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Transport Numbers of Singly-, Doubly- and Triply-Charged Cations in Porous Glasses

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Abstract

Transport numbers of sodium, nickel, and lanthanum counterions have been studied in microporous (average pore radius is r = 2–3.4 nm) and macroporous (r = 16–27 nm) magnetite-free glasses and those containing magnetite in their matrices. It has been found that, in the case of microporous glasses, the relation between the transport numbers of the studied cations is primarily governed by the structure of secondary silica in pore channels. For membranes prepared from macroporous glasses, the transport numbers of the cations in the pore space depend on the surface charge magnitude and the structure of the electrical double layer.

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ACKNOWLEDGMENTS

We are grateful to Prof. N.V. Chezhina for valuable consultations and I.N. Anfimova for the help in the preparation of glasses. The two-phase glasses were obtained at the Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences (subject no. 0097-2019-0015).

Funding

This work was supported by the Russian Foundation for Basic Research, project no. 20-03-00544a.

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Authors and Affiliations

  1. St. Petersburg State University, 199034, St. Petersburg, Russia

    L. E. Ermakova & A. S. Kuznetsova

  2. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, 199034, St. Petersburg, Russia

    A. S. Kuznetsova & T. V. Antropova

Authors
  1. L. E. Ermakova
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  2. A. S. Kuznetsova
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  3. T. V. Antropova
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Correspondence to L. E. Ermakova.

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Translated by A. Kirilin

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Ermakova, L.E., Kuznetsova, A.S. & Antropova, T.V. Transport Numbers of Singly-, Doubly- and Triply-Charged Cations in Porous Glasses. Colloid J 83, 294–301 (2021). https://doi.org/10.1134/S1061933X21030030

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  • DOI: https://doi.org/10.1134/S1061933X21030030

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