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Influence of the Structure of the Aminoalkyl Group in Polysiloxane on the Selectivity of Its Interaction with Metal Ions

  • Inorganic Synthesis and Industrial Inorganic Chemistry
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Abstract

Polysiloxanes containing nonchelating 3-aminopropyl and chelating N-(2-aminoethyl)-3-aminopropyl groups with the degree of functionalization of 28 and 24%, respectively, were prepared by sol–gel synthesis. The polysiloxanes obtained showed comparable activity in sorption of Pd(II), Pt(IV), Fe(III), Cd(II), Zn(II), Co(II), Ni(II), Cu(II), Mn(II), Pb(II), Ca(II), and Mg(II) ions from model multicomponent solutions. At pH < 3,3-aminopropylpolysiloxane selectively takes up platinoid ions. The chelating structure of N-(2-aminoethyl)-3-aminopropyl groups leads to a decrease in the selectivity of the interaction with Pd(II) ions but increases the affinity for Fe(III), Ni(II), and Cu(II). Preconcentration in the dynamic mode allows quantitative sorption of Pd(II) and Pt(IV), followed by virtually quantitative elution of the metal ions from the sorbent surface.

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ACKNOWLEDGMENTS

The authors are grateful to Cand. Sci. (Chem.), Assistant Prof. of the Chair of Analytical and Environmental Chemistry, Ural Federal University M.V. Morozova for analyzing the sorbate solutions with an iCAP 6500 Duo atomic emission spectrometer.

Funding

The study was financially supported by the Russian Federation Government, resolution no. 211, contract no. 02.A03.21.0006. The sorbents were synthesized within the framework of the government assignment for the Postovsky Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences (themes AAAA-A19-119012490006-1 and AAAA-A19-119012290117-6).

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Correspondence to A. S. Kholmogorova or A. V. Pestov.

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Translated from Zhurnal Prikladnoi Khimii, No. 4, pp. 482–490, January, 2021 https://doi.org/10.31857/S0044461821040071

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Kholmogorova, A.S., Fedoseeva, E.A., Neudachina, L.K. et al. Influence of the Structure of the Aminoalkyl Group in Polysiloxane on the Selectivity of Its Interaction with Metal Ions. Russ J Appl Chem 94, 478–485 (2021). https://doi.org/10.1134/S1070427221040078

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