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Nanocomposite Hydrogels with Multifunctional Cross-Links

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Abstract

Polyvinyl alcohol hydrogels with multifunctional cross-links—silica nanoparticles surface-modified with phenylboronic groups—have been fabricated. It has been demonstrated that such hydrogels exhibit pronounced viscoelastic properties, and their viscosity and elastic modulus are significantly higher than those for gels with single borate ion cross-links.

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REFERENCES

  1. Liu, Y. and Hsu, S., Front. Chem., 2018, vol. 6, p. 449. https://doi.org/10.3389/fchem.2018.00449

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  2. Li, J., Zhang, Z., Cao, X., Liu, Y., and Chen, Q., Soft Matter, 2018, vol. 14, pp. 6767–6773. https://doi.org/10.1039/c8sm01019f

    Article  CAS  PubMed  Google Scholar 

  3. Bishop, M., Shahid, N., Yang, J., and Barron, A.R., Dalton Trans., 2004, pp. 2621–2634. https://doi.org/10.1039/B406952H

  4. Al-Muntasheri, G.A., SPE Prod. Oper., 2014, vol. 29, pp. 243–260. https://doi.org/10.2118/169552-PA

    Article  Google Scholar 

  5. Lee, P.I., US Patent 4559186, publication date December 17, 1985.

  6. Thoniyot, P., Tan, M.J., Karim, A.A., Young, D.J., and Loh, X.J., Adv. Sci., 2015, vol. 2, p. 1400010. https://doi.org/10.1002/advs.201400010

    Article  CAS  Google Scholar 

  7. Silva, M.A. and Dreiss, C.A., Polym. Int., 2016, vol. 65, pp. 268–279. https://doi.org/10.1002/pi.5051

    Article  CAS  Google Scholar 

  8. Bulatova, R.R. and Bakeeva, I.V., Vestn. MITKhT, 2011, vol. 6, pp. 3–21.

    Google Scholar 

  9. Qin, H., Zhang, T., Li, H.-N., Cong, H.-P., Antonietti, M., and Yu, S.-H., Chem., 2017, vol. 3, pp. 691–705. https://doi.org/10.1016/j.chempr.2017.07.017

    Article  CAS  Google Scholar 

  10. Li, Q., Barret, D.G., Messersmith, P.B., and Holten-Andersen, N., ACS Nano, 2016, vol. 10, pp. 1317–1324. https://doi.org/10.1021/acsnano.5b06692

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  11. Barabanova, A.I., Shevnin, P.L., Pryakhina, T.A., Bychko, K.A., Kazantseva, V.V., Zavin, B.G., Vygodskii, Ya.S., Askadskii, A.A., Filippova, O.E., and Khokhlov, A.R., Polym Sci., Ser A, 2008, vol. 50, pp. 1242–1254.

    Article  CAS  Google Scholar 

  12. Barabanova, A.I., Pryakhina, T.A., Afanas’ev, E.S., Zavin, B.G., Vygodskii, Ya.S., Askadskii, A.A., Philippova, O.E., and Khokhlov, A.R., Appl. Surf. Sci., 2012, vol. 258, pp. 3168–3172. https://doi.org/10.1016/j.apsusc.2011.11.057

    Article  CAS  Google Scholar 

  13. Bellamy, L., Infra-Red Spectra of Complex Molecules, New York: Wiley, 1958. Translated under the title Infrakrasnye spektry slozhnykh molekul, Moscow: Inostrannaya Literatura, 1963.

  14. https://www.chemicalbook.com/SpectrumEN_206658-89-1_1HNMR.htm. March 3, 2021.

  15. De Buyl, F. and Kretschmer, A., J. Adhesion, 2008, vol. 84, pp. 125–142. https://doi.org/10.1080/00218460801952809

    Article  CAS  Google Scholar 

  16. Pletneva, V.A., Molchanov, V.S., and Philippova, O.E., Langmuir, 2015, vol. 31, pp. 110–119. https://doi.org/10.1021/la504399e

    Article  CAS  PubMed  Google Scholar 

  17. Kanaya, T., Takahashi, N., Takeshita, H., Ohkura, M., Nishida, K., and Kaji, K., Polym. J., 2012, vol. 44, pp. 83–94. https://doi.org/10.1038/pj.2011.88

    Article  CAS  Google Scholar 

  18. Grosberg, A.Yu. and Khokhlov, A.R., Statistical Physics of Macromolecules, Melville, AIP Press, 1994.

    Google Scholar 

  19. Shibaev, A.V. and Philippova, O.E., Nanosystems: Phys., Chem., Math., 2017, vol. 8, pp. 732–739. https://doi.org/10.17586/2220-8054-2017-8-6-732-739

    Article  CAS  Google Scholar 

  20. Shibaev, A.V., Ospennikov, A.S., Kuklin, A.I., Arkharova, N.A., Orekhov, A.S., and Philippova, O.E., Coll. Surf. A.: Phys. Chem. Asp., 2020, vol. 586, p. 124284. https://doi.org/10.1016/j.colsurfa.2019.124284

    Article  CAS  Google Scholar 

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Funding

This study was supported by the Russian Science Foundation (project no. 19-73-20133).

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Authors and Affiliations

  1. Moscow State University, 119991, Moscow, Russia

    A. I. Barabanova, A. V. Shibaev,  A. R. Khokhlov & O. E. Philippova

  2. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia

    A. I. Barabanova

Authors
  1. A. I. Barabanova
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  2. A. V. Shibaev
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  3. A. R. Khokhlov
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  4. O. E. Philippova
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Corresponding author

Correspondence to A. V. Shibaev.

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Translated by G. Kirakosyan

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Barabanova, A.I., Shibaev, A.V., Khokhlov, A.R. et al. Nanocomposite Hydrogels with Multifunctional Cross-Links. Dokl Phys Chem 497, 41–47 (2021). https://doi.org/10.1134/S0012501621040011

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  • DOI: https://doi.org/10.1134/S0012501621040011

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