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Ruthenium and Nickel Complexes with Cymanthrenenecarboxylic Acid: Synthesis and Structures

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Abstract

The heterometallic complex (L1)Ru(κ2-O2CC5H4)Mn(CO)3(O2CC5H4)Mn(CO)3) (I) (L1 is the pivalate ligand) is synthesized by the reaction of the ruthenium(II) complex (L1)Ru(κ2-O2CCMe3)(O2CCMe3) with cymantrenylcarboxylic acid (HO2CC5H4)Mn(CO)3. The consecutive reactions of nickel acetate with cymantrenenecarboxylic acid and diimine 1,4-di-tert-butyl-1,4-diazabutadiene-1,3 affords the complex (L2)Ni(κ2-O2CC5H4Mn(CO)3)2 (II) (L2 = tBu–N=CH–CH=N–tBu). Complexes I and II are identified by the elemental and X-ray diffraction analyses data (СIF files CCDC nos. 2001354 (I) and 2001355 (II)).

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ACKNOWLEDGMENTS

The studies were carried out using the equipment of the Center for Collective Use of Physical Methods of Investigation at the Kurnakov Institute of General and Inorganic Chemistry (Russian Academy of Sciences).

Funding

This work was supported by the Russian Science Foundation, project no. 18-73-10206.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    S. S. Shapovalov & I. V. Skabitskii

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  1. S. S. Shapovalov
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  2. I. V. Skabitskii
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Correspondence to S. S. Shapovalov.

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The authors declare that they have no conflicts of interest.

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Translated by E. Yablonskaya

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Shapovalov, S.S., Skabitskii, I.V. Ruthenium and Nickel Complexes with Cymanthrenenecarboxylic Acid: Synthesis and Structures. Russ J Coord Chem 47, 330–334 (2021). https://doi.org/10.1134/S1070328421050055

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