Abstract
Based on analysis and generalization of the results of studies of the surface (acid-base and adsorption) properties of components of the GaSb–ZnTe system, the regularities of their changes with varying composition are established; it is found that they may both obey Vegard’s rule (exhibit a smooth character) and deviate from it (exhibit an extreme character). The reasons for the appearance of extrema in the property–composition diagrams are explained. Correlations between the surface and bulk properties are found, which are useful not only in scientific but also in practical aspects. The absorbents that are the most active with respect to NH3, CO, and O2 are identified; it is proposed to use them for manufacturing corresponding sensors. The possibility and feasibility of using the results obtained for semiconductor gas analysis are shown.
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REFERENCES
I. A. Kirovskaya, Physical and Chemical Properties of Binary and Multicomponent Diamond-Like Semiconductors. (Sib. Otd. Ross. Akad. Nauk, Novosibirsk, 2015) [in Russian].
Thin Films of Indium Antimonide: Preparation, Properties, Application, Ed. by V. A. Kas’yan et al. (Shtiinca, Kishinev, 1989) [in Russian].
N. P. Gladkikh, The Structure of Thin Films (Kharkiv Nats. Univ., Kharkiv, 2006) [in Russian].
I. A. Kirovskaya, Adsorption Processes (Irkutsk, Gos. Univ., Irkutsk, 1995) [in Russian].
S. S. Gorelik, P. N. Rastorguev, and Yu. A. Skakov, X‑Ray and Electron Microscopic Analysis (Metallurgiya, Moscow, 1970) [in Russian].
E. F. Smyslov, Zavod. Lab., Diagn. Mater. 72 (5), 33 (2006).
L. P. Pavlov, Methods for Measuring Parameters of Semiconductor Materials (Vysshaya Shkola, Moscow, 1975) [in Russian].
L. G. Maidanovskaya, Catalytic Reactions in the Liquid Phase (Akad. Nauk KazSSR, Alma-Ata, 1963) [in Russian].
A. P. Kreshkov, L. N. Bykova, and N. A. Kazaryan, Acid-Base Titration in Nonaqueous Solutions (Khimiya, Moscow, 1967) [in Russian].
L. H. Little, Infrared Spectra of Adsorbed Species (London: Academic, 1966; Mir, Moscow, 1969).
I. A. Kirovskaya, Surface Phenomena (Omsk. Gos. Tekh. Univ., Omsk, 2010) [in Russian].
F. M. Rapoport and A. A. Il’inskaya, Laboratory Methods for Obtaining Pure Gases (Goskhimizdat, Moscow, 1963) [in Russian].
L. V. Novgorodtseva and Yu. D. Glushakova, in Proc. XI Int. Conf. “Student and Scientific and Technological Progress,” (Novosibirsk, 2002), p. 174.
I. A. Kirovskaya, Adsorbents Based on A II B VI –A II B VI Systems—Materials for Semiconductor Gas Analysis (Sib. Otd. Ross. Akad. Nauk, Novosibirsk: 2018) [in Russian].
I. A. Kirovskaya, Solid Solutions of Binary and Multicomponent Semiconductor Systems (Omsk. Gos. Tekh. Univ., Omsk, 2010) [in Russian].
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Kirovskaya, I.A., Novgorodtseva, L.V., Kropotin, O.V. et al. Surface Properties of Binary and Multicomponent Semiconductors of the GaSb–ZnTe System. Regularities of Their Change. J. Surf. Investig. 15, 586–591 (2021). https://doi.org/10.1134/S1027451021030277
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DOI: https://doi.org/10.1134/S1027451021030277