We investigated sputtered nanocarbon films with respect to the effect of suppressing surface oxygen on their electrochemical properties. The nanocarbon film consisted of nanocrystallites with mixed sp² and sp³ bonds formed by unbalanced magnetron sputtering. Ultraviolet/ozone (UV/O₃) irradiation and electrochemical pretreatment (ECP) were conducted to change the surface oxygen concentration of nanocarbon film. X-ray photoelectron spectroscopy (XPS) measurements revealed that nanocarbon films with different amounts of surface oxygen could be prepared. In addition, we observed no significant increase of the surface roughness (R_a) at the angstrom level after treatments, owing to a stable structure containing 40% of sp³ bonds. The electrode characteristics, including the potential window and electrochemical properties for some redox species, such as Ru(NH₃)₆^3+/2+, were investigated. Some electrochemical measurements of zinc ions (Zn²⁺) and hydrogen peroxide (H₂O₂) showed that the electrochemical reaction was improved by suppressing the surface oxygen. These results clearly indicated that the low surface oxygen concentration plays an important role in these electrochemical reactions.