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AgNO3 COMPLEXES WITH 15-CROWN-5 AND DIBENZO-18-CROWN-6

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Abstract

Two new complexes of silver nitrate with crown ethers are prepared and structurally characterized. The diffusion of diethyl ether vapor into the reaction solution results in the crystallization of [Ag(15C5)(NO3)] (15C5 = 15-crown-5) (1) and [Ag(DB18C6)(NO3)]·DMF (DB18C6 = dibenzo-18-crown-6) (2). Both complexes are characterized by single crystal XRD, powder XRD, IR spectroscopy, and elemental analysis.

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Funding

The work was supported by the RFBR grant No. 8-33-20067.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    A. V. Chupina, P. A. Abramov & M. N. Sokolov

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  1. A. V. Chupina
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  2. P. A. Abramov
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  3. M. N. Sokolov
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Correspondence to A. V. Chupina.

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The authors declare that they have no conflict of interests.

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Russian Text © The Author(s), 2021, published in Zhurnal Strukturnoi Khimii, 2021, Vol. 62, No. 5, pp. 765-771.https://doi.org/10.26902/JSC_id72875

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Chupina, A.V., Abramov, P.A. & Sokolov, M.N. AgNO3 COMPLEXES WITH 15-CROWN-5 AND DIBENZO-18-CROWN-6. J Struct Chem 62, 711–717 (2021). https://doi.org/10.1134/S0022476621050073

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  • DOI: https://doi.org/10.1134/S0022476621050073

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