Skip to main content

Advertisement

SpringerLink
Log in

Industrial processing of phosphogypsum into organomineral fertilizer

  • Original Paper
  • Published:
Environmental Geochemistry and Health Aims and scope Submit manuscript

Abstract

The purpose of this study is to solve the problem of industrial waste storage. Waste from the production of mineral fertilizers is considered in this study (as an example—phosphogypsum LLC «Industrial group «Phosphorit»). Waste storages on a landfill have a significant negative impact on the environment. This fact has been confirmed by studies of wastewater from the dump (drainage water). Phosphogypsum utilization as a mineral component of an organic-mineral mixture without preliminary purification is the most promising approach. In this case, the joint utilization of lignin sludge as an organic component is required. The absence of excess content of toxic elements and the presence of plant nutrients in the required quantities was established as a result of laboratory studies of soil additive. In addition, the authors noted an increased content of stable strontium in phosphogypsum. Localization of strontium in the soil mixture is ensured by fractional application. Strontium is replaced by covalent calcium when the components are absorbed by the plants. The developed soil mixture should be considered as a single-use organomineral additive with prolonged action. Forestry activities, reclamation of disturbed lands, slopes of highways and landfills of solid municipal waste are promising areas of implementation.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3

Similar content being viewed by others

Availability of data and material

A positive expert opinion for the publication of the article materials in the open press was received.

Code availability

Not applicable.

References

  • Alekseev, A. I. (2015). Complex processing of Apatite-nepheline ores based on the creation of closed technological schemes. Journal of Mining Institute, 215, 75–82.

    Google Scholar 

  • Bekbaev, R. (2017). Reclamation efficiency of phosphogypsum on irrigated lands in the Asa-Talas river basin. International Agricultural Journal, 1, 5–11.

    Google Scholar 

  • Belyuchenko, I. S., & Antonenko, D. A. (2015). Influence of complex compost on aggregate composition and water-air properties of ordinary chernozem. Soil Science, 7, 858–864.

    Google Scholar 

  • Belyuchenko, I. S., Dobrydnev, E. P., Gukalov, V. N. et al. (2011). A method for improving the agrophysical properties of the soil. Patent RU2423812, publ. 07.20.2011.

  • Belyuchenko, I. S., Dobrydnev, E. P., Muravyov, E. I., et al. (2008). The use of phosphogypsum for the reclamation of oil-contaminated soils. Proceedings of KubSAU, 3, 72–77.

    Google Scholar 

  • Belyuchenko, I. S., Melnik, O. A., Petukh, Y. Y., et al. (2014). A method for reclamation of agricultural land. Patent RU2516468, publ. 05.20.2014.

  • Belyuchenko, I. S., & Muravyov, E. I. (2009). The influence of industrial and agricultural waste on the physical and chemical properties of soils. Ecological Bulletin of the North Caucasus, 5(1), 84–86.

    Google Scholar 

  • Dobrydnev, E. P., & Loktionov, MYu. (2013). The main results of the study of the agroecological efficiency of phosphogypsum in agriculture in the Krasnodar Territory. Fertility, 1, 7–9.

    Google Scholar 

  • Filippova, T. E. (2002). A method for increasing soil fertility. Patent RU2178964, publ. 10.02.2002.

  • Gezer, F., Turhan, S., Uğur, F. A., et al. (2012). Natural radionuclide content of disposed phosphogypsum as TENORM produced from phosphorus fertilizer industry in Turkey. Annals of Nuclear Energy, 50, 33–37.

    Article  CAS  Google Scholar 

  • Hilton, J. (2010). Phosphogypsum (PG): Uses and current handling practices worldwide. 25th Annual Lakeland Regional Phosphate Conference, Lakeland, USA.

  • Karapetian, K., & Dzhevaga, N. (2017a). Modern technologies of complex processing of phosphates. ARPN Journal of Engineering and Applied Sciences, 12(15), 4588–4594.

    CAS  Google Scholar 

  • Karapetian, K., & Dzhevaga, N. (2017b). Technology of processing of apatites in the production of fused phosphates as modern highly effective fertilizers. International Multidisciplinary Scientific Geoconference SGEM. https://doi.org/10.5593/sgem2017/51/S20.027

    Article  Google Scholar 

  • Kizinek, S. V., & Loktionov, MYu. (2013). The effectiveness of various forms of calcium-containing fertilizers in rice cultivation. Fertility, 1, 14–16.

    Google Scholar 

  • Kolesnikov, S. I., Rotina, E. N., & Kazeev, K. S. (2013). Technology of evaluation methods of soil remediation effectiveness according to biological indicators. Middle East Journal of Scientific Research, 17(7), 914–918.

    CAS  Google Scholar 

  • Korobanova, T. N. (2015). The monitoring of dangerous geodynamic processes during the dump’s formation in Balakovo («Apatit»). MinIng Informational and Analytical Bulletin (scientific and Technical Journal), 4, 405–408.

    Google Scholar 

  • Kovyazin, V. F., Martynov, A. N., & Kuznetsov, E. N. (2016). The state of soils in green spaces of St. Petersburg. Proceedings of higher educational institutions. Forest Journal, 4, 9. https://doi.org/10.17238/issn0536-1036.2016.4.9

    Article  CAS  Google Scholar 

  • Meshcheryakov, Y. G. & Fedorov, S. V. (2007). Industrial processing of phosphogypsum. Saint Petersburg: Stroyizdat SPb.

  • Molkov, A. A., Dergunov, Yu. I., & Suchkov, V. P. (2006). Phosphogypsum processing method. Bulletin of the Chelyabinsk Scientific Center, 4, 59–63.

    Google Scholar 

  • Oxford, R.E. (1992). Granulated nitrogen-phosphorus-potassium-sulfur fertilizer from waste gypsum slurry. Patent US5158594, publ. 27.10.1992.

  • Pashkevich, M. A., Bech, J., Matveeva, V. A., & Alekseenko, A. V. (2020). Biogeochemical assessment of soils and plants in industrial, residential and recreational areas of Saint Petersburg. Journal of Mining Institute, 241, 125. https://doi.org/10.31897/PMI.2020.1.125

    Article  Google Scholar 

  • Pashkevich, M. A., Petrova, T. A., & Rudzisha, E. (2019). Lignin sludge application for forest land reclamation: feasibility assessment. Journal of Mining Institute, 235, 106. https://doi.org/10.31897/pmi.2019.1.106

    Article  Google Scholar 

  • Petukh, YuYu., & Gukalov, V. V. (2011). Effect of phosphogypsum on the composition of soil mesofauna in winter wheat crops. Ecological Bulletin of the North Caucasus, 5(2), 66–69.

    Google Scholar 

  • Ponomareva, Yu. V., & Belyuchenko, I. S. (2005). Effect of phosphogypsum on soil properties, germination of winter wheat seeds. Environmental Problems of the Kuban, 27, 184–192.

    Google Scholar 

  • Ren, Z. (2009). Phosphogypsum sustained-controlled compound fertilizer. Patent CN101434495, publ. 20.05.2009.

  • Sheujen, A. K. & Bondareva T. N. (2015). The use of phosphogypsum neutralized in rice crops as a multicomponent fertilizer. Communication I. Polythematic network electronic scientific journal of the Kuban State Agrarian University (Scientific journal KubSAU). http://ej.kubagro.ru/2015/09/pdf/20.pdf. Accessed 03 August 2020.

  • Shilnikov, I. A., & Akanova, N. I. (2013). The state and efficiency of chemical soil reclamation in agriculture in the Russian Federation of various forms of calcium-containing fertilizers in rice cultivation. Fertility, 1, 9–13.

    Google Scholar 

  • Strizhenok, A., & Korelskiy, D. (2016). Assessment of the state of soil-vegetation complexes exposed to powder-gas emissions of nonferrous metallurgy enterprises. Journal of Ecological Engineering, 17, 25. https://doi.org/10.12911/22998993/64562

    Article  Google Scholar 

  • Strizhenok, A., & Tcvetkov, P. (2017). Ecology-economical assessment of new reclamation method for currently working technogenic massifs. Journal of Ecological Engineering, 18, 58. https://doi.org/10.12911/22998993/66251

    Article  Google Scholar 

  • Suresh, P.O., Nirmit, S., Ajay, J. et al. (2020). Process for preparing granulated phosphogypsum fertilizer composition. Patent IN201921007123, publ. 28.08.2020.

  • Yakovleva, A. S., Kaniskin, M. A., & Terekhova, V. A. (2013). Environmental assessment of soils exposed to phosphogypsum. Soil Science, 6, 737–743.

    Google Scholar 

  • Yan, L., Chen, F., Chen, L. (2014). Sulfur-containing composite microbial fertilizer and production method thereof. Patent CN103570435, publ. 12.02.2014.

  • Yurkova, R. E. (2012). Methods of inactivation of heavy metals and restoration of soil fertility of irrigated lands. Scientific Journal of the Russian Research Institute of Melioration Problems, 1, 1–12.

    Google Scholar 

  • Zelenova A. N., Nazarov, V. A., Sineltsev, A. A. (2017). A method of obtaining a complex organomineral fertilizer based on natural aluminosilicates. Patent RU2607600, publ. 01.10.2017.

Download references

Funding

The study was carried out on the laboratory and experimental base of the accredited Center for the Collective Use of High-Tech Equipment of the St. Petersburg Mining University and supported by the Government of St. Petersburg. The study was carried out at the expense of a subsidy for the fulfillment of the state task in the field of scientific activity for 2021 (№FSRW-2020-0014).

Author information

Authors and Affiliations

  1. Saint-Petersburg Mining University, Saint Petersburg, Russian Federation

    Vera A. Matveeva, Yuriy D. Smirnov & Denis V. Suchkov

Authors
  1. Vera A. Matveeva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yuriy D. Smirnov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Denis V. Suchkov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Denis V. Suchkov.

Ethics declarations

Conflict of interest

The authors declare that they have no conflict of interest.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Matveeva, V.A., Smirnov, Y.D. & Suchkov, D.V. Industrial processing of phosphogypsum into organomineral fertilizer. Environ Geochem Health 44, 1605–1618 (2022). https://doi.org/10.1007/s10653-021-00988-x

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10653-021-00988-x

Keywords

Search

Navigation