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STRUCTURAL FEATURES OF CADMIUM(II) COMPLEXES WITH BIS(BENZIMIDAZOL-2-YL)METHANE

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Abstract

A series of cadmium(II) coordination compounds with bis(benzimidazol-2-yl)methane (L) is synthesized. Single crystals are obtained, and molecular and crystal structures of [Cd4(L)4Cl6(EtOH)0.77(H2O)1.23] [CdCl4]·H2O·5EtOH, [Cd(L)I2], and [Cd(L)2(EtOH)2][Cd(L)(NO3)3]2·6EtOH complexes are determined. According to the single crystal X-ray diffraction analysis, the organic ligand has a bidentate cyclic coordination. Distinctions in the structures of the compounds depending on the anion present are observed. The [Cd(L)I2] complex is mononuclear with cadmium ions are in the tetrahedral environment. Cadmium chloride and nitrate complexes are cationic-anionic with cadmium ions in different environments, and their coordination numbers vary in the range of 4-7.

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REFERENCES

  1. H. Y. Zhao, F. L. Yang, N. Li, and X. J. Wang. J. Mol. Struct., 2017, 1148, 62, DOI: 10.1016/j.molstruc.2017.07.013.

    Article  CAS  Google Scholar 

  2. X. Du, Y. Y. Wang, Y. Q. Zhao, and G. H. Cui. J. Struct. Chem., 2014, 55(4), 734, DOI: 10.1134/S0022476614040222.

    Article  CAS  Google Scholar 

  3. Y. H. Wen, C. G. Chen, H. L. Wen, X. W. Mu, and K. Yao. J. Chem. Crystallogr., 2018, 48, 12, DOI: 10.1007/s10870-018-0711-9.

    Article  CAS  Google Scholar 

  4. M. Rodriguez-Cordero, N. Cigüela, L. Llovera, T. González, A. Briceño, V. R. Landaeta, and J. Pastrán. Inorg. Chem. Commun., 2018, 91, 124, DOI: 10.1016/j.inoche.2018.03.019.

    Article  CAS  Google Scholar 

  5. B. Roopashree, V. Gayathri, and H. Mukund. J. Coord. Chem., 2012, 65, 1354, DOI: 10.1080/00958972.2012.673123.

    Article  CAS  Google Scholar 

  6. S. L. Xiao, Y. H. Li, P. J. Ma, and G. H. Cui. Inorg. Chem. Commun., 2013, 37, 54, DOI: 10.1016/j.inoche.2013.09.047.

    Article  CAS  Google Scholar 

  7. Q. X. Liu, Q. Wei, X. J. Zhao, H. Wang, S. J. Li, and X. G. Wang. Dalton Trans., 2013, 42, 5902, DOI: 10.1039/C3DT33013C.

    Article  CAS  PubMed  Google Scholar 

  8. Z. Liu, Y. Chen, P. Liu, J. Wang, and M. Huang. J. Solid State Chem., 2005, 178, 2306, DOI: 10.1016/j.jssc.2005.04.037.

    Article  CAS  Google Scholar 

  9. A.L. Li, D. Liu, Y. H. Li, and G. H. Cui. J. Mol. Struct., 2019, 1195, 514, DOI: 10.1016/j.molstruc.2019.06.013.

    Article  CAS  Google Scholar 

  10. J. Li, L. Li, H. Hou, Y. Fan, and L. Gao. Inorg. Chim. Acta, 2009, 362, 4671, DOI: 10.1016/j.ica.2009.06.035.

    Article  CAS  Google Scholar 

  11. X. Liu, X. Guo, Y. Niu, Q. Wang, Q. Cui, H. Hou, X. Lv, and S. Ng. J. Chem. Crystallogr., 2009, 39, 147, DOI: 10.1007/s10870-008-9445-4.

    Article  CAS  Google Scholar 

  12. X. B. Liu, Y. Q. Zhao, W. L. Liu, and G. H. Cui. J. Struct. Chem., 2017, 58(4), 750, DOI: 10.1134/S0022476617040151.

    Article  CAS  Google Scholar 

  13. C. H. He, C. H. Jiao, J. C. Geng, and G. H. Cui. J. Coord. Chem., 2012, 65, 2294, DOI: 10.1080/00958972.2012.692783.

    Article  CAS  Google Scholar 

  14. S. L. Xiao, X. Du, L. Qin, C. H. He, and G. H. Cui. J. Inorg. Organomet. Polym. Mater., 2012, 22, 1384, DOI: 10.1007/s10904-012-9742-4.

    Article  CAS  Google Scholar 

  15. R. Yang, W. C. Xiao, K. Van Hecke, and G. H. Cui. J. Inorg. Organomet. Polym. Mater., 2015, 25, 772, DOI: 10.1007/s10904-014-0157-2.

    Article  CAS  Google Scholar 

  16. I. Nawrot, K. Czerwińska, B. Machura, and R. Kruszynski. J. Lumin., 2017, 181, 103, DOI: 10.1016/j.jlumin.2016.08.032.

    Article  CAS  Google Scholar 

  17. W. Dai and D. W. Fu. Acta Crystallogr., Sect. E: Struct. Rep. Online, 2008, 64, m1017, DOI:10.1107/S1600536808006454.

    Article  CAS  Google Scholar 

  18. C. K. Xia, W. Wu, L. Y. Huang, and J. M. Xie. Acta Crystallogr., Sect. E: Struct. Rep. Online, 2007, 63, m2981, DOI: 10.1107/S1600536807056188.

    Article  CAS  Google Scholar 

  19. J. H. Qin and X. D. Han. Z. Kristallogr. - New Cryst. Struct., 2012, 227, 7, DOI: 10.1524/ncrs.2012.0004.

    Article  Google Scholar 

  20. C. H. Jiao, J. C. Geng, C. H. He, and G. H. Cui. J. Mol. Struct., 2012, 1020, 134, DOI: 10.1016/j.molstruc.2012.03.051.

    Article  CAS  Google Scholar 

  21. H. Yang, X. Meng, Y. Liu, H. Hou, Y. Fan, and X. Shen. J. Solid State Chem., 2008, 181, 2178, DOI: 10.1016/j.jssc.2008.04.045.

    Article  CAS  Google Scholar 

  22. X. X. Zhao, D. Liu, Y. H. Li, and G. H. Cui. Polyhedron, 2018, 156, 200, DOI: 10.1016/j.poly.2018.09.041.

    Article  CAS  Google Scholar 

  23. S. Y. Hao, S. X. Hou, Z. C. Hao, and G. H. Cui. Spectrochim. Acta, Part A, 2018, 189, 613, DOI: 10.1016/j.saa.2017.08.073.

    Article  CAS  Google Scholar 

  24. Y. Wang, H. B. Xu, Z. M. Su, K. Z. Shao, Y. H. Zhao, H. P. Cui, Y. Q. Lan, and X. R. Hao. Inorg. Chem. Commun., 2006, 9, 1207, DOI: 10.1016/j.inoche.2006.07.028.

    Article  CAS  Google Scholar 

  25. X. L. Wang, J. X. Zhang, L. L. Hou, G. C. Liu, H. Y. Lin, and A. X. Tian. J. Coord. Chem., 2011, 64, 1177, DOI: 10.1080/00958972.2011.564616.

    Article  CAS  Google Scholar 

  26. C. H. Jiao, C. H. He, J. C. Geng, and G. H. Cui. J. Coord. Chem., 2012, 65, 2852, DOI: 10.1080/00958972.2012.706283.

    Article  CAS  Google Scholar 

  27. J. W. Zhang, X. M. Kan, X. H. Li, C. H. Gong, A. X. Tian, and X. L. Wang. Z. Anorg. Allg. Chem., 2014, 640, 1293, DOI: 10.1002/zaac.201400019.

    Article  CAS  Google Scholar 

  28. A. A. Lamkadden, F. Capitelli, E.-M. Essassi, M. Harcharras, A. A. Larena, and A. Ennaciri. J. Maroc. Chim. Heterocycl., 2010, 9, 9, DOI: 10.48369/IMIST.PRSM/jmch-v9i1.2892.

  29. E. M. Essassi, A. Lamkadem, and R. Zniber. Bull. Soc. Chim. Belg., 1991, 100, 277, DOI: 10.1002/bscb.19911000313.

    Article  Google Scholar 

  30. S. S. Al-Juaid, N. H. Buttrus, C. Eaborn, P. B. Hitchcock, J. D. Smith, and K. Tavakkoli. J. Chem. Soc., Chem. Commun., 1988, 1389, DOI: 10.1039/C39880001389.

    Article  Google Scholar 

  31. W. Ouellette, B. S. Hudson, and J. Zubieta. Inorg. Chem., 2007, 46, 4887, DOI: 10.1021/ic062269a.

    Article  CAS  PubMed  Google Scholar 

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Funding

The work was performed within the State Contract of the Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences for basic scientific research.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    K. S. Smirnova, T. S. Sukhikh, S. A. Adonin & E. V. Lider

  2. Novosibirsk State University, Novosibirsk, Russia

    T. S. Sukhikh, I. V. El’tsov & E. V. Lider

Authors
  1. K. S. Smirnova
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  2. T. S. Sukhikh
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  3. S. A. Adonin
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  4. I. V. El’tsov
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  5. E. V. Lider
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Correspondence to E. V. Lider.

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Russian Text © The Author(s), 2021, published in Zhurnal Strukturnoi Khimii, 2021, Vol. 62, No. 5, pp. 772-780.https://doi.org/10.26902/JSC_id72884

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Smirnova, K.S., Sukhikh, T.S., Adonin, S.A. et al. STRUCTURAL FEATURES OF CADMIUM(II) COMPLEXES WITH BIS(BENZIMIDAZOL-2-YL)METHANE. J Struct Chem 62, 718–726 (2021). https://doi.org/10.1134/S0022476621050085

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