, Mahalesh D, Ambika Prasad M V N et al 2018 J. Nanosci. Technol. 4 516

  25. Singh Kuldeep, Ohlan Anil, Kotnala R K, Bakhshi A K and Dhawan S K 2008 Mater. Chem. Phys. 112 651

    Article  CAS  Google Scholar 

  26. Bashir T, Shakoor A, Ahmad E, Saeed M, Niaz N A and Tirmizi S K 2015 Polym. Sci. Ser. B 57 257

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Acknowledgements

We are grateful to the Department of Physics and Material Science at GUK, for providing necessary characterization facilities.

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Authors and Affiliations

  1. Department of Physics, Gulbarga University, Kalaburagi, 585106, India

    Bharati Basavaraj & Basavaraja Sannakki

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  1. Bharati Basavaraj
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  2. Basavaraja Sannakki
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Correspondence to Bharati Basavaraj.

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Basavaraj, B., Sannakki, B. Investigations on dielectric properties of polymer nanocomposites of PANI/Fe2O3. Bull Mater Sci 44, 203 (2021). https://doi.org/10.1007/s12034-021-02484-5

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  • DOI: https://doi.org/10.1007/s12034-021-02484-5

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