Abstract
An easy collecting Fe3O4 magnetic methylene blue molecularly imprinted polymer was synthesized via bulk polymerization method. It was found that the adsorption capacity can be increased with increasing of methylene blue concentration. Following a comprehensive characterization, its measured maximum adsorption capacity on methylene blue, for the first time, can be reached to 4860 mg/g, much higher than other adsorbents such as activated carbon, water-absorbent resin etc., and also higher than methylene blue molecularly imprinted polymer prepared in our lab before without the Fe3O4. In addition, the molecularly imprinting technique was confirmed to give a high methylene blue selectivity. From a physical chemistry point of view, the adsorption performance of magnetic methylene blue molecularly imprinted polymer was well represented by the Langmuir equation and agree well with the pseudo-first-order kinetic model. Shown that the adsorption was mainly a monolayer and chemical adsorption process and the rate control steps were mainly liquid film diffusion.
Similar content being viewed by others
REFERENCES
F. Wang, L. Liu, W. Cao, and G. Wu, Water Sci. Technol.: Water Supply 18, 603 (2018).
T. Gessner and U. Mayer, Ullmann’s Encyclopedia of Industrial Chemistry (Wiley-VCH Verlag GmbH and Co. KGaA, Weinheim, 2000).
M.-S. Chiou, P.-Y. Ho, and H.-Y. Li, Dyes Pigm. 60, 69 (2004).
M. Ertas, B. Acemioglu, M. H. Alma, and M. Usta, J. Hazard. Mater. 183, 421 (2010).
K. Y. H. Khader and M. Bino, J. Chem. Technol. Biotechnol. 62, 0268 (1995).
I. Cao, L. Wei, Q. Huang, L. Wang, and S. Han, Chemosphere. 38, 565 (1999).
N. Wang, H. Lin, M. Zhaoand, and R. Xiao, AATCC J. Res. 4, 16 (2017).
N. Wang, C. Suand, and S. Xiao, Color. Technol. 131, 434 (2015).
N. Wang, H. Lin, and H. Zhu, J. Solution Chem. 45, 1689 (2016).
N. Wang and M. Zhao, J. Dispersion Sci. Technol. 37, 190 (2015).
J. Qin, M. Oo, K. Kekre, F. Knops, and P. Miller, Sep. Purif. Technol. 49, 295 (2006).
K. Walha, R. B. Amar, L. Firdaous, F. Quéméneur, and P. Jaouen, Desalination 207, 95 (2007).
V. Vadivelan and K. V. Kumar, J. Colloid Interface Sci. 286, 90 (2005).
M. F. Coughlin, B. K. Kinkle, and P. L. Bishop, Chemosphere 46, 11 (2002).
B. H. Hameed, A. L. Ahmad, and K. N. A. Latiff, Dyes Pigm. 75, 143 (2007).
B. K. Singh and N. S. Rawat, J. Chem. Technol. Biotechnol. 61, 307 (1994).
R. Zhao, Y. Wang, X. Li, B. Sun, and C. Wang, ACS Appl. Mater. Interfaces 7, 26649 (2015).
M. A. Malik, A. Ghaffar, and K. Ahmed, Plasma Sources Sci. Technol. 11, 236 (2002).
G. Muthuraman and T. T. Teng, J. Ind. Eng. Chem. 15, 841 (2009).
A. Houas, H. Lachheb, M. Ksibi, E. Elaloui, C. Guillard, and J.-M. Herrmann, Appl. Catal., B 31, 145 (2001).
A. Alinsafi, M. Khemis, M. N. Pons, J. P. Leclerc, A. Yaacoubi, A. Benhammou, and A. Nejmeddine, Chem. Eng. Process. 44, 461 (2005).
C. Minero, M. Lucchiari, D. Vione, and V. Maurino, Environ Sci. Technol. 39, 158 (2005).
L. Xu, H. Zhao, S. Shi, G. Zhang, and J. Ni, Dyes Pigm. 77, 158 (2008).
S. M. Ghoreishi and R. Haghighi, Chem. Eng. J. 95, 163 (2003).
L. Yao, S. K. Lua, L. Zhang, R. Wang, and Z. Dong, J. Hazard. Mater. 280, 428 (2014).
Z. He, L. Lin, S. Song, M. Xia, L. Xu, H. Ying, and J. Chen, Sep. Purif. Technol. 62, 376 (2008).
W. Chu and C.-W. Ma, Water Res. 34, 3153 (2000).
Y. Xiong, C. He, T. An, X. Zhu, and H. T. Karlsson, Water, Air, Soil Pollut. 144, 67 (2003).
A. Molinelli, J. O’Mahony, K. Nolan, M. R. Smyth, M. Jakusch, and B. Mizaikoff, Anal. Chem. 77, 5196 (2005).
J. Hu, X. Mao, S. Cao, and X. Yuan, Polym. Sci., Ser. A 52, 328 (2010).
M. Quaglia, B. Sellergren, and E. De Lorenzi, J. Chromatogr. A 1044, 53 (2004).
A. Bossi, F. Bonini, A. P. Turner, and S. A. Piletsky, Biosens. Bioelectron. 22, 1131 (2007).
Y. Watabe, K. Hosoya, N. Tanaka, T. Kubo, T. Kondo, and M. Morita, J. Chromatogr. A 1073, 363 (2005).
N. T. Greene and K. D. Shimizu, J. Am. Chem. Soc. 127, 5695 (2005).
X. Zhu, J. Yang, Q. Su, J. Cai, and Y. Gao, J. Chromatogr. A 1092, 161 (2005).
E. Caro, R. M. Marcé, P. A. G. Cormack, D. C. Sherrington, and F. Borrull, J. Chromatorg. A 995, 233 (2003).
N. Pérez-Moral and A. G. Mayes, Biosens. Bioelectron. 21, 1798 (2006).
E. Asadi, S. Azodi-Deilami, M. Abdouss, D. Kordestani, A. Rahimi, and S. Asadi, Korean J. Chem. Eng. 31, 1028 (2014).
A. Martín-Esteban, TrAC, Trends Anal. Chem. 45, 169 (2013).
E. Locatelli, L. Gil, L.L. Israel, L. Passoni, M. Naddaka, A. Pucci, T. Reese, V. Gomez-Vallejo, P. Milani, M. Matteoli, J. Llop, J. P. Lellouche, and M. C. Franchini, Int. J. Nanomed. 7, 6021 (2012).
C. Corot, P. Robert, J. M. Idee, and M. Port, Adv. Drug Delivery Rev. 58, 1471 (2006).
Y. Yang, Y. You, Y. Liu, and Z. Yang, Microchim. Acta 180, 379 (2013).
D. A. Usanov, A. E. Postel’ga, T. S. Bochkova, V. N. Gavrilin, and S. V. Igonin, Tech. Phys. 62, 1440 (2017).
Z. Liu, P. Koczera, D. Doleschel, F. Kiessling, and J. Gätjens, Chem. Commun. 48, 5142 (2012).
X. B. Zeng, H. Hu, L. Q. Xie, F. Lan, W. Jiang, Y. Wu, and Z. W. Gu, Int. J. Nanomed. 7, 3365 (2012).
N. Wang, S.-J. Xiao, and C.-W. Su, Colloid Polym. Sci. 294, 1305 (2016).
D. Kavitha and C. Namasivayam, Bioresour. Technol. 98, 14 (2007).
B. Li, J. Guo, K. Lv, and J. Fan, Environ. Pollut. 254, 113014 (2019).
C.-X. Yang, L. Lei, P.-X. Zhou, Z. Zhang, and Z.-Q. Lei, J. Colloid Interface Sci. 443, 97 (2015).
R. Zhao, X. Li, B. Sun, Y. Li, Y. Li, and C. Wang, Chem. Res. Chin. Univ. 33, 986 (2017).
S. Asman, N. A. Yusof, A. H. Abdullah, and M. J. Haron, Molecules 17, 1916 (2012).
H. Guo, H. Wang, N. Zhang, J. Li, J. Liu, A. Alsaedi, T. Hayat, Y. Li, and Y. Sun, Chem. Eng. J. 369, 736 (2019).
K. Glazyrin, C. McCammon, L. Dubrovinsky, M. Merlini, K. Schollenbruch, A. Woodland, and M. Hanfland, Am. Mineral. 97, 128 (2012).
H. Lei, D. He, Y. Guo, Y. Tang, and H. Huang, Appl. Surf. Sci. 442, 71 (2018).
B. Guo, P. Yin, J. Xu, F. S. Liu, and J. N. Wu, Pigm. Resin Technol. 41, 91 (2012).
D. Zhao, Q. Zhang, H. Xuan, Y. Chen, K. Zhang, S. Feng, A. Alsaedi, T. Hayat, and C. Chen, J. Colloid Interface Sci. 506, 300 (2017).
Y. Fu, J. Wang, Q. Liu, and H. Zeng, Carbon 77, 710 (2014).
C. Gonzato, M. Courty, P. Pasetto, and K. Haupt, Adv. Funct. Mater. 21, 3947 (2011).
X. Wang, G. Qiu, Y. Ge, W. Zheng, L. Kong, Y. Xue, B. Ren, and Y. Peng, Korean J. Chem. Eng. 32, 2355 (2015).
I. Kiran, S. Ilhan, N. Caner, C.F. Iscen, and Z. Yildiz, Desalination 249, 273 (2009).
H. M. Freundlich, J. Phys. Chem. A 57, 385 (1906).
M. M. Dubinin, Chem. Rev. 60, 235 (1960).
X. H. Huang, J. J. Song, H. Li, M. T. Gong, and Y. Zhang, J. Hazard. Mater. 365, 53 (2019).
Y. Cui, W. Kang, L. Qin, J. Ma, X. Liu, and Y. Yang, Chem. Eng. J. 397, 125480 (2020).
S. Lagergren, K. Sven. Vetenskapsakad. Handl. 24, 1 (1998).
S. Azizian, J. Colloid Interface Sci. 276, 47 (2004).
W. J. Weber and J. C. Morris, J. Sanit. Eng. Div., Am. Soc. Civil Eng. 89, 31 (1963).
Funding
This work was supported by the Key Technology and Industrial Application Demonstration Project of High Quality and High Purity Nano Calcium Carbonate of Guangxi province (Grant no. 17202030-2).
Author information
Authors and Affiliations
Corresponding authors
Ethics declarations
There are no conflicts to declare.
Rights and permissions
About this article
Cite this article
Hongfu Meng, Zhao, T., Jing, J. et al. Preparation and Properties of Novel Magnetic Methylene Blue Molecularly Imprinted Polymer. Polym. Sci. Ser. B 63, 245–256 (2021). https://doi.org/10.1134/S1560090421030106
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1560090421030106