Skip to main content
Log in

Mathematical Model of Rectification Process and Selection of the Separation Sequence for Multicomponent Mixtures

  • Published:
Mathematical Models and Computer Simulations Aims and scope

Abstract

Based on the equations of thermodynamic balances, a model of a stationary non-equilibrium distillation process is proposed. It is shown that the heat consumption for any given efficiency of a distillation column depends monotonically on the parameters of the reversible distillation. Using this result, the authors propose an algorithm for choosing the optimal separation sequence for a system of several columns used for multicomponent distillation process; this algorithm is based on the criterion of the minimum of the total energy consumption with the use of the coefficient of thermal efficiency which depends on the still and dephlegmator temperatures. The algorithm for calculating the coefficient of thermal efficiency in the mixture fractionation process is proposed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.

Similar content being viewed by others

REFERENCES

  1. I. A. Aleksandrov, Rectification and Absorption Apparatus (Khimiya, Moscow, 1978) [in Russian].

    Google Scholar 

  2. I. A. Aleksandrov, Distillation and Rectification in Oil Refining (Khimiya, Moscow, 1981) [in Russian].

    Google Scholar 

  3. S. A. Bagaturov, Fundamentals of the Theory and Calculation of Distillation and Rectification (Khimiya, Moscow, 1978) [in Russian].

    Google Scholar 

  4. F. B. Petlyuk and L. A. Serafimov, Multicomponent Rectification. Theory and Calculation (Khimiya, Moscow, 1983) [in Russian].

    Google Scholar 

  5. V. B. Kogan, Azeotropic and Extractive Rectification (Khimiya, Moscow, 1971) [in Russian].

    Google Scholar 

  6. C. D. Holland, Fundamentals of Multicomponent Distillation (McGraw-Hill, New York, 1981).

    Google Scholar 

  7. H. Z. Kister, Distillation Design (McGraw-Hill, New York, 1992).

    Google Scholar 

  8. L. A. Serafimov, T. V. Chelyuskina, and P. O. Mavletkulova, “Finding optimal multicomponent distillation flowsheets,” Theor. Found. Chem. Eng. 49 (1), 41–49 (2015).

    Article  Google Scholar 

  9. G. M. Ostrovskii, N. N. Ziyatdinov, F. U. Mustafina, and D. A. Rygov, “Optimal synthesis of a system of simple distillation columns,” Theor. Found. Chem. Eng. 47 (6), 709–718 (2013).

    Article  Google Scholar 

  10. A. I. Balunov and V. P. Maikov, “Entropy and information in the theory of rectification,” Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol. 46 (9), 54–67 (2003).

    Google Scholar 

  11. A. M. Tsirlin, Irreversible Estimates of the Limiting Capabilities of Thermodynamic and Microeconomic Systems (Nauka, Moscow, 2003) [in Russian].

    Google Scholar 

  12. A. Tsirlin, I. A. Sukin, A. Balunov, and K. Schwalbe, “The rule of temperature coefficient for selection of optimal separation sequence for multicomponent mixtures in thermal systems,” J. Non-Equilib. Thermodyn. 42 (4), 359–369 (2017).

    Article  Google Scholar 

  13. I. Prigogine and R. Defay, Chemical Thermodynamics (Longmans Green, London, 1954; Nauka, Novosibirsk, 1966).

  14. A. M. Tsirlin, A. I. Balunov, and I. A. Sukin, “Estimates of energy consumption and selection of optimal distillation sequence for multicomponent distillation,” Theor. Found. Chem. Eng. 50 (3), 250–259 (2016).

    Article  Google Scholar 

  15. R. C. Reid, J. M. Prausnitz, and T. K. Sherwood, The Properties of Gases and Liquids (McGraw-Hill, New York, 1977; Khimiya, Leningrad, 1982).

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to A. M. Tsirlin.

Additional information

Translated by E. Smirnova

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Tsirlin, A.M., Sukin, I.A. & Balunov, A.I. Mathematical Model of Rectification Process and Selection of the Separation Sequence for Multicomponent Mixtures. Math Models Comput Simul 13, 483–491 (2021). https://doi.org/10.1134/S2070048221030182

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S2070048221030182

Keywords:

Navigation