Skip to main content
SpringerLink
Log in

Effect of Quaternary Element (Ni and Mn) Additions on Structural and Magnetic Properties of Cu-Based Alloys

  • Condensed Matter
  • Published:
Brazilian Journal of Physics Aims and scope Submit manuscript

Abstract

We investigated the quaternary Cu-25.49%Zn-7.68%Al-3.44%Ni and Cu-26.03%Zn-6.31%Al-2.73%Mn (wt. %) alloys according to their structural and magnetic properties. For structural observations, we employed X-ray diffraction (XRD), scanning electron microscope (SEM), and electron dispersion spectroscopy (EDS) techniques to study. The magnetic properties of alloys were characterized as a function of temperature (T) and applied external magnetic field (H) by using Physical Properties Measurement System (PPMS) magnetometry. According to SEM and XRD observations, the existing microstructures consist of two types of precipitates that are namely α and intermetallic κ-phases in CuZnAlNi alloy. We also observed the austenite phase in CuZnAlMn alloy. The M-H magnetization curves exhibited obvious paramagnetic behavior for the examined alloys. Although Ni and Mn elements have similar magnetic nature, they show different magnetic characteristics with different structures.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  1. D.C. Lagoudas, Shape Memory Alloys Modeling and Engineering Applications (Springer, New York, 2008)

    MATH  Google Scholar 

  2. S.K. Vajpai, R.K. Dube, S. Sangal, Mat. Sci. Eng. A 378 (2011)

  3. F.C. Lovey, A.M. Condo, J. Guimpel, M.J. Yucaman, Mat. Sci. Eng. A 426 (2008)

  4. J.M. Jani, M. Leary, A. Subic, M.A. Gibson, Mater. Design (1980–2015) 56, 1078 (2014)

  5. M.R. da Silva, P. Gargarella, T. Gustmann, W.J. Botta Filho, C.S. Kiminami, J. Eckert et al., Mater. Sci. Eng. A 661, 61 (2016)

    Article  Google Scholar 

  6. G. Lojen, M. Gojić, I. Anžel, J Alloys Comp. 580, 497 (2013)

    Article  Google Scholar 

  7. A.L. Roytburd, Kurdjumovand His School in Martensite of the 20th Century. Mat. Sci. Eng. A 273–275, 1 (1999)

    Article  Google Scholar 

  8. S. Wu, D. Wang, Z. Zhang, C. Li, X. Liu, X. Meng, Z. Feng, X. Di, Sci. Tech. Weld. Join. 24(2), 112 (2019)

    Article  Google Scholar 

  9. L. Morales-Rivas, F. Archie, S. Zaefferer, M. Benito-Alfonso, S.P. Tsai, J.R. Yang, et al., J Alloys Comp. 752, 505 (2018)

  10. S.N.S. Al-Humairi, Cu-Based Shape Memory Alloys: Modified Structures and Their Related Properties, Recent Adv in Eng Mater Metall. Intech Open (2019)

  11. D.A. Porter, K.E. Easterling, Phase Transformations in Metals and Alloys (CRC Press, Cheltenham, 2001).

    Google Scholar 

  12. Z. Nishiyama, M.E. Fine, C.M. Wayman, MartensiticTransformation (Academic Press, New York, 1978).

    Google Scholar 

  13. S.Q. Zhang Xiangyang, Y. Shouwen, J. Mec. Phys. Solids. 48, 2163 (2000)

    Article  ADS  Google Scholar 

  14. Y. Sutou, R. Kainuma, K. Ishida, Mater. Sci. Eng. A 273–275, 375 (1999)

    Article  Google Scholar 

  15. C. Canbay Aksu, A. Aydoğdu, Y. Aydoğdu, J Supercond. Nov. Magn. 24, 871 (2011)

    Article  Google Scholar 

  16. R. Rapacioliand, M. Ahlers, Scr. Metall. 11, 1147 (1977)

    Article  Google Scholar 

  17. S. Miyazaki, K. Otsuka, Iron Steel Inst. Jpn. Int. 29, 353 (1989)

    Article  Google Scholar 

  18. C. Mlarr, Mater. Sci. Eng. A. 273–275, 577 (1999)

    Google Scholar 

  19. A. Agrawal, R.K. Dube, J. Alloys Comp. 750, 235 (2018)

    Article  Google Scholar 

  20. N. Safaa, E. Saud, T. Hamzah, M.K. Abubakar, B. Ibrahim, J. Abdollah, Mater. Res. 30, 2258 (2015)

  21. R.A. Dunlap, G. Stroink, K. Dini, J. Phys. F: Met. Phys. 16, 1083 (1986)

  22. B.D. Cullity, Introduction to Magnetic Materials (Addison-Wesley Reading)(1972)

  23. D. Jiles, Introduction to Magnism and Magnetic materials (Chapman and Hall)(1991)

  24. M.O. Prado, F.C. Lovey, L. Civale, Acta Mater. 46, 137 (1998)

    Article  ADS  Google Scholar 

  25. F. Dagdelen, T. Gokhan, A. Aydogdu, Y. Aydogdu, O. Adigüzel, Mater. Letters. 57(5–6), 1079 (2003)

    Google Scholar 

  26. Y.E. Gerdan, E. Aldirmaz, M. Guler, H. Tanak, E. Guler, J. Supercon, Novel Magnet. 31, 3919 (2018)

  27. V. Asanovic, K. Delijic, N. Jaukovic, Scr. Mater. 58(7), 599 (2008)

    Article  Google Scholar 

  28. A.K. Bhuniya, Mat. Sci. Eng. A 125 (2005)

  29. M.O. Moroni, R. Saldivia, M. Sarrazin, A. Sepu´lveda, Mater. Sci. Eng. A 335, 313 (2002)

    Article  Google Scholar 

  30. A. Caneiro, M. Chandrasekaran, Scr. Metall. 22, 1797 (1988)

    Article  Google Scholar 

  31. M. Ahlers, Prog. Mater. Sci. 135 (1986)

  32. J. Lelatko, H. Morawiec, J Mater Sci 31, 2767 (1996)

    Article  ADS  Google Scholar 

  33. B.P. Pisarek, Archives of Foundry Eng. 13, 72 (2013)

    Article  Google Scholar 

  34. E.J. Gutiérrez Castañeda, R.E. Barreras Castro, A. Contreras Briseño, B. Fernández Arguijo, A.A. Torres Castillo, A. Salinas Rodríguez, et al., Magnetochem. 5, 48 (2019)

  35. K.K Alaneme, A. Eloho Okotete, N. Maledi, J. Mater. Res. Technol. 6(2), 136 (2017)

  36. K.K. Alaneme, S. Umar, J Sci. Adv. Mater. Devices 3, 371 (2018)

    Article  Google Scholar 

  37. M.S. Nascimento, G. Alves dos Santos, R. Teram, V. Torres dos Santos, M. Rodrigues da Silva, A. Augusto Couto, Mater. 12, 1267 (2019)

  38. E.A. Culpan, G. Rose, J. Mater. Sci. 13, 1647 (1978)

    Article  ADS  Google Scholar 

  39. T. Lyman, E.A. Durand, P.M. Unterweiser, (Eds.), Metals Handbook, vol.8, 8th Edition, (American Society for Metals, Metals Park, OH)(1973)

  40. U.S. Mallik, V. Sampath, J. Alloys Comp. 469, 156 (2009)

    Article  Google Scholar 

  41. S. Kajiwara, T. Kikuchi, Acta Metall. 30, 589 (1982)

  42. L.G. Bujoreanu, Mater. Sci. Eng. A 481–482, 395 (2008)

    Article  Google Scholar 

  43. L. Eon-Sik, K. Young, Scr. Metal. Mater. 24, 745 (1990)

    Article  Google Scholar 

  44. Y. Deng, G.S. Ansell, Acta Metall. Mater. 38, 69 (1990)

    Article  Google Scholar 

  45. P.K. Yoo, G.S. Jeen, H.Y. Park, J. Mat. Sci. Lett. 13, 23 (1994)

  46. X. Sun, C. Jing, C. Liu, M. Ye, Y. Huang, G. Zhang, Phase Trans. 92, 13 (2019)

  47. A. Isalgue, V. Torra, J. Phys. IV France 11 (2001)

  48. A. Planes, L.I. Mafiosa, E. Vives, J. Rodriguez-Carvajal, M. Morins, G. Guenin, J.L. Macqueron, J. Phys.: Condens. Matter 4, 553 (1992)

  49. W.B. Pearson, In: Raynor G V, (eds.), A Handbook Of Lattice Spacings and Structures of Metals and Alloys (Pergamon Press, New York, 1958)

    Google Scholar 

  50. S. Alkan, Y. Wu, A. Ojha, H. Sehitoglu, Acta Mater. 149, 220 (2018)

  51. A.T. Isalgué, V. Torra, J. Fernandez, F.C. Lovey, Mater. Sci. Eng. A 378, 227 (2004)

    Article  Google Scholar 

  52. P.K. Yoo, G.S. Jeen, H.Y. Park, H.Y. Kim, S.T. Park, H.C. Lee, J.B. Park, J. Mat. Sci. Lett. 17, 173 (1998)

  53. B.A. Kolachev, A.A. Ilyin, P.D. Drozdov, Izv. Vuzov Tsvetn. Met. 6, 41 (1997)

  54. N.S. Stoloff, R.G. Davies, Mechanical Properties of Ordering Alloys (Metallurgiya Moscow, Russian Translation, 1969).

    Google Scholar 

  55. M. Kok, Z.D. Yakinci, A. Aydogdu, Y. Aydogdu, J Therm. Anal. Calorim. 115, 555 (2014)

    Article  Google Scholar 

  56. D. Abbe, R. Caudront, R. Pynn, Phys. F: Met. Phys. 14, 1117 (1984)

  57. E.H. Williams, Phsic. Rev. 828 (1931)

  58. E. Aldirmaz, M. Guler, E. Guler, J. Superconduct. Novel Magn. 33, 755 (2020)

  59. K. Oikawa, N. Koeda, Y. Sutou, T. Omori, R. Kainuma, K. Ishida, Mater. Trans. 45, 2780 (2004)

    Google Scholar 

Download references

Funding

This study was financially supported by the Amasya University under Project No. FMB-BAP 19–0405.

Author information

Authors and Affiliations

  1. Department of Physics, Amasya University, Amasya, Turkey

    E. Aldirmaz

  2. Department of Physics, Ankara Hacı Bayram Veli University, Ankara, Turkey

    M. Güler & E. Güler

Authors
  1. E. Aldirmaz
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. Güler
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. Güler
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to E. Aldirmaz.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Aldirmaz, E., Güler, M. & Güler, E. Effect of Quaternary Element (Ni and Mn) Additions on Structural and Magnetic Properties of Cu-Based Alloys. Braz J Phys 51, 1224–1229 (2021). https://doi.org/10.1007/s13538-021-00926-3

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s13538-021-00926-3

Keywords

Search

Navigation