Abstract
Structure, morphology, and composition of the gas for natural gas hydrates sampled in the Kedr-1 mud volcano (Lake Baikal) are studied. It is shown that all these hydrates have cubic structure II, and the hydrate‐bound gas contains about 14% of ethane (the rest is methane). One of the samples is a porous monolithic hydrate layer sandwiched between the layers of hydrate granules. The hydrate has similar structures and compositions in the layer and in the granules. As far as we know, no such morphology features of natural hydrates have been reported so far. Possible mechanisms underlying the formation of such objects are discussed.
Similar content being viewed by others
REFERENCES
Z. R. Chong, S. H. B. Yang, P. Babu, P. Linga, and X.-S. Li. Appl. Energy, 2016, 162, 1633, DOI: 10.1016/j.apenergy.2014.12.061.
V. A. Soloviev. Russ. Geol. Geophys., 2002, 43, 648.
C. Ruppel. J. Chem. Eng. Data, 2015, 60(2), 429, DOI: 10.1021/je500770m.
X.-S. Li, C.-G. Xu, Y. Zhang, X.-K. Ruan, and G. L. Y. Wang. Appl. Energ., 2016, 172, 286, DOI: 10.1016/j.apenergy.2016.03.101.
Y. Cui, C. Lu, M. Wu, Y. Peng, Y. Yao, and W. Luo. Adv. Geo-Energ. Res., 2018, 2(1), 53, DOI: 10.26804/ager.2018.01.05.
A. Hassanpouryouzband, E. Joonaki, M. V. Farahani, S. Takeya, C. Ruppel, J. Yang, N. J. English, J. M. Schicks, K. Edlmann, H. Mehrabian, Z. M. Aman, and B. Tohidi. Chem. Soc. Rev., 2020, 49, 5225, DOI: 10.1039/c8cs00989a.
E. D. Sloan and C. A. Koh. Gas Hydrates of Natural Gases, 3rd ed. CRC Press: Boca Raton, London, New York, 2008.
A. Y. Manakov, V. I. Kosyakov, and S. F. Solodovnikov. Structural Chemistry of Gas Hydrates and Related Compounds. In: Comprehensive Supramolecular Chemistry II / Ed. J. L. Atwood. Elsevier: Oxford, 2017, 161-206.
S. Subramanian, R. A. Kini, S. F. Dec, and E. D. Sloan Jr. Chem. Eng. Sci., 2000, 55, 1981, DOI: 10.1016/S0009-2509(99)00389-9.
S. Soltanimehr, J. Javanmardi, and K. Nasrifar. J. Chem. Eng. Data, 2017, 62(7), 2143, DOI: 10.1021/acs.jced.7b00232.
M. I. Kuzmin, G. V. Kalmychkov, A. D. Duchkov, V. F. Geletii, A. Y. Golmshtok, E. B. Karabanov, B. N. Khakhaev, L. A. Pevzner, H. Ioshida, N. M. Bazhin, Y. A. Dyadin, E. G. Larionov, A. Y. Manakov, M. M. Mandelbaum, and I. F. Vashchenko. Geol. Ore Deposits, 2000, 42(1), 20.
O. M. Khlystov, S. Nishio, A. Y. Manakov, H. Sugiyama, A. V. Khabuev, O. V. Belousov, and M. A. Grachev. Russ. Geol. Geophys., 2014, 55, 1122, DOI: 10.1016/j.rgg.2014.08.007.
O. Khlystov, M. De Batist, H. Shoji, A. Hachikubo, S. Nishio, L. Naudts, J. Poort, A. Khabuev, O. Belousov, A. Manakov, and G. Kalmychkov. J. Asian Earth Sci., 2013, 62, 162, DOI: 10.1016/j.jseaes.2012.03.009.
A. Y. Manakov, O. M. Khlystov, A. Hachikubo, K. Minami, S. Yamashita, A. Khabuev, A. G. Ogienko, A. V. Ildyakov, G. V. Kalmychkov, and T. V. Rodionova. J. Struct. Chem., 2019, 60(9), 1437, DOI: 10.1134/S0022476619090087.
M. Kida, O. Khlystov, T. Zemskaya, N. Takahashi, H. Minami, H. Sakagami, A. Krylov, A. Hachikubo, S. Yamashita, H. Shoji, J. Poort, and L. Naudts. Geophys. Res. Lett., 2006, 33(24), L24603, DOI: 10.1029/2006GL028296.
A. Y. Manakov, O. M. Khlystov, A. Hachikubo, and A. G. Ogienko. Russ. Geol. Geophys., 2013, 54(4), 475, DOI: 10.1016/j.rgg.2013.03.009.
A. Hachikubo, H. Minami, S. Yamashita, A. Khabuev, A. Krylov, G. Kalmychkov, J. Poort, M. De Batist, A. Chenskiy, A. Manakov, and O. Khlystov. Sci. Rep., 2020, 10, 14747, DOI: 10.1038/s41598-020-71410-2.
O. M. Khlystov, E. E. Kononov, H. Minami, A. V. Kazakov, A. V. Khabuev, N. A. Gubin, and A. G. Chenskii. Geogr. Nat. Resour., 2018, 1, 59, DOI: 10.21782/GiPR0206-1619-2018-1(59-65).
H. Minami, A. Hachikubo, S. Yamashita, H. Sakagami, R. Kasashima, M. Konishi, H. Shoji, N. Takahashi, T. Pogodaeva, A. Krylov, A. Khabuev, A. Kazakov, M. De Batist, L. Naudts, A. Chensky, N. Gubin, and O. Khlystov. Geo-Mar. Lett., 2018, 38, 403, DOI: 10.1007/s0036 7-018-0542-x.
G. V. Kalmychkov, B. G. Pokrovsky, A. Hachikubo, and O. M. Khlystov. Lithol. Min. Resour., 2017, 52, 102, DOI: 10.1134/S0024490217020055.
K. Rottger, A. Endriss, J. Ihringer, S. Doyle, and W. F. Kuhs. Acta Crystallogr., Sect. B, 1994, 50, 644, DOI: 10.1107/S0108768194004933.
CHECKCELL. http://www.cristal.org/SDPD-list/2000/msg00083.html (accessed May 5, 2020).
S. Takeya, T. Uchida, Y. Kamata, J. Nagao, M. Kida, H. Minami, H. Sakagami, A. Hachikubo, N. Takahashi, H. Shoji, O. Khlystov, M. Grachev, and V. Soloviev. Angew. Chem., Int. Ed., 2005, 44, 6928, DOI: 10.1002/anie.200501845.
C. J. Rawn, A. J. Rondinone, B. C. Chakoumakos, S. L. Marshall, L. A. Stern, S. Circone, S. H. Kirby, C. Y. Jones, B. H. Toby, and Y. Ishii. In: Proc. 4th Int. Conf. Gas Hydrate. Yokohama, 2002, 595.
K. C. Hester, Z. Huo, A. L. Ballard, C. A. Koh, K. T. Miller, and E. D. Sloan. J. Phys. Chem. B, 2007, 111, 8830, DOI: 10.1021/jp0715880.
A. Y. Manakov, A. Y. Likhacheva, V. A. Potemkin, A. G. Ogienko, A. V. Kurnosov, and A. I. Ancharov. ChemPhysChem, 2011, 12(13), 2476, DOI: 10.1002/cphc.201100126.
E. Spangenberg, M. Priegnitz, K. Heeschen, and J. M. Schicks. J. Chem. Eng. Data, 2015, 60(2), 258, DOI: 10.1021/je5005609.
W. F. Waite, J. C. Santamarina, D. D. Cortes, B. Dugan, D. N. Espinoza, J. Germaine, J. Jang, J. W. Jung, T. J. Kneafsey, H. Shin, K. Soga, W. J. Winter, and T.-S. Yun. Rev. Geophys., 2009, 47, RG4003, DOI: 10.1029/2008RG000279.
G. D. Ginsburg and V. A. Soloviev. Submarin. Gaz. Gidrat. (Submarine Gas Hydrates) [in Russian]. VNIIOkeangeologiya: Saint Petersburg, Russia, 1994.
W. F. Kuhs, G. Genov, E. Goreshnik, A. Zeller, K. S. Techmer, and G. Bohrmann. Int. J. Offshore Polar Eng., 2004, 14(4), 305.
Funding
The work was supported by basic research programs of NIIC SB RAS (No. 0236-2021-0001) and LIN SB RAS (No. 0279-2021-0006).
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
The authors declare that they have no conflict of interests.
Additional information
Russian Text © The Author(s), 2021, published in Zhurnal Strukturnoi Khimii, 2021, Vol. 62, No. 6, pp. 958-965.https://doi.org/10.26902/JSC_id74424
Rights and permissions
About this article
Cite this article
Manakov, A.Y., Khlystov, O.M., Sagidullin, A.K. et al. STRUCTURE, MORPHOLOGY, AND COMPOSITION OF NATURAL GAS HYDRATES SAMPLED IN THE KEDR-1 MUD VOLCANO (LAKE BAIKAL). J Struct Chem 62, 889–896 (2021). https://doi.org/10.1134/S0022476621060081
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0022476621060081