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Synthesis of Imidoyl Chlorides Using Phosphorus Trichloride

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Abstract

The reaction of carboxamides with phosphorus trichloride under heating at 75–80°C for 1 h in the presence of a 4-dimethylaminopyridine catalyst was used to synthesize imidoyl chlorides in yields of 63–99%.

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Authors and Affiliations

  1. Volgograd State Technical University, 400005, Volgograd, Russia

    E. V. Shishkin, T. L. Q. Vo, Yu. V. Popov, Yu. L. Zotov, T. L. Nguyen & V. E. Shishkin

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  1. E. V. Shishkin
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  2. T. L. Q. Vo
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  3. Yu. V. Popov
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  4. Yu. L. Zotov
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  5. T. L. Nguyen
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  6. V. E. Shishkin
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Corresponding author

Correspondence to T. L. Q. Vo.

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The authors declare no conflict of interest.

Additional information

Translated from Zhurnal Organicheskoi Khimii, 2021, Vol. 57, No. 5, pp. 747–750 https://doi.org/10.31857/S0514749221050086.

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Shishkin, E.V., Vo, T.L.Q., Popov, Y.V. et al. Synthesis of Imidoyl Chlorides Using Phosphorus Trichloride. Russ J Org Chem 57, 849–851 (2021). https://doi.org/10.1134/S1070428021050134

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  • DOI: https://doi.org/10.1134/S1070428021050134

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