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Relationship between the Omniphobic Properties and the Swelling Degree of SLIPS Coatings Based on Polymer Gel Thin Films

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Abstract

The study addresses the relationship between the omniphobic properties of coatings based on polymer matrices doped with liquid lubricants (Slippery Liquid-Infused Porous Surfaces, SLIPS) and the degree of swelling of the matrices in the lubricant. A method for fabrication of matrices based on poly(perfluoroalkyl methacrylates) impregnated with fluorinated oils with different lubricant contents by one-stage synthesis in supercritical (SC) CO2 is proposed. The dependence of the contact angle hysteresis and the sliding angle on the degree of swelling was studied for water and saturated hydrocarbon droplets. The lubricant content in the matrices was determined by thermogravimetric analysis and ellipsometry.

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REFERENCES

  1. Daniel, D., Timonen, J.V.I., Li, R., Velling, S.J., and Aizenberg, J., Nat. Phys., 2017, vol. 13, pp. 1020–1025.

    Article  CAS  Google Scholar 

  2. Snoeijer, J.H. and Andreotti, B., Annu. Rev. Fluid Mech., 2013, vol. 45, pp. 269–292. https://doi.org/10.1146/annurev-fluid-011212-140734

  3. Landau, L. and Levich, B., in: Dynamics of Curved Fronts, Elsevier, 1988, pp. 141–153. https://doi.org/10.1016/b978-0-08-092523-3.50016-2

  4. Li, J., Ueda, E., Paulssen, D., and Levkin, P.A., Adv. Funct. Mater., 2019, vol. 29, p. 1802317. https://doi.org/10.1002/adfm.201802317

    Article  CAS  Google Scholar 

  5. Wong, T.-S., Kang, S.H., Tang, S.K.Y., Smythe, E.J., Hatton, B.D., Grinthal, A., and Aizenberg, J., Nature, 2011, vol. 477, pp. 443–447. https://doi.org/10.1038/nature10447

    Article  CAS  PubMed  Google Scholar 

  6. Sotiri, I., Tajik, A., Lai, Y., Zhang, C.T., Kovalenko, Y., Nemr, C.R., Ledoux, H., Alvarenga, J., Johnson, E., Patanwala, H.S., Timonen, J.V.I., Hu, Y., Aizenberg, J., and Howell, C., Biointerphases, 2018, vol. 13, p. 06D401. https://doi.org/10.1116/1.5039514

  7. Daniel, D., Timonen, J.V.I., Li, R., Velling, S.J., Kreder, M.J., Tetreault, A., and Aizenberg, J., Phys. Rev. Lett., 2018, vol. 120, p. 244503. https://doi.org/10.1103/PhysRevLett.120.244503

    Article  CAS  PubMed  Google Scholar 

  8. Zefirov, V.V., Lubimtsev, N.A., Stakhanov, A.I., Elmanovich, I.V., Kondratenko, M.S., Lokshin, B.V., Gallyamov, M.O., and Khokhlov, A.R., J. Supercrit. Fluids, 2018, vol. 133, pp. 30–37. https://doi.org/10.1016/j.supflu.2017.09.020

    Article  CAS  Google Scholar 

  9. Kazaryan, P.S., Tyutyunov, A.A., Kondratenko, M.S., Elmanovich, I.V., Stakhanov, A.I., Zefirov, V.V., Gallyamov, M.O., Blagodatskikh, I.V., and Khokhlov, A.R., J. Supercrit. Fluids, 2019, vol. 149, pp. 34–41. https://doi.org/10.1016/j.supflu.2019.03.018

    Article  CAS  Google Scholar 

  10. Igumnov, S.R., Sterlin, A.A., and Tuytuynov, Z.A., Mikhailova. RF Patent 2497801C1, 10.11.2013, Byul. No. 31. https://patents.google.com/patent/RU2497801C1/en. Accessed March 1, 2021.

  11. Fujiwara, H., Spectroscopic Ellipsometry: Principles and Applications, Chichester: Wiley, 2007. https://doi.org/10.1002/9780470060193

  12. Dean, J.A., Lange’s Handbook Of Chemistry, New York: McGraw-Hill, 1999.

    Google Scholar 

  13. Barszczewska-Rybarek, I.M., Korytkowska-Walach, A., Kurcok, M., Chladek, G., and Kasperski, J., Acta Bioeng. Biomech., 2017, vol. 19, pp. 47–53. https://doi.org/10.5277/ABB-00590-2016-01

    Article  PubMed  Google Scholar 

  14. Toomey, R., Freidank, D., and Ruhe, J., Swelling behavior of thin, surface-attached polymer networks, Macromolecules, 2004, vol. 37, pp. 882–887. https://doi.org/10.1021/ma034737v

    Article  CAS  Google Scholar 

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ACKNOWLEDGMENTS

This work was performed using the research equipment of the Center for Collective Use “Analytical Center for the Problems of Deep Oil Refining and Petrochemistry,” Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences. The electron microscopy examination was performed using the equipment of the Center for Collective Use “Analysis of Chemical and Biological Systems and Natural Materials,” Federal Research Center of Chemical Physics, Russian Academy of Sciences (no. 506694).

Funding

This work was supported by the Russian Science Foundation, project no. 17-13-01359-P. P.S. Kazaryan is a holder of fellowship of the Foundation for the Development of Theoretical Physics and Mathematics “Basis.”

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Authors and Affiliations

  1. Faculty of Physics, Moscow State University, 119991, Moscow, Russia

    P. S. Kazaryan, E. P. Kharitonova & M. S. Kondratenko

  2. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 119991, Moscow, Russia

    S. V. Makaev

  3. Faculty of Chemistry, Moscow State University, 119991, Moscow, Russia

    A. A. Gulin

  4. Semenov Institute of Chemical Physics, Russian Academy of Sciences, 119991, Moscow, Russia

    A. A. Gulin

Authors
  1. P. S. Kazaryan
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  2. E. P. Kharitonova
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  3. S. V. Makaev
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  4. A. A. Gulin
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  5. M. S. Kondratenko
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Corresponding author

Correspondence to P. S. Kazaryan.

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Translated by Z. Svitanko

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Kazaryan, P.S., Kharitonova, E.P., Makaev, S.V. et al. Relationship between the Omniphobic Properties and the Swelling Degree of SLIPS Coatings Based on Polymer Gel Thin Films. Dokl Phys Chem 497, 28–33 (2021). https://doi.org/10.1134/S0012501621030027

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  • DOI: https://doi.org/10.1134/S0012501621030027

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