Skip to main content
SpringerLink
Log in

Facile Synthesis of Micro CuO Crystals for Li Ion Full Battery

  • Communications
  • Published:
Journal of Inorganic and Organometallic Polymers and Materials Aims and scope Submit manuscript

Abstract

Micro CuO crystals are synthesized by hydrothermal method in one step. The CuO-Li ion full battery is assembled using the porous lithium foil-graphite as a anode and the prepared CuO crystals as a cathode. The micro CuO crystals are characterized by scanning electron micro porousscopy, X-ray powder diffractometer, Fourier Transform infrared spectrometer, thermogravimeter, Brunauer–Emmett–Teller surface area measurements, and differential scanning calorimeter. The full battery is tested by the galvanostatic current charge-discharge technology at higher current densities of 0.25–0.5 mA/cm2. The porous lithium foil-graphite anode can effectively inhibit the powder of anode lithium, and improve the reversibility of the battery.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

References

  1. Z. Zhang, M. Zhang, P. Lu, Q. Chen, H. Wang, Q. Liu, CuO nanorods growth on folded Cu foil as integrated electrodes with high areal capacity for flexible Li-ion batteries. J. Alloy. Compd. 809, 151823 (2019)

    Article  CAS  Google Scholar 

  2. R. Khatoon, Y. Guo, S. Attique, K. Khan, A.K. Treen, M.U. Haq et al., Facile synthesis of α-Fe2O3/Nb2O5 heterostructure for advanced Li-Ion batteries. J. Alloy. Compd. 837, 155294 (2020)

    Article  CAS  Google Scholar 

  3. X. Chen, F. Deng, X. Liu, K.-P. Cui, R. Weerasooriya, Hydrothermal synthesis of MnO2/Fe(0) composites from Li-ion battery cathodes for destructing sulfadiazine by photo-Fenton process. Sci. Total Environ. 774, 145776 (2021)

    Article  CAS  Google Scholar 

  4. X. Zhou, J. Ding, J. Tang, J. Yang, H. Wang, M. Jia, Tailored Bi2O3-encapsulated FeF3·0.33H2O composites as high performance cathodes for Li-ion batteries. J. Electroanaly. Chem. 847, 113227 (2019)

    Article  CAS  Google Scholar 

  5. M. Zenasni, A. Quintero-Jaime, A. Benyoucef, A. Benghalem, Synthesis and characterization of polymer/V2O5 composites based on poly (2-aminodiphenylamine). Polym. Composite 42, 1064–1074 (2021)

    Article  CAS  Google Scholar 

  6. C. Wang, Q. Li, F. Wang, G. Xia, R. Liu, D. Li, N. Li, J.S. Spendelow, G. Wu, Morphology-dependent performance of CuO anodes via facile and controllable synthesis for lithium-ion batteries. ACS Appl. Mater. Inter. 6, 1243–1250 (2014)

    Article  CAS  Google Scholar 

  7. P. Wang, X. Gou, S. Xin, F. Cao, Facile synthesis of CuO nanochains as high-rate anode materials for lithium-ion batteries. New J. Chem. 43, 6535–6539 (2019)

    Article  CAS  Google Scholar 

  8. Y. Liu, L. Xiong, P. Li, H. Fu, Z. Hou, L. Zhu, Self-supported CuO nanoflake arrays on nanoporous Cu substrate as high-performance negative-electrodes for lithium-ion batteries. J. Power Sources 428, 20–26 (2019)

    Article  CAS  Google Scholar 

  9. Z. Hu, H. Chen, C. Li, N. Li, K. Xiang, Facile synthesis of CuO-NiO nanocomposites with high surface areas and their application for lithium-ion batteries. Micro Nano Lett. 8, 544–548 (2013)

    Article  Google Scholar 

  10. R. Meng, H. Hou, X. Liu, C. Yan, J. Duan, S. Liu, High performance binder-free quaternary composite CuO/Cu/TiO2 NT/Ti anode for lithium ion battery. Ceram. Int. 42, 6039–6045 (2016)

    Article  CAS  Google Scholar 

  11. W. Yuan, J. Luo, Z. Yan, Z. Tan, Y. Tang, High-performance CuO/Cu composite current collectors with array-pattern porous structures for lithium-ion batteries. Electrochim. Acta 226, 89–97 (2017)

    Article  CAS  Google Scholar 

  12. W. Yuan, Z. Yan, B. Pan, Z. Qiu, J. Luo, Z. Tan et al., Hierarchical MCMB/CuO/Cu anode with super-hydrophilic substrate and blind-hole structures for lithium-ion batteries. J. Alloy. Compd. 719, 353–364 (2017)

    Article  CAS  Google Scholar 

  13. M. Wang, X. Zhang, X. He, B. Zhu, H. Tang, C. Wang, In-situ grown flower-like C@SnO2/Cu2O nanosheet clusters on Cu foam as high performance anode for lithium-ion batteries. J. Alloy. Compd. 856, 158202 (2021)

    Article  CAS  Google Scholar 

  14. Z. Li, G. Xie, C. Wang, Z. Liu, J. Chen, S. Zhong, Binder free Cu2 O/CuO/Cu/Carbon-polymer composite fibers derived from metal/organic hybrid materials through electro deposition method as high performance anode materials for lithium-ion batteries. J. Alloy. Compd. 864, 158585 (2021)

    Article  CAS  Google Scholar 

  15. Y. Wang, L. Cao, J. Li, L. Kou, J. Huang, Y. Feng et al., Cu/Cu2O@Ppy nanowires as a long-life and high-capacity anode for lithium ion battery. Chem. Eng. J. 391, 123597 (2020)

    Article  CAS  Google Scholar 

  16. S. Yuan, S. Weng, F. Wang, X. Dong, Y. Xia, Revisiting the designing criteria of advanced solid electrolyte interphase on lithium metal anode under practical condition. Nano Energy 83, 105847 (2021)

    Article  CAS  Google Scholar 

  17. C.D.I. Torre-Gamarra, M.E. Sotomayor, J. Sanchez, B. Levenfeld, A. Varez et al., High mass loading additive-free LiFePO4 cathodes with 500 μm thickness for high areal capacity Li-ion batteries. J. Power Sources 458, 228033 (2020)

    Article  Google Scholar 

  18. Y.Z. Song, J. Song, L. Zhang, B. Dai, C. Wei, Electrochemical preparation of lithium-rich graphite anode for LiFePO4 battery. High Energy Chem. 54, 441–454 (2020)

    Article  Google Scholar 

  19. Z. Yin, W. Fan, Y. Ding, J. Li, L. Guan, Q. Zheng, Shell Structure control of PPy-modified CuO composite nanoleaves for lithium batteries with improved cyclic performance. ACS Sustainable Chem. Eng. 3, 507–517 (2015)

    Article  CAS  Google Scholar 

  20. Z.R. Parekh, S.H. Chaki, A.B. Hirpara, G.H. Patel, R.M. Kannaujiya, A.J. Khimani, M.P. Deshpande, CuO nanoparticles – synthesis by wet precipitation technique and its characterization. Phys. B 610, 412950 (2021)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

The authors gratefully acknowledge the financial support of the Open Science Foundation for Jiangsu Province Key Laboratory for Chemistry of Low-Dimentional Materials (Grant No. JSKC17009), the Open Science Foundation for Jiangsu Key Laboratory for Biomass–based Energy and Enzyme Technology (Grant No. JSBEET1207), and the Science foundation for Huaiyin Normal University (Grant No.11HSGJBZ13).

Author information

Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Jiangsu Province Key Laboratory for Chemistry of Low-Dimentional Materials, Huaiyin Normal University, Huai’an, 223300, People’s Republic of China

    Y. Z. Song, Z. J. Liu, B. X. Qi & Mengting Li

  2. School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, 212013, People’s Republic of China

    Jimin Xie

  3. Wuhan Dongfeng Mike New Energy Co., Ltd., Wuhan, 430070, People’s Republic of China

    W. H. Song

Authors
  1. Y. Z. Song
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Z. J. Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. B. X. Qi
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Mengting Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Jimin Xie
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. W. H. Song
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Y. Z. Song.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Song, Y.Z., Liu, Z.J., Qi, B.X. et al. Facile Synthesis of Micro CuO Crystals for Li Ion Full Battery. J Inorg Organomet Polym 31, 4434–4439 (2021). https://doi.org/10.1007/s10904-021-02043-9

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10904-021-02043-9

Keywords

Search

Navigation